耐蚀性钛合金

概述了耐蚀性钛合金的发展过程及Ｔｉ－Ｎｉ－（Ｐｄ、Ｒｕ）－Ｃｒ、Ｔｉ－Ｒｕ－Ｎｉ、Ｔｉ－ｐｄ－Ｃｏ等新型耐蚀钛合金的耐蚀性能。     

Ag-Cu-Ti-(Ti+C)反应-复合钎焊SiC陶瓷和 Ti合金的接头组织

研究用合金化Ag-Cu-Ti粉、Ti粉、C粉组成的混合粉末真空无压钎焊再结晶SiC陶瓷和Ti合金,采用X射线衍射、扫描电镜和能谱仪对接头的组织结构进行了分析.结果表明:在67.6%Ag-26.4%Cu-6%Ti(质量分数)粉末中加入相当于15%～30%TiC(体积分数)的(Ti C)粉末(Ti与C摩尔比为1:1),经920℃,30 min真空钎焊,Ti和C原位合成TiC,形成以TiC晶粒强化的连接良好的复合接头;形成的TiC分布于Ag相、Cu-Ti相中;TiC的形成明显降低了接头的热应力.过量的(Ti C)粉末则导致反应不完全,容易在连接层中产生孔洞,影响接头强度;焊接过程中,Ti由钛合金扩散进入连接层,Cu也有部分从连接层中扩散进入钛合金.     

海洋大气环境下TC4钛合金与316L不锈钢铆接件腐蚀行为研究

研究了TC4-316L异种金属铆接件在模拟海洋大气环境条件下的腐蚀行为。利用失重法、X射线光电子能谱分析(XPS)、扫描电子显微镜(SEM)、激光共聚焦显微镜等方法分析了试样的腐蚀动力学、锈层成分、腐蚀形貌。结果表明,TC4-316L铆接件在周期浸润实验1200 h后,316L不锈钢发生了腐蚀,而TC4钛合金并没有明显的腐蚀现象;316L不锈钢腐蚀产物包含FeOOH,Fe3O4和Fe2O3,而TC4钛合金表面主要为TiO2和Ti2O3等钛的氧化物组成的氧化膜。与单件316L不锈钢相比,由于电偶腐蚀与缝隙腐蚀的共同作用,TC4-316L铆接件中的316L不锈钢腐蚀加速。     

Effects of Process Parameters on the Temperature Field in Ti-6A1-4V Alloy Blade Precision Forging Process

Blade precision forging is a high temperature and large plastic deformation process. Process parameters have a great effect on temperature distribution in billet, so in this paper, by taking a Ti-6Al-4V alloy blade with a tenon as an object, the influence of process parameters on the temperature distribution in precision forging process was investigated using 3D coupled thermo-mechanical FEM (finite element method) code developed by the authors. The results obtained illustrate that: (1) the gradient of temperature distribution increases with increasing the deformation degree; (2) with increasing the initial temperature of the billet, the zones of high temperature become larger, and the gradient of temperature distribution hardly has any increase; (3)friction factors have little effect on the distribution of temperature field; (4) with increasing upper die velocity,temperature of the billet increases while the temperature gradient in billet decreases. The results are helpful to the design and optimization of the process parameters in precision forging process of Ti-alloy blade.     

TC4钛合金全髋关节机械压力机恒载荷精密模锻技术

本文介绍了机械压力机恒载荷精密模锻技术的原理;研究了TC4钛合金全髋关节的精密模锻技术。经试验验证,采用机械压力机恒载荷精密模锻技术生产的锻件尺寸精度高、表面光洁、锻造流线不外露。符合美国标准ASTM F620与中国医药标准YY0117．1—93的要求。     

Microstructure evolution of different loading zones during TA15 alloy multi-cycle isothermal local forging

The microstructure evolution of the TA15 Ti-alloy in different loading zones under two kinds of multi-cycle isothermal local forging (multi-cycle local near-β forging and multi-cycle conventional forging combined with near-β heat treatment) was investigated and the mechanical properties predicted. Under the first processing route, a microstructure with small grain size was obtained with a significant difference in morphology and composition between the first and second loading zones. An equiaxial microstructure with larger size and more α-phase was obtained in the first loading zone. In the second loading zone when cooled by water after multiple forging cycles and a tri-modal microstructure (finely interlaced and disordered lamellar α, transformed β matrix, and a few equiaxed α) was obtained. The second loading zone possesses excellent room and high temperature mechanical properties. Under the second processing route, the relatively large bimodal microstructures in both loading zones are almost identical. When treated using a vacuum annealing furnace after forging, a coarse clustered lamellar secondary α-phase appeared, which has poor mechanical properties.     

热处理对Ti65钛合金板材的显微组织、织构及拉伸性能的影响

研究了不同热处理条件下Ti65钛合金板材的显微组织和织构的变化规律,分析了板材织构的类型和热处理影响拉伸强度的机制。结果表明,热处理对板材的显微组织和织构类型具有显著的影响。通过热处理可分别得到具有等轴组织、双态组织或片层组织的板材。等轴组织板材的织构为晶体c轴与板材RD方向呈现70°~90°夹角的B/T型织构,双态组织和片层组织板材的主要织构类型与等轴组织类似,且出现晶体学c轴与RD方向平行的织构。双态组织板材内的位错和亚结构使板材的室温拉伸强度提高,但是对高温拉伸变形的阻碍能力有限。板材中的织构是影响合金力学性能各向异性的主要因素。经980℃/1 h/AC+700℃/4 h/AC热处理后的板材横、纵向拉伸强度的差异最小,且都具有较高的室温拉伸性能和最佳的650℃拉伸性能。     

基于Murty判据的Ti-6.5Al-3.5Mo-1.5Zr-0.3Si钛合金α β相区热变形机制及工艺优化

根据Murty失稳判据,利用原始等轴组织的TC11钛合金在780～990℃和0.001～70s-1范围内的等温恒应变速率压缩实验数据,建立了该合金的加工图.依据加工图研究了TC11钛合金的变形机制和变形缺陷与变形热力参数之间的关系.结果表明,在780～990℃和0.001～0.01 s-1范围是超塑性变形区;在780～990℃和高于0.01 s-1范围,易出现β相裂纹和空洞、局部流动以及绝热剪切等流变失稳现象.根据加工图分析,结合微观组织观察结果,并考虑变形抗力的大小,确定出了较佳的变形热力参数范围为850～940℃和0.001～0.01 s-1,最佳的变形热力参数在900℃和0.001 s-1附近.     

强流脉冲碳离子束辐照钛合金表面的热效应数值模拟

建立了强流脉冲碳离子束辐照Ti6A l4V靶材的热传导理论模型,采用Msc.Marc有限元程序,对功率密度为1.4×107W/cm2的强流脉冲碳离子束辐照靶材时产生的热效应进行了数值计算,确定了辐照后靶材表面温度场,得到了温度梯度和温度变化速率的变化规律,并进行了实验验证.     

Ti－3Al－2．5V合金管的研制

本文介绍了高级自行车用Ｔｉ－３Ａｌ－２．５Ｖ合金管的研制过程，着重叙述其加工工艺与性能。研制结果表明。Ｔｉ－３Ａｌ－２．５Ｖ属于近α型钛合金，具有较好的冷热塑性变形能力，管材性能优良，适用于作赛车、山地车的车架材料。