全文获取类型
收费全文 | 1036篇 |
免费 | 40篇 |
国内免费 | 106篇 |
专业分类
电工技术 | 4篇 |
综合类 | 61篇 |
化学工业 | 108篇 |
金属工艺 | 438篇 |
机械仪表 | 104篇 |
矿业工程 | 8篇 |
能源动力 | 19篇 |
轻工业 | 1篇 |
石油天然气 | 2篇 |
武器工业 | 10篇 |
无线电 | 87篇 |
一般工业技术 | 234篇 |
冶金工业 | 90篇 |
原子能技术 | 13篇 |
自动化技术 | 3篇 |
出版年
2024年 | 4篇 |
2023年 | 13篇 |
2022年 | 26篇 |
2021年 | 38篇 |
2020年 | 26篇 |
2019年 | 34篇 |
2018年 | 28篇 |
2017年 | 27篇 |
2016年 | 28篇 |
2015年 | 41篇 |
2014年 | 39篇 |
2013年 | 40篇 |
2012年 | 41篇 |
2011年 | 73篇 |
2010年 | 62篇 |
2009年 | 71篇 |
2008年 | 51篇 |
2007年 | 67篇 |
2006年 | 82篇 |
2005年 | 52篇 |
2004年 | 44篇 |
2003年 | 45篇 |
2002年 | 15篇 |
2001年 | 25篇 |
2000年 | 33篇 |
1999年 | 28篇 |
1998年 | 18篇 |
1997年 | 23篇 |
1996年 | 19篇 |
1995年 | 23篇 |
1994年 | 15篇 |
1993年 | 10篇 |
1992年 | 12篇 |
1991年 | 2篇 |
1990年 | 11篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1986年 | 1篇 |
排序方式: 共有1182条查询结果,搜索用时 0 毫秒
1.
Effect of Rare Earth Element Cerium on Mechanical Properties and Morphology of TiN Coating Prepared by Arc Ion Plating 总被引:7,自引:0,他引:7
TiN coatings were deposited on polished substrates of W18Cr4V high speed steel by means of vacuum arc ion plating. The effect of cerium on adhesion between TiN coating and substrate was studied. The microstructures and composition of TiN coatings were also investigated by means of scanning electron microscope (SEM), Auger electron spectroscopy (AES), and X-ray diffraction (XRD) technique. It was found that cerium is an effective modifying agent and the addition of suitable amount of cerium to TiN coatings can produce relatively excellent properties such as micro-hardness, wear resistance, oxidation resistance and porosity. The experimental results show that the added cerium in TiN coatings makesa contribution to form the preferred direction along with a (111 ) or (222) close packed face, which may be one of the reasons that improves some properties mentioned above. 相似文献
2.
38MnSiVS5 steel is similar to 38MnVS6 steel (EN), the difference being the addition of a small Ti content. Typical Ti and Al contents in the chemical composition of 38MnSiVS5 steel are Ti=0.020 and Al=0.035 mass%. Both elements combine easily with nitrogen, especially Ti, and it has been observed that relatively high Al levels are harmful for austenite grain size control at reheating temperatures. In this work 38MnSiVS5 steel is used to manufacture a large number of castings, varying only the Ti and Al contents and obtaining ingots with a different Ti/Al ratio in each case. The results show that abnormal growth of the austenitic grain occurs irrespective of the Ti and Al contents, due fundamentally to the partial dissolution and coarsening of TiN precipitates. However, the steels with high Al contents present worse behaviour due to the formation of a second type of precipitates, namely AIN, which quickly dissolve between 1000 and 1100°C, causing a drastic decline in local pinning forces that gives rise to more pronounced abnormal growth of the affected grains. 相似文献
3.
4.
WANG Xi YANG Genqing LIU Xianghuai ZHENG Zhihong HUANG Wei ZHOU Zuyao ZOU Shichang Ion Beam Laboratory Shanghai Institute of Metallurgy Academia Sinica shanghai China 《金属学报(英文版)》1992,5(11):370-374
A new method for preparation of hard TiN films has been developed by using electronbeam evaporation-deposition of Ti and bombardment with 40 keV Xe~+ ion beam ina N_2 gas environment.The synthesized TiN films were superior to PVD and CVDones in respects of improved adhesion to substrate and low preparing temperature.Theyexhibited good wear resistance and high hardness up to 2200 kg/mm~2.Some industrialapplications have been reported. 相似文献
5.
This paper investigates the interfacial structure in hot-wall CVD TiN/κ-Al2O3 multilayer coatings using both HREM and DFT modeling. Two multilayers with different thicknesses of the TiN layers (50 and 600 nm) separating the κ-Al2O3 layers are analyzed. The general microstructure of the two multilayers is relatively similar. The TiN layer in the thicker TiN/κ-Al2O3 coating is thick enough to be several TiN grains high. This means that epitaxial columns, which are often found in the thinner TiN/κ-Al2O3 coatings, are not present. However, the orientation relationships at the TiN/κ-Al2O3 interfaces are the same in both multilayers. The HREM investigations show that κ-Al2O3 (001) planes can grow directly on flat (111) TiN faces, without any other phases or detectable amounts of impurities, such as sulphur, present. Where the TiN layers are more curved, γ-Al2O3 can be grown, at least partly stabilized by the cube-on-cube orientation relationship between γ-Al2O3 and the underlying TiN. The DFT calculations show very similar adsorption strengths for an O monolayer positioned on Ti-terminated TiC(111) and TiN(111) surfaces, with preferred adsorption in the fcc site. O adsorption on N-terminated TiN(111) is much weaker, with preferred adsorption in the top site. Calculated elastic-energy contributions yield a higher stability for κ-Al2O3 on TiN(111) than on TiC(111) and a higher stability for κ-Al2O3 than for α-Al2O3 on both TiC and TiN. This indicates that the observed higher stability of κ-Al2O3 on TiC(111) than on TiN(111) is not due to the lattice mismatch, while the preferred epitaxial growth of κ-Al2O3 over α-Al2O3 can be partly attributed to the mismatch. 相似文献
6.
Naoto Kimbara Akio Nishijima Toshio Sato Yuji Yoshimura Hiromichi Shimada Nobuyuki Matsubayashi Akinori Yukimura 《Catalysis Letters》1990,6(3-6):409-415
TiN supported molybdenum sulfide catalysts showed much higher activity for cleavage of C-C bonds than oxide supported molybdenum sulfide catalysts, indicating the possibility of a new generation of supports for hydroprocessing catalysts. 相似文献
7.
利用热阴极离子镀技术在牌号为ZK1的硬质合金表面镀制TiN硬质涂层,并在300℃至700℃空气环境下进行抗氧化实验。运用XRD和XPS对涂层进行微观结构和成分的分析,并用SEM进行涂层断口的观察,最后采用显微硬度计和自动划痕仪分別对涂层的显微硬度和膜基结合力进行了检测。实验结果表明,涂层厚度约为5μm,涂层成分以TiN为主,平均显微硬度达2388HV,结合力最大达85N。随着氧化温度的升高,在涂层表面先后形成了TiNxOy、TiO2,涂层的显微硬度和膜基结合力都呈下降趋势并在550℃处剧烈下降。 相似文献
8.
采用2Ti/2Al/3TiN粉体为原料,通过反应热压烧结,以制备Ti2AlN-TiN复合材料。采用X射线衍射(XRD)、场发射扫描电镜(FE-SEM)结合能谱仪(EDS)分析试样。研究结果表明,在1350℃保温2h,压力为30MPa,可烧结得到组织细小、致密的Ti2AlN-TiN复合材料。材料中层片状Ti2AlN晶粒长约5m,TiN晶粒大小为1~2m。复合材料具有良好的机械性能,其显微硬度与弯曲强度分别达8.57GPa和450MPa。 相似文献
9.
采用多弧离子镀设备,在高速钢W18Cr4V上先进行等离子氮化,再沉积TiN薄膜,研究了不同渗氮温度和时间对PN+TiN薄膜组织和性能的影响。结果表明,温度为500℃左右和时间为2h以上条件下对W18Cr4V进行渗氮处理后再沉积TiN薄膜,可以得到最佳的薄膜表面显微硬度(1800~2000HV0.05)和膜/基结合力(50N),涂层耐磨性也得到明显提高。 相似文献
10.