CO2热泵热水器的应用与发展

目前,在面临开发制冷剂替代物的环境下,CO2以绿色环保和优良的热物性,在众多替代物中脱颖而出。CO2在跨临界循环状态,气体冷却器中存在的温差大,更使它在热泵热水系统中得到了广泛的应用。本文着重介绍CO2热泵系统的原理、它在热泵热水器上的发展研究和应用前景。     

Residential CO2 heat pump system for combined space heating and hot water heating

A theoretical and experimental study has been carried out for a residential brine-to-water CO₂ heat pump system for combined space heating and hot water heating. A 6.5 kW prototype heat pump unit was constructed and extensively tested in order to document the performance and to study component and system behaviour over a wide range of operating conditions. The CO₂ heat pump was equipped with a unique counter-flow tripartite gas cooler for preheating of domestic hot water (DHW), low-temperature space heating and reheating of DHW.

The CO₂ heat pump was tested in three different modes: space heating only, DHW heating only and simultaneous space heating and DHW heating. The heat pump unit gave off heat to a floor heating system at supply/return temperatures of 33/28, 35/30 or 40/35 °C, and the set-point temperature for the DHW was 60, 70 or 80 °C. Most tests were carried out at an evaporation temperature of −5 °C, and the average city water temperature was 6.5 °C. The experimental results proved that a brine-to-water CO₂ heat pump system may achieve the same or higher seasonal performance factor (SPF) than the most energy efficient state-of-the-art brine-to-water heat pump systems as long as: (1) the heating demand for hot water production constitutes at least 25% of the total annual heating demand of the residence, (2) the return temperature in the space heating system is about 30 °C or lower, (3) the city water temperature is about 10 °C or lower and (4) the exergy losses in the DHW tank are small.     

The optimum high pressure for CO2 transcritical refrigeration systems with internal heat exchangers

The system performance of a CO₂ refrigeration system is greatly affected by the compressor discharge pressure. An internal heat exchanger (IHX) with high effectiveness is an important factor to achieve high system performance. The expression traditionally used to describe the heat exchange effectiveness is not suitable for CO₂ systems. As a result a practical effectiveness expression for IHX, based on enthalpy difference, has been derived and is reported in this paper. Detailed analysis on the relationship between the optimum high pressure P_k,opt and other systematic parameters was performed. Evaporating temperature has little influence on P_k,opt; and IHX can minimize the sensitivity of the system to the refrigerant quality x at the evaporator outlet. Based on simulation data, a correlation of P_k,opt was developed that predicts the simulation values with a deviation of less than 3.6% in the whole range and 0.94% when the evaporating temperature t₁=5.3 °C. The results reported in this paper can be used in optimum control and performance evaluation of the whole system.     

Integration of a three-stage expander into a CO2 refrigeration system

The inclusion of an expander with work recovery provides two advantages for transcritical CO₂ refrigeration cycles: the COP is improved and the exhaust pressure of the main compressor is lowered. Several designs of expanders have been proposed for this application and some prototypes have been tested already. In our laboratory a three-stage expander has been developed, which replaces the throttle valve of the normal refrigeration cycle and expands into the two-phase region. For optimum integration into the overall system it is proposed to install a vapour-liquid separator between the second and third stage of expansion. The vapour is guided back to the third expander stage whereas the liquid is supplied to the cooling stations via thermostatic or electronic expansion valves.     

Transcritical CO2 refrigeration cycle with ejector-expansion device

An ejector expansion transcritical CO₂ refrigeration cycle is proposed to improve the COP of the basic transcritical CO₂ cycle by reducing the expansion process losses. A constant pressure mixing model for the ejector was established to perform the thermodynamic analysis of the ejector expansion transcritical CO₂ cycle. The effect of the entrainment ratio and the pressure drop in the receiving section of the ejector on the relative performance of the ejector expansion transcritical CO₂ cycle was investigated for typical air conditioning operation conditions. The effect of different operating conditions on the relative performance of the ejector expansion transcritical CO₂ cycle was also investigated using assumed values for the entrainment ratio and pressure drop in the receiving section of the ejector. It was found that the COP of the ejector expansion transcritical CO₂ cycle can be improved by more than 16% over the basic transcritical CO₂ cycle for typical air conditioning operation conditions.     

Flash gas bypass for improving the performance of transcritical R744 systems that use microchannel evaporators

The performance of transcritical R744 systems with direct expansion (DX) can be significantly improved by implementing a Flash Gas Bypass (FGB). The idea behind the concept is to bypass refrigerant vapor, created during the isenthalpic expansion process, around the evaporator. By feeding the evaporator with liquid refrigerant, pressure drop is reduced and refrigerant distribution is improved. With R744 as the working fluid, increased refrigerant-side heat transfer coefficients are expected as well. In addition, the FGB concept proves to be beneficial in terms of system design, in particular for combined air-conditioning and heat pumping applications. An experimental comparison to a conventional DX-system reveals that FGB increases the cooling capacity and COP at the same time by up to 9 and 7%, respectively. Even larger improvements are possible in case a variable speed compressor is utilized to match the performance of the conventional DX-system. A simulation model helps to separate the individual improvement mechanisms. It was found that the reduction of refrigerant-side pressure drop is the dominant improvement mechanism of FGB.     

Comparative performance analysis of solar powered supercritical-transcritical CO2 based systems for hydrogen production and multigeneration

CO₂ based power and refrigeration cycles have been developed and analyzed in different existing studies. However, the development of a CO₂ based comprehensive energy system and its performance analysis have not been considered. In this study, the integration of a CO₂ based solar parabolic trough collector system, a supercritical CO₂ power cycle, a transcritical CO₂ power cycle, and a CO₂ based cascade refrigeration system for hydrogen production and multigeneration purpose is analyzed thermodynamically. This study aims to analyze and compare the difference in the thermodynamic performance of comprehensive energy systems when CO₂ is used as the working fluid in all the cycles with a system that uses other working fluids. Therefore, two comprehensive energy systems with the same number of subsystems are designed to justify the comparison. The second comprehensive energy system uses liquid potassium instead of CO₂ as a working fluid in the solar parabolic trough collector and a steam cycle is used to replace the transcritical CO₂ power cycle. Results of the energy and exergy performance analysis of two comprehensive energy systems showed that the two systems can be used for the multigeneration purpose. However, the use of a steam cycle and potassium-based solar parabolic trough collector increases the comprehensive energy systems’ overall energy and exergy efficiency by 41.9% and 26.7% respectively. Also, the use of liquid potassium as working fluid in the parabolic trough collectors increases the absorbed solar energy input by 419 kW and 2100 kW thereby resulting in a 23% and 90.7% increase in energetic and exergetic efficiency respectively. The carbon emission reduction potential of the two comprehensive energy systems modelled in this study is also analyzed.     

Heat rejection pressure optimization for a carbon dioxide split system: An experimental study

Recent studies indicate carbon dioxide (R744) as a valid alternative to classical substances such as HFCs used in vapour compression plants. However a transcritical refrigeration cycle is needed because the critical temperature of carbon dioxide is usually near the ambient temperature. Consequently the carbon dioxide refrigerator performances are significantly influenced by the heat rejection pressure. In this paper an experimental investigation on working optimization for a “split-system” to cool air in residential applications is presented: by varying the heat rejection pressure an optimum working condition has been found at different ambient temperatures. Furthermore a simplified model to predict the optimum heat rejection pressure is shown and a comparison with experimental results is carried out. Both the model validation and the experimental results suggest that the heat rejection pressure optimization is an convenient method to improve the performance of a carbon dioxide split system. Finally an algorithm based on the aforementioned model has been proposed in order to control an electronic back pressure valve by means of a PLC.     

St. Venant–Exner Equations for Near-Critical and Transcritical Flows

The solution of the St. Venant–Exner equations as a model for bed evolution is studied under conditions when the Froude number, F, approaches unity, and the quasi-steady model becomes singular. It is confirmed that the strict criterion for critical flow, the vanishing of a water surface disturbance celerity, is not met, yet the direction of propagation of a bed wave apparently changes depending on whether F>1 or F<1. An analysis of the linearized model problem for an infinitesimal bed wave under near-uniform conditions is performed, and qualitative features of the solution are brought out. Under appropriate sediment transport conditions, when F2→1, two bed waves, one traveling upstream and the other traveling downstream, are found to develop from an initially single localized bed perturbation. Simulations of the full unsteady problem were performed with the Preissmann scheme to confirm the linear analysis and to study the effects of nonlinearity and friction. A transcritical case, in which a region where F2<1 is succeeded by a region where F2>1, is also investigated, and the solution exhibits an apparently different behavior than cases where the flow is everywhere sub- or supercritical, but can be understood as a hybrid of the latter cases.     

Transcritical CO2 Heat Pump Dryer: Part 2. Validation and Simulation Results

The simulation model of a transcritical CO₂ heat pump dryer presented in Part 1 has been first validated with available experimental data in this part and then used to simulate the heat pump dryer to study the variation of performance parameters such as heating COP, moisture extraction rate, and specific moisture extraction rate. The validation with experimental data shows that the model slightly over predicts the system performance. The possible reasons for the difference between experimental and numerical results are explained. Simulation results show the effect of key operating parameters such as bypass air ratio, re-circulation air ratio, dryer efficiency, ambient condition (temperature and relative humidity), and air mass flow rate. Results show that unlike bypass air ratio and ambient relative humidity, the effect of dryer efficiency, recirculation air ratio, ambient temperature, and air mass flow rate are very significant as far as the system performance is concerned.