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排序方式: 共有455条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(5):6208-6217
Three different coatings, namely TiAlN, TiAlN (external)/NbN (internal) and NbN (external)/TiAlN (internal), were deposited on cemented carbides by arc ion plating. The comparative investigation conducted in this study elucidates the effect of the NbN layer and coating systems on the growth, mechanical properties, and tribological performance of the coatings. The results showed that the surface of the TiAlN and TiAlN/NbN coatings was smoother when TiAlN served as the external layer. The NbN/TiAlN coating, wherein NbN formed the external layer, had a much rougher but more symmetrical surface. With the introduction of the NbN layer, the increased micro stress induced a lower adhesion strength in the TiAlN/NbN and NbN/TiAlN coatings. The TiAlN/NbN and NbN/TiAlN coatings exhibited higher hardness and hardness/effective elastic modulus (H/E*). During the friction test, when the temperature was elevated to 700 °C, the tribological performance of the monolayer TiAlN coating was the lowest because of the TiO2-induced breakage of the dense tribo-oxide film. The NbN layer participated in the formation of a NbOx film at elevated temperatures, which was responsible for the high tribological performance of the two bilayer coatings. When the NbN layer was on the outermost layer and in direct contact with the elevated temperature atmosphere, the NbN/TiAlN coating generated a tribo-oxide film with high integrity, and its coefficient of friction decreased by 27% of that at room temperature. Therefore, the NbN/TiAlN coating exhibited the highest wear resistance at 700 °C. 相似文献
2.
《Intermetallics》2015
The tribological properties of zirconium-based bulk metallic glass (BMG) sliding against polymers, steels, and ceramics at different loads and speeds were investigated. Acoustic emission (AE) technology was used to analyze wear states. The frictional coefficients of the BMG slid against the steel and ceramic balls were high but decreased with increased applied normal load and sliding speed. As the steel balls were more ductile than the ceramic ones, the steel–BMG sliding pairs generated weaker AE signals and exhibited larger wear rates. The BMG tested against the polymer balls had much lower and more stable frictional coefficients than the ones against the steel or ceramic balls because of transferred polymer layers on the BMG surfaces. The BMG against the polymer balls also exhibited the highest AE signals among the three types of counter materials used, indicating that abrasive wear dominated in the polymer-BMG sliding pairs. These results demonstrated the potential application of the BMG as a new tribomaterial that could be an alternative to the traditional crystalline metals for various counter materials. 相似文献
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Javier Lara-Romero Rafael Maya-Yescas José Luis Rico-Cerda José Luis Rivera-Rojas Fernando Chiñas Castillo Matey Kaltchev 《Thin solid films》2006,496(2):463-468
The thermal decomposition of model extreme-pressure lubricant additives on clean iron was studied in ultrahigh vacuum conditions using molecular beam strategies. Methylene chloride and chloroform react to deposit a solid film consisting of FeCl2 and carbon, and evolve only hydrogen into the gas phase. No gas-phase products and less carbon on the surface are detected in the case of carbon tetrachloride. Dimethyl and diethyl disulfide react on clean iron to deposit a saturated sulfur plus carbon layer at low temperatures (∼600 K) and an iron sulfide film onto a Fe + C underlayer at higher temperatures (∼950 K). Methane is the only gas-phase product when dimethyl disulfide reacts with iron. Ethylene and hydrogen are detected when diethyl disulfide is used. 相似文献
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The nanocomposite Cr-Cu-N thin films have been deposited at a substrate temperature of 250 °C by a bipolar asymmetric pulsed DC reactive magnetron sputtering process. Different Cu contents ranging from 0.4 to 14.9 at.% were achieved. The structures of Cr-Cu-N thin films were analyzed by XRD. The surface and cross sectional morphologies of thin films were examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The nanoindentation and scratch tests were adopted to evaluate the mechanical and tribological properties of Cr-Cu-N coatings. The influences of Cu content on the structure, mechanical and tribological properties of Cr-Cu-N coatings were explored. It is observed that the columnar structure no longer exists when the Cu content exceeds 10.9 at.%. The stability of CrN phase in the coating is influenced by the Cu content. The scratching coefficient of thin films decreases with increasing Cu content. Sufficient adhesion and tribological properties of Cr-Cu-N coatings are achieved. The maximum average hardness around 20 GPa and scratching coefficient around 0.1 are found in the coatings with around 2.1 to 2.6 at.% Cu in this work. 相似文献
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The tribological behavior of micro- and nano-crystalline diamond films is evaluated in dry sliding and water lubricating condition. The main wear mechanism is found to be abrasive wear mode induced by self-polishing. Non-diamond components and higher compressive residual stresses are detected in flat MCD films after dry sliding, in comparison to NCD. Origin of decreased friction coefficient in CVD diamond tribosystems under water lubrication is attributed to the effect of water on the formed graphic material and the chemisorbing of diamond surface with H2O, hydrogen or hydroxyl ions. For the MCD/NCD or NCD/MCD contact, the surface roughness of ball largely determines the stable friction coefficient in dry sliding, where NCD film usually presents higher wear rate. 相似文献
9.
Tianyang Chen Jinghu Ji Yonghong Fu Xiping Yang Hao Fu Lunan Fang 《Ceramics International》2021,47(16):23162-23180
The performance of mechanical seals can be improved by using multi-scale composite textures with spiral grooves and micro-dimples, but without a clear texture function mechanism, it is difficult to optimize the textures on the sealing surface. This research established a mathematical model based on the mass-conservative JFO cavitation boundary to analyze the mechanical seal performance of multi-scale composite micro-textures. We use the multi-grid method for numerical solutions, investigate the hydrodynamic lubrication characteristics of composite-textured mechanical seals, and inspect the coupling effect of micro-dimples and spiral grooves. We also analyzed the influence of the geometrical parameters of composite textures on the sealing performance and optimized the sealing surface textures using theoretical analysis. The numerical analysis showed that the multi-scale composite-textured mechanical seal produced a coupling effect between the micro-dimples and spiral grooves, which improved the lubrication of the sealing pair. Eventually, C/SiC mechanical seal bench tests confirmed the tribological improvement of composite textures compared with the un-textured seal under various sealing liquid pressures and rotation speeds. Through comparing the Stribeck curve, the multi-scale composite textured C/SiC mechanical seals have a lower and more stable friction torque than the un-textured. 相似文献
10.
《Ceramics International》2016,42(8):9972-9980
Ti3SiC2/Cu composites with different contents of Cu were fabricated by mechanical alloying and spark plasma sintering method. The phase composition and structure of the composites were analyzed by X-ray diffractometry and scanning electron microscopy equipped with energy dispersive spectroscopy. The mechanical and tribological properties of Ti3SiC2/Cu composites were tested and analyzed compared with monolithic Ti3SiC2 in details. The results show that the Cu leads to the decomposition of Ti3SiC2 to produce TiCx, Ti5Si3Cy, Cu3Si, and TiSi2Cz. The friction coefficient and wear rate of the composites are lower than that of monolithic Ti3SiC2, which is ascribed to the fixing effect of hard TiCx, Ti5Si3Cy, and Cu3Si to inhibit the abrasive friction and wear. However, at elevated temperatures (ranging from room temperature to 600 °C) the friction and wear of the composites are higher than those at room temperature. Plastic flowing and tribo-oxidation wear accompanied by material transference contribute to the increased friction and wear at elevated temperatures. 相似文献