贵溪冶炼厂闪速炉炉体第二次改造

介绍贵冶闪速炉炉体两次改造 ,炉体冷却元件的设置及设计特点 ,阐明了设置冷却元件必要性及使用的实际效果。     

Implications from γ-globulin adsorption onto cation exchangers fabricated by sequential alginate grafting and sulfonation

Our previous work proved that high adsorption capacity and uptake rate of lysozyme were achieved on alginate(Alg)-grafted re sin with an ionic capacity(IC) of 240 mmol·L~(-1)(Alg-FF-240).Moreover,the salt-tolerant feature of Alg-FF-230 was improved by using sequential alginate grafting and sulfonation strategy.Inspired by the enhanced adsorption performance of lysozyme,we have herein proposed to investigate the static and dynamic adsorption behaviors of γ-globulin on a series of Alg-grafted resins with different grafting densities and sulfonation degrees.The adsorption ca pacity of γ-globulin decreased with increa sing alginate-grafting density(IC) from 160 to 230 mmol·L~(-1) at 0 mmol·L~(-1) NaCl because of the steric hindrance caused by the alginate-grafting layer.Effects of ionic strength(IS) indicated that the adsorption capacities of the resins with the IC value of 230-370 mmol·L~(-1) were much higher than CM Sepharose FF at 50-100 mmol·L~(-1) NaCl,and the uptake rate of Alg-FF-230 was about twice as much as that of CM Sepharose FF.This work demonstrated the important effects of alginate-grafting layer and IS in γ-globulin adsorption behavior,which would be helpful in the design of Alggrafted resins and the selection of proper IS condition for protein purification.     

Synthesis of NaYF4:20% Yb3+,2% Er3+,2% Ce3+@NaYF4 nanorods and their size dependent uptake efficiency under flow condition

Lanthanide doped fluorescent nanoparticles have gained considerable attention in biomedical applications. However, the low uptake efficiency of nanoparticles by cells has limited their applications. In this work, we demonstrate how the uptake efficiency is affected by the size of nanoparticles under flow conditions. Using the same size NaYF₄:20% Yb³⁺,2% Er³⁺,2% Ce³⁺ (the contents of rare earths elements are in molar fraction) nanoparticles as core, NaYF₄:20% Yb³⁺,2% Er³⁺,2% Ce³⁺@NaYF₄ core–shell structured nanorods (NRs) with different sizes of 60–224 nm were synthesized by thermal decomposition and hot injection method. Under excitation at 980 nm, a strong upconversion green emission (541 nm, ²H_11/2 → ⁴I_15/2 of Er³⁺) is observed for all samples. The emission intensity for each size nanorod was calibrated and is found to depend on the width of NRs. Under flow conditions, the nanorods with 96 nm show a maximum uptake efficiency by endothelial cells. This work demonstrates the importance of optimizing the size for improving the uptake efficiency of lanthanide-doped nanoparticles.     

The New Frontier Issues for Cognition Technology

Cognitive engineering has developed enormously over the last fifteen years. Yet, despite many excellent research projects and publications, its full potential has not been embraced into mainstream system design. This paper will examine the reasons for this failure and argue that the problem is not simply inertia or lack of education. There are strong organisational influences that cause resistance to this particular approach. The discipline itself has characteristics that make it fragile in the modern corporate structure. In addition, the cognitive engineers themselves are not blameless in the equation. They appear to have done exactly what they criticise the engineering community for doing: they have packaged their product in a manner that is not ‘user friendly’ to its target population, not structured to suit its application, and not output in the format required. Suggestions will be made to rectify the situation: a list of actions is proposed for practising cognitive engineers to make their product more likely to enjoy widespread uptake.     

A fast procedure for the estimation of the hydrogen storage capacity by cryoadsorption of metal-organic framework materials from their available porous properties

In order to identify the best porous materials for the cryogenic physisorption of hydrogen, high-throughput calculations are performed starting, i.e., from the collected information in crystallographic databases. However, these calculations, like molecular simulations, require specific training and significant computational cost. Herein, a relatively simple procedure is proposed to estimate and compare hydrogen uptakes at 77 K and pressure values from 40 bar starting from the porous properties of MOF materials, without involving simulation tools. This procedure uses definitions for adsorption and considers the adsorbed phase as an incompressible fluid whose pressure-density change is that for the liquid phase at 19 K. For the 7000 structures from the CoRE MOF database, the average error of the predictions is only of 1% from reference values at 100 bar, with an SD of ±8%. This accuracy is lower than that from simulation tools, but involving lower computational cost and training.     

长期地膜覆盖与施肥对土壤磷素和玉米吸磷量的影响

利用比较法对长期连续覆膜(17年)后土壤磷素的变化以及玉米吸收量的变化进行了研究。结果表明:经过17年的耕作,无论是施有机肥还是磷肥均能显著增加土壤中速效磷以及全磷的含量;覆膜栽培与裸地栽培比较结果,覆膜对于土壤中速效磷以及全磷含量的变化影响不大;对植株的籽粒、轴、叶片、茎的全磷进行了测定后显示:覆膜可以促进籽粒、轴、茎对磷的吸收,抑制了叶片对磷养分的吸收;从成熟期地上部分累积磷的总量来看,覆膜可以明显提高作物对磷的吸收。     

皖南红黄壤地区连续施用磷钾肥对油菜产量、养分吸收及土壤肥力的影响

在皖南红黄壤地区利用大田试验研究了连续施用磷钾肥对油菜产量、养分吸收和土壤肥力的影响。结果表明:在施用氮肥的基础上合理配施磷钾肥,促进了油菜的生长发育,提高了油菜植株的养分含量和养分吸收量,从而显著增加了油菜的产量,并且磷肥的增产效应大于钾肥效应,三季油菜平均产量以处理P90K120最高,达到了1968.7 kg hm-2;同时连续施用磷钾肥能够改善土壤养分含量,显著提高了土壤速效钾、速效磷含量,与试验前土壤相比,速效磷增加了14.83~20.2 mg kg-1,速效钾增加了69.51~109.61 mg kg-1。     

Ozone Impacts on Vegetation

During the past 50 years, phytotoxic effects of tropospheric ozone on plants have been observed over large areas of the northern hemisphere. The present review highlights some important aspects of the interaction between tropospheric ozone and plants. These include the transfer of ozone from the air to the site of action inside the leaves, primary reactions at the cell membrane, metabolic disturbances, and resulting effects on plant growth. Based on experimental exposure-response relationships, the ozone risk for vegetation can be assessed; in Europe, these assessments suggest widespread impacts of short-term and long-term ozone exposure on plants under well-irrigated conditions.     

杂交苏丹草镉的吸收与分布规律研究

随着土壤中添加镉量的增加,杂交苏丹草的株高明显降低,生物量显著下降。镉添加量为40mg kg土的处理,杂交苏丹草株高和地上部的生物量分别只有对照的48%和8.4%。不加镉的对照,杂交苏丹草根、茎、叶的含镉量分别为3.2,2.7,3.2μg g-1,各部位含镉量没有显著差异;而在添加镉的土壤中,则呈现出根>茎>叶的变化规律;土壤添加镉的量越大,杂交苏丹草各部位含镉量越高,当镉添加量为40mg kg-1土时,根、茎、叶的含镉量分别为451.9,132.5,79.4μg g-1。杂交苏丹草植株中镉含量与土壤中镉的添加量呈现为显著的直线正相关,镉的累积量呈现为先上升后下降的规律。     

Ultradispersed particles in heavy oil: Part I, preparation and stabilization of iron oxide/hydroxide

In this study, ultradispersed colloidal particles of iron oxide/hydroxide were prepared in-situ in heavy oil matrices adopting (w/o) microemulsion approach for nanoparticle preparation detailed in our previous work [1-3]. The effect of composition of heavy oil on the stable concentration of colloidal particles, particle uptake, was investigated. The following trends in particle uptake were common between the (w/o) microemulsions and the heavy oil matrices. An optimum water content was found for which a maximum particle uptake was attained. Particle uptake increased as the content of vacuum residue, VR, and precursor salt concentration increased. Vacuum residue contributes high asphaltene content, which acts as a surface active agent. The iron oxide/hydroxide particles had been recently shown to effectively remove H₂S_(g) from oil phase [4]. H₂S_(g) is a hazardous by-product of heavy oil recovering and upgrading which should be removed as soon as it forms. Results pertaining to H₂S_(g) removal from heavy oil employing ultradispersed particles are communicated in Part II of this study.