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1.
活塞环在内燃机中有着支撑、密闭、储油、导热的作用,内燃机活塞环制备材料应该具备优良的加工性能、耐高温、耐腐蚀、导热性好且具有良好的强韧性,较好的与气缸材料表面的磨合性能。球墨铸铁和专用钢材已经成为制备内燃机活塞环的基础材料,目前国内外采用多种表面处理技术比如:镀铬、氮化、PVD与CVD镀膜、喷钼、喷涂陶瓷层等表面处理工艺进行表面改性,提高内燃机活塞环的使用寿命和使用性能。需要不断研究和开发新的内燃机活塞环的表面处理技术来满足实际生产和应用中内燃机越来越高的要求。 相似文献
2.
NiTi形状记忆合金激光气体氮化层表面特征 总被引:2,自引:0,他引:2
为改善NiTi合金的表面性能,利用2kW连续波Nd:YAG对NiTi合金进行激光气体氮化处理。采用SEM、TEM、XRD、XPS和纳米压痕研究了氮化层的显微组织及表面特征.结果表明:激光气体氮化可以在NiTi合金表面制备连续、无裂纹、厚度为2μm的TiN表面层,该表面层中基本不合有Ni元素且具有很高的硬度,其纳米压痕硬度为29.28GPa. 相似文献
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The sliding wear and impact wear resistances of D2 steel with nitriding layer, PVD titanium nitride coating and their duplex treatment were investigated. The experimental results suggest that the duplex treatment has the best sliding and impact wear resistances under experimental conditions. And the wear resistance of PVD titanium nitride is better than that of nitriding. The impact wear resistance and wear mechanism of all three surface layers remain unchanged under impact load of 0.2 J or 1 J. All samples end with the same symptom of flaking. 相似文献
7.
离子氮化对镀铬层组织与性能的影响 总被引:2,自引:0,他引:2
研究了镀铬层经离子氮化后的组织和性能。分别用SEM、电子探针和X光衍射仪观察和分析了复合处理层剖面的组织、结构和成分,试验结果表明:离子氮化能使镀铬层的网状裂纹弥合,可明显提高了镀层表面硬度、结合力和耐蚀性。 相似文献
8.
Internal nitridation of Co containing 3 a/o of either Cr, Al, or Ti was studied over the range of 700–1100° C in NH3/H2 (694 ratio). The kinetics of thickening of the reaction zone followed the parabolic rate law, suggesting that solidstate diffusion was rate controlling. Activation energies obtained were 51.2 Kcal/molfor Co-3Cr, 46.6 Kcal/mol for Co-3Ti, and 27.9 Kcal/mol for Co-3Al. XRD showed only CrN, AlN, and TiN. Deep etching revealed that AlN formed hexagonal plates near the surface when formed at high temperature, the precipitates becoming more massive (blocky morphology) near the reaction front. TiN formed elongated dendritic precipitates, whereas CrN tended to form spheroids. The precipitate size varied with temperature, decreasing with decreasing temperature. In some cases, nitriding formed a case but no visible precipitates even at very high magnifications in the SEM. The solubility of nitrogen in cobalt was determined by long-time equilibration and subsequent chemical analyses. The diffusivity of nitrogen in cobalt was determined from measured permeabilities and the experimentally determined solubilities. Mechanisms are discussed, and the behavior of internal nitridation is compared with internal carburization and oxidation in cobalt alloys. 相似文献
9.
The internal-nitriding behavior in ammonia-hydrogen atmospheres of type-310 stainless steel and 310 to which either 2 wt.% Ti or 3 wt.% Al were added was studied over the range of 550–950°C. An Fe-24Cr binary alloy was included to assess the role of a BCC crystal structure vs the FCC crystal structure of 310 stainless steel. The BCC alloy exhibited the most rapid kinetics as expected. X-ray diffraction showed only the presence of CrN in all the alloys up to 735°C. At 850°C and above, both CrN and Cr2N were detected. The nonformation of TiN and AlN at lower temperatures is attributed to nucleation problems. Precipitates were extremely fine (unresolvable even at 20,000×) at 563°C and became much coarser with increasing temperature. The precipitate density, size, and shape varied across the internal-nitriding zone at the higher temperatures. External scaling was noted at 850°C and above, however, it was not a continuous film. The activation energy of internal nitriding from 563–735°C ranged from 3.8 kcal/mol for 310+2Ti to 18.2 kcal/mol for 310+3Al; from 850–950°C, the activation energy ranged from 44 (310+2Ti) to 56.6 kcal/mol (310+3Al). Microhardness profiles show that an intermediate zone exists between the nitride case and the base metal. The origin of this zone is discussed. 相似文献
10.
通过分析活塞环的基体组织、径向弹力与气缸套的匹配以及对其施行表面处理,以提高活塞环的耐磨性。对活塞环进行调质或渗氮处理,可显著提高其使用寿命。 相似文献