Coil‐Type Asymmetric Supercapacitor Electrical Cables

Cable‐shaped supercapacitors (SCs) have recently aroused significant attention due to their attractive properties such as small size, lightweight, and bendability. Current cable‐shaped SCs have symmetric device configuration. However, if an asymmetric design is used in cable‐shaped supercapacitors, they would become more attractive due to broader cell operation voltages, which results in higher energy densities. Here, a novel coil‐type asymmetric supercapacitor electrical cable (CASEC) is reported with enhanced cell operation voltage and extraordinary mechanical‐electrochemical stability. The CASECs show excellent charge–discharge profiles, extraordinary rate capability (95.4%), high energy density (0.85 mWh cm⁻³), remarkable flexibility and bendability, and superior bending cycle stability (≈93.0% after 4000 cycles at different bending states). In addition, the CASECs not only exhibit the capability to store energy but also to transmit electricity simultaneously and independently. The integrated electrical conduction and storage capability of CASECS offer many potential applications in solar energy storage and electronic gadgets.     

（S）-噻吗洛尔半水合物的合成及表征

为了开发β受体阻断剂新药（S）-噻吗洛尔半水合物，采用3-吗啉-4-氯-1，2，5-噻二唑为起始原料，经水解反应得到中间体1（3-吗啉-4-羟基-1，2，5-噻二唑）。中间体1与R-环氧氯丙烷发生醚化反应，经后处理及重结晶得到中间体2 {（R）-4-［4-（环氧乙烷-2-基甲氧基）-1，2，5-噻二唑-3-基］吗啉}。中间体2经胺化反应、马来酸成盐及重结晶得到（S）-马来酸噻吗洛尔。（S）-马来酸噻吗洛尔经游离、纯水转晶得到符合药典标准的（S）-噻吗洛尔半水合物，总收率14.05%且e.e.值为99.66%。最终成品经IR、1H-NMR、13C-NMR、MS、TGA、DSC表征，并优化各步反应条件。结果表明:以三乙胺为醚化反应缚酸剂75 ℃反应最佳；以乙醇为胺化反应溶剂46 ℃反应16 h最佳；S-噻吗洛尔的转晶拆分以水作溶剂，比传统不对称合成工艺安全稳定，操作简单，适合工业化生产。     

Crossing the Border: From Keto- to Imine Reduction in Short-Chain Dehydrogenases/Reductases

The family of NAD(P)H-dependent short-chain dehydrogenases/reductases (SDRs) comprises numerous biocatalysts capable of C=O or C=C reduction. The highly homologous noroxomaritidine reductase (NR) from Narcissus sp. aff. pseudonarcissus and Zt_SDR from Zephyranthes treatiae, however, are SDRs with an extended imine substrate scope. Comparison with a similar SDR from Asparagus officinalis (Ao_SDR) exhibiting keto-reducing activity, yet negligible imine-reducing capability, and mining the Short-Chain Dehydrogenase/Reductase Engineering Database indicated that NR and Zt_SDR possess a unique active-site composition among SDRs. Adapting the active site of Ao_SDR accordingly improved its imine-reducing capability. By applying the same strategy, an unrelated SDR from Methylobacterium sp. 77 (M77_SDR) with distinct keto-reducing activity was engineered into a promiscuous enzyme with imine-reducing activity, thereby confirming that the ability to reduce imines can be rationally introduced into members of the “classical” SDR enzyme family. Thus, members of the SDR family could be a promising starting point for protein approaches to generate new imine-reducing enzymes.     

个性化公开密钥系统的设计

论文提出利用用户提供的个性化信息来随机产生关联大素数,保证了素数选取的随机化、个性化,提高了RSA算法的安全性。     

Asymmetric Regulation System Fit for Chinese Telecom Market

After the new round of restructuring of Chinese telecom sector,it's pressing to formulate and implement asymmetric regulation policies so as to shape an effectively competitive market structure in a relatively short term.This paper reviewed the asymmetric regulation policies and practices carried out in foreign telecom market,and then according to the specific situations of Chinese telecom market,proposed the principles and corresponding policies for establishing an asymmetric regulation system fit for Chin...     

基于运动矢量的视频图象数字水印算法

数字水印技术是近年发展起来的一种用于数字产品版权保护和真伪性论证的新兴技术。与静止图象相比，视频水印技术要满足盲检的要求。本文根据运动矢量的特征值ρl，提出了一种视频图象水印新算法。实验结果表明，所提出的水印算法简单、快速，能满足视频编码的实时性要求；算法与现有的视频压缩标准有很好的兼容性；水印的提取具有盲检功能，无需原图象；水印的嵌入不影响I帧的图象质量，与嵌入水印前的原压缩图象相比，嵌入水印后的视频图象信噪比损失很小。     

公开可得到的无密码水印系统的安全性分析

在许多水印商用场合，水印嵌入和检测软件作为一个黑盒子能够公开地被得到，基于这种水印系统模型，针对目前常用的三种水印嵌入方法进行安全性分析。理论分析表明，攻击者能够在保证电子产品质量的前提下很容易地删除水印，最后，提出相应的改进方向。     

基于自适应四叉树分形图像编码的数字水印技术

提出了一种基于自适应四叉树分形编码的数字水印技术。对原始图像进行四叉树分形编码后，通过给定子块在不同的寻找区域中搜索其最佳匹配父块来嵌入水印。实验结果表明，本方法在嵌入水印编码时间、图像质量和鲁棒性方面均比传统的方法有较大的改进。     

新颖的基于小波变换的数字水印方案

随着计算机网络技术与多媒体技术的快速发展，数字产品的版权保护已经成为信息技术领域中最重要的问题之一，提出了一种新颖的基于离散小波变换的数字水印方案，该方案利用改进的Pacthwork算法，将水印嵌入到LL子带中，水印信号在解码过程中无需使用原始图像可快速地重嵌入，该算法利用BCH码来降低误码率，应用所提出的算法，把一个32个字符的水印嵌入到图像中，实现结果表明水印是不可察觉的，经过JPEG有损压缩，低通与中值滤波等图像处理操作后仍是鲁棒的。     

一种用于版权保护的音频数字水印算法

研究了一种基于小波变换的音频数字水印算法，水印为一幅二值图像，仿真实验表明该算法具有较强的稳健性，可用于数字音产品的版权保护。