镁质瓷泥浆流变性能的改进

滑石质瓷是一种高性能瓷的材料，但由于其泥浆的稠化性及泥料塑性差，阻碍了滑石质瓷的大量生产。实验表明：引入长石作助熔剂并加入适量粘土，可以改进泥料塑性及泥浆流变性能，使烧成变形度小，机械强度提高，能较好地满足制品成型的工艺要求。实验中设计了多组配料，分析比较烧后试样的性能测试结果，确定最佳配方及烧结温度。     

添加剂对合成堇青石的影响

本文研究了锆英砂、碳酸钡、硅线石、氟化钙四种添加剂及其含量对合成堇青石晶相组成的影响。结果表明:四种添加剂的加入均提高了堇青石的含量,且加入量都有一最佳值,分别为锆英砂2wt%、碳酸钡3wt%、硅线石2wt%、氟化钙2wt%。     

三石─堇青石匣钵的研制

引入“三石”改善堇青石质匣钵性能,提高匣钵使用寿命。     

“八五”期间陶瓷窑用耐火材料的新进展

本文综合评述了“八五”期间我国陶瓷窑用耐火材料工业在合成低膨胀耐火材料，优质高档窑具品种，窑体及窑车隔热耐火等方面的研究与开发进展，以及各类优质耐火材料在建筑卫生陶瓷窑，日用陶瓷窑上的成功应用。     

Viscosity of Porous Glasses

Viscosity of porous glasses has been derived from the elastic stress analysis, using the viscous analogy. Viscosity as a function of porosity has been estimated for spherical as well as for arbitrary pore geometry. Since the pore geometry changes during sintering, a shape factor that varies with pore geometry has been considered to predict the viscosity–porosity relationship. Viscosity as a function of porosity was measured on cordierite-type glass by isothermal sinter-forging experiments and data showed good agreement with the analysis. Experimental data from literature on viscosity as a function of porosity on two other glasses also show good agreement with the analysis.     

Investigation of the effect of surface phosphate ester dispersant on viscosity by coarse-grain modeling of BaTiO slurry

To understand the role of phosphate ester dispersant, we investigated the rheology of a BaTiO slurry. For the model case, a coarse-grain molecular dynamics (CGMD) simulation was performed with the butyral polymer didodecyl hydrogen phosphate (DHP) in the toluene/ethanol solvent. By systematically analyzing the effect of DHP from an atomic-scale first principle and from all-atom MD to microscale CGMD simulation, we investigated how the adsorption of a DHP dispersant on a BaTiO surface affects the microstructure rheology of a BaTiO slurry. The first-principle and all-atom MD simulation suggests that DHP molecules prefer to locate near the BaTiO surface. CGMD simulation shows a reduction in viscosity with an increase in dispersants, suggesting that the dispersant population near the BaTiO surface plays a key role in controlling the rheology of the BaTiO slurry. In this study, we propose an approach for understanding the BaTiO slurry with molecular-level simulations, which would be a useful tool for efficient optimization of slurry preparation.     

合成堇青石陶瓷材料的研究进展

概述了堇青石材料的组成、结构、性能特点及应用领域。阐述了堇青石的合成方法以及基本原理，重点介绍了天然矿物原料合成堇青石的研究进展。     

Bi2O3对堇青石陶瓷的相组成、微观结构和性能的影响

采用X射线衍射、扫描电镜、差热分析和热膨胀仪等手段研究了由氧化物粉末(MgO，Ai2O3和SiO2)制备堇青石陶瓷时，添加Bi2O3对堇青石陶瓷相变、相组成和性能的影响，Bi2O3在烧结过程中的作用机理是低温产生液相促进烧结。试验表明，在1350℃烧结3h，该陶瓷由堇青石和孤立分布的玻璃相组成。随Bi2O3含量增加，陶瓷的致密度、弯曲强度和热膨胀系数逐渐升高。Bi2O3的添加量(质量分数)大于4％时，原料相石英消失。硅氧网络骨架结合力减小和一定量的玻璃相是引起堇青石陶瓷热膨胀系数升高的主要原因。     

合成堇青石研究现状及进展

堇青石具有低的热膨胀系数、较好的抗热震性能等优点,广泛应用于耐火材料,电子封装材料,多孔陶瓷,催化剂载体及红外辐射材料.目前,工业上主要通过人工合成的方法制备堇青石.人工合成堇青石所用原料已在天然矿物原料的基础上,扩大到固体废物等原料,并且已有很多成功的合成实例.与天然产出的堇青石相比,合成堇青石的性能更加优越.从堇青石的合成原料、合成方法及机理、添加剂改性等方面,就其研究进展进行了介绍,并认为加强对其他合成方法及低温合成的研究,加强对改性添加剂及从固体废物中寻找原料的研究是未来的发展趋势.     

Li2O-MgO-Al2O3-SiO2系高温低膨胀釉的制备及性能研究

以焦炉炉门堇青石衬砖的使用情况为依据，得出适合堇青石衬砖高温低膨胀釉的体系为Li2O-MgO-Al2O3-SiO2系。釉料在合理的化学组成范围内生成堇青石与口．锂辉石固溶体晶体。试验成功的研制出适用于堇青石衬砖的高温低膨胀釉，釉料在1350℃与堇青石砖共同烧成，釉层能均匀光滑的铺展在堇青石衬砖表面，它能在1200℃下使用而不融化，它的热膨胀系数为2．85×10^-4，在20℃～1000℃并且还有待于进一步降低。釉与堇青石衬砖热膨胀相匹配，因此釉层经五次热震（1100℃，水冷）后的没有裂纹出现。XRD物相分析得出釉有堇青石与口．锂辉石固溶体晶体相生成。釉能填充堇青石衬砖表面的气孔并以自身的高致密性防止了有害物质向砖内部渗透，起保护层作用。