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1.
Hydrogel-based nanofibers or vice versa are a relatively new class of nanomaterials, in which hydrogels are structured in nanofibrous form. Structure and size of the material directly governs its functionality, therefore, in hydrogel science, the nanofibrous form of hydrogels enables its usage in targeted applications. Hydrogel nanofiber system combines the desirable properties of both hydrogel and nanofiber like flexibility, soft consistency, elasticity, and biocompatibility due to high water content, large surface area to volume ratio, low density, small pore size and interconnected pores, high stiffness, tensile strength, and surface functionality. Swelling behavior is a critical property of hydrogels that is significantly increased in hydrogel nanofibers due to their small size. Electrospinning is the most popular method to fabricate “hydrogel nanofibers,” while other processes like self-assembly, solution blowing and template synthesis also exist. Merging the characteristics of both hydrogels and nanofibers in one system allows applications in drug delivery, tissue engineering, actuation, wound dressing, photoluminescence, light-addressable potentiometric sensor (LAPS), waterproof breathable membranes, and enzymatic immobilization. Treatment of wastewater, detection, and adsorption of metal ions are also emerging applications. In this review paper, we intend to summarize in detail about electrospun “hydrogel nanofiber” in relation to its synthesis, properties, and applications. 相似文献
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Characterisation of two biomass fuels (pelletised Miscanthus Giganteus and wood) was performed using thermogravimetric analysis with measurement of products by means of Fourier transform infrared spectroscopy (TG-FTIR). Three heating rate profiles were applied (10, 30 and 100 °C/min), with a final temperature of 900 °C. HCN and HNCO were found to be the major N-products, while the NH3 fraction was detected to a minor extent. Kinetic parameters were obtained from the TG-FTIR results using a model based on parallel first-order reactions with a Gaussian distribution of activation energies. On the basis of the above kinetic analysis and product yields, input files for the functional group-devolatilisation, vaporisation, cross-linking biomass-pyrolysis model were prepared. The fit of model parameters to TG-FTIR product-evolution data was found to be generally good, but the model-predicted yields for some species did not fit experimental data at all heating rates. Further improvements in the model are needed to resolve above difficulty. 相似文献
3.
硅烷交联超高分子量聚乙烯 总被引:7,自引:0,他引:7
采用硅烷对超高分子量聚乙烯(UHMWPE)进行交联改性,系统地研究了交联UHMWPE的凝胶率、熔点、结晶度、力学性能与耐磨性。结果表明,硅烷偶联剂导致了UHMWPE的交联,使UHMWPE的凝胶率提高。当硅烷含量较低时,UHMWPE的熔点增高、结晶度增大;当硅烷含量较高时,UHMWPE的熔点、结晶度呈下降的趋势;硅烷交联导致了UHMWPE材料的模量和强度提高,磨耗率降低;当硅烷含量较高时,交联UHMWPE材料的力学性能和磨耗率均变差;当硅烷含量为0.2份~0.4份时,交联UHMWPE材料的综合性能最佳。 相似文献
4.
Qianyu Yang Chen Gao Xuemei Zhang Chihui Tsou Xingyu Zhao Manuel Reyes De Guzman Zejun Pu Xinyue Li Yue Lu Chunyan Zeng Li Yuan Yiqing Xia Yuping Sheng Yiqing Fu 《大分子材料与工程》2021,306(7):2100093
Hydrogels with excellent stiffness, toughness, anti-fatigue, and self-recovery properties are regarded as promising water-containing materials. In this work, a dual physically cross-linked (DPC) sodium alginate (SA)/poly[acrylamide (AAm)-acrylic acid (AAc)-octadecyl methacrylate (OMA)]-Fe3+ hydrogel is reported, which is constructed by hydrophobic association (HA) and ionic coordination (IC). The optimal DPC hydrogel demonstrates excellent mechanical performance: tensile modulus of 0.65 MPa, tensile strength of 3.31 MPa, elongation at break of 1547%, and toughness of 27.8 MJ m–3. SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels also exhibit prominent anti-fatigue and self-recovery performance (99.1–109.7% modulus recovery and 90.4–108.9% dissipated energy recovery after resting for 5 min without additional stimuli at ambient temperature) through the reconstruction of reversible physical cross-linking. Some of the SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels even exhibit a stretching-induced strengthening effect, which is similar to the performance of muscle—“the more training, the more strength.” Hence, the combination of HA and IC will provide an effective approach to design DPC hydrogels with desirable mechanical performances and a longer service life for wider applications of soft materials. 相似文献
5.
铸造用CO2固化碱性酚醛树脂是一种新型造型、制芯用粘结剂,它是由羟甲基含量较高的甲阶碱性酚醛树脂和含氧酸盐及碱等物质组成的混合物,甲阶碱性酚醛树脂性能及它们的组成是影响CO2固化碱性酚醛树脂砂强度的主要因素。模仿实际CO2固化酚醛树脂砂的固化过程,利用测定不同条件下碱性酚醛树脂水溶液pH值变化的方法,对CO2固化碱性酚醛树脂与不同交联剂的固化机理进行了探讨,从中得出有关CO2固化碱性酚醛树脂的交联剂和碱的用量范围,并在此基础上,考察它们和表面稳定剂对砂型抗压强度的影响,获得铸造用CO2固化碱性酚醛树脂较佳组成。 相似文献
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8.
石蜡聚苯乙烯微球的制备 总被引:1,自引:0,他引:1
通过悬浮聚合技术合成了石蜡聚苯乙烯微球,研究了合成过程中引发剂浓度及交联剂用量对微球粒径及其分布的影响。 相似文献
9.
本文研究广丙烯酸酯单体的共聚合反应以及交联型压敏胶带的制备过程,从而确定了最佳工艺条件,并测定了压敏胶带的老化,贮存期,可剥离等性能。 相似文献
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