Author Keywords: trimethylaluminium hydrolysate; stereoregular; poly(propylene oxide); fractionation; end-group analysis; cyclic oligomers 相似文献
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1.
用实验方法研究了Al_2O_3陶瓷缺口试件在循环载荷作用下的疲劳寿命。结果表明,缺口导致的应力集中效应显著降低了循环疲劳寿命;若用缺口根部最大应力为应力水平,则不同缺口半径陶瓷试件具有相同疲劳断裂规律,说明陶瓷材料的疲劳集中系数和理论应力集中系数相同。本文还分析讨论了陶瓷材料的循环疲劳寿命表达式和循环疲劳断裂机理。 相似文献
2.
We analyze specific features of the design of equipment used for mechanical testing of sheet structural materials under the conditions of biaxial static, cyclic, or dynamic loading. We propose original solutions of the problems related to the fatigue testing of crosslike specimens performed without using complex hydraulic systems and their dynamic testing carried out by using very simple testing machines for uniaxial tension–compression. 相似文献
3.
K.W. Allen S.M. Smith W.C. Wake A.O. van Raalte 《International Journal of Adhesion and Adhesives》1985,5(1):23-32
The effect of cyclic stressing on the strength of single lap adhesive joints has been studied and a considerable reduction in strength observed when the maximum stress exceeds about 40% of the ultimate tensile strength, but whether or not a true endurance limit exists is not proven. Fallacies are shown in some of the techniques which have been proposed for studying the fatigue behaviour of adhesive joints. 相似文献
4.
This paper focuses on the microscopic damage and progressive failure of a composite reinforced by plain-weave glass cloth under tensile fatigue loading. The fatigue process was divided into three stages like that of multi-directional laminates. It was found that the internal damage at each stage (matrix cracks, debonds in the weft, successive debonds in the warp and ‘metadelaminations’ between warps and wefts) occurred near the cross-over point of the fabric. The modulus decay mechanism was explained by considering the progression of this internal damage. From the end of the first stage to the beginning of the middle stage, a characteristic damage state (CDS) (called a ‘meta-CDS’) was observed. It was found that woven composites have a unit area of damage accumulation (called a ‘unit cell’) and the damage of each unit cell and its distribution control the total fatigue damage of the material. 相似文献
5.
6.
Theoretical analyses for the single fibre pull-out and push-out models under monotonic loading are given which are based on a shear-lag analysis in a fracture mechanics approach considering non-constant friction at the debonded interface as a result of fibre Poisson contraction (or expansion). The solutions allow the determination of typical fibre/matrix interfacial properties such as the interfacial fracture toughness, Gic, the coefficient of friction, μ, and the residual clamping stress, q0. Under cyclic loading the interfacial properties are expected to degrade as a result of repetitive abrasion, and a power law function is assumed between μ and the number of elapsed cycles, N. However, Gic is assumed to be unaffected and a fracture mechanics based debond criterion is derived for the relationship between the external applied stress, the debond length and the reduced friction coefficient for both fibre pull-out and fibre push-out. In addition, the relative displacements between the free fibre end and the matrix top are obtained for cyclic fatigue when the fibre is loaded and unloaded. A relationship obtained for the protrusion (or intrusion) length in fibre pull-out (or push-out) experiments allows the severity of the interface frictional degradation to be evaluated and characterised. Similarities and differences in the frictional degradation behaviour between fibre pull-out and push-out are also identified. 相似文献
7.
Klaus Witt 《Color research and application》1994,19(4):273-276
The proposed new color-difference formula of CIE TC 129, which is a modified version of CIELAB, was tested with a recently published data set of textile pass/fail judgments. Goodness of fit is improved, if the parameter of lightness is set near 2, and if, additionally, a weight function for lightness is defined that reduces the weight of a lightness difference with lightness level in relation to chroma or hue scaling. © 1994 John Wiley & Sons, Inc. 相似文献
8.
N. Ilayaraja A. Manivel D. Velayutham M. Noel 《Journal of Applied Electrochemistry》2008,38(2):175-186
Electrochemical perfluorination (ECPF) of n-hexanoyl, n-heptanoyl, n-octanoyl, n-nonanoyl and n-decanoyl chlorides was carried out under identical experimental conditions in liquid HF. The product distribution among perfluorinated
carboxylic acids, perfluoro ethers, perfluoroalkanes, isomerised and fragmented products containing less number of carbon
atoms was identified using 19F NMR. The selectivity of C6–C10 perfluoro carboxylic acid varied between 29 and 36%. The alkali insoluble perfluoro cyclic ether and perfluoro alkane fractions
increased with increasing chain length. The increase of perfluoroalkane fractions is mainly due to decarboxylation. Cyclic
ether fractions also decreased slightly with increase in chain length. Among the cyclic ethers α substituted oxolanes were
the predominant products. Six membered cyclic ethers were always found to contain β substitution. The possible pathways for
these products are also indicated.
An erratum to this article can be found at 相似文献
9.
P. Adaikkalam N. Sathaiyan S. Visvanathan 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1993,56(4):389-392
Cyclic voltammetric and galvanostatic experiments have been carried out with both synthetic and commercial bleach solutions with a view to regenerating the same. Maximum efficiency could be achieved if the oxidation is carried out below an anodic potential of 0·80 V vs SCE. The data obtained in galvanostatic experiments with RCE confirm the results of the earlier technique. 相似文献
10.
Partially stereoregular poly(propylene oxide) samples were synthesized via reactions catalysed by a preformed analytically defined trimethylaluminium hydrolysate. These samples were fractionated into two contrastingly different fractions.
1. (i) D-polymers: This fraction constituted the major part (up to 90%). It mainly contained cyclic low molecular weight oligomers (MW < 1000). The linear chains found in D-polymers had hydroxyl end groups. No double bonds could be detected spectroscopically.
2. (ii) K-polymers: This fraction was high molecular weight stereoregular polymer. Stepwise thermal precipitation from dilute isooctane solution of K-polymers yielded a succession of fractions which differed in melting point. It appears that the phase equilibria during the thermal precipitations were not controlled by the molecular weights of species.