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排序方式: 共有3509条查询结果,搜索用时 15 毫秒
1.
Oxide-based near infrared (IR)-shielding coatings consisting of quarter‐wave stacks of oxygen-deficient tantalum oxide (Ta2O5?x) and silicon oxide (SiO2) multilayers and tin-doped indium oxide (In2O3) (ITO) films with the thicknesses of 200–600 nm can block the passage of IR-A (wavelength: 760–1400 nm) and IR-B (wavelength: 1400–3000 nm) radiation, respectively. In this study, the optical properties and microstructure of these oxide-based IR-shielding coatings were investigated. Transmission electron microscopy images indicated that amorphous Ta2O5?x/amorphous SiO2 multilayers were uniform and dense. ITO films were found to be highly crystalline and show carrier concentrations of up to 7.1 × 1020 cm?3, resulting in the strong IR-B optical absorption due to the plasma excitation of the free carriers. Oxide-based IR-shielding coatings with an ITO thickness of 420 nm were found to have near-IR shielding rates of >90% and an average visible light transmittance of >70%. The effects of IR on human keratinocytes were studied to evaluate the IR-induced photoaging in human skin. It was found that the downregulation of cellular proliferation and the enhancement of senescence-associated β-galactosidase activity induced by IR irradiation were significantly inhibited by oxide-based IR-shielding coatings. Thus, this study provides a facile method for the development of coatings for smart windows with high IR-shielding ability and high visible light transmittance. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(36):16121-16131
Ammonia is considered as a promising hydrogen or energy carrier. Ammonia absorption or adsorption is an important aspect for both ammonia removal, storage and separation applications. To these ends, a wide range of solid and liquid sorbents have been investigated. Among these, the deep eutectic solvent (DES) is emerging as a promising class of ammonia absorbers. Herein, we report a novel type of DES, i.e., metal-containing DESs for ammonia absorption. Specifically, the NH3 absorption capacity is enhanced by ca. 18.1–36.9% when a small amount of metal chlorides, such as MgCl2, MnCl2 etc., are added into a DES composed of resorcinol (Res) and ethylene glycol (EG). To our knowledge, the MgCl2/Res/EG (0.1:1:2) DES outperforms most of the reported DESs. The excellent NH3 absorption performances of metal–containing DESs have been attributed to the synergy of Lewis acid–base and hydrogen bonding interactions. Additionally, good reversibility and high NH3/CO2 selectivity are achieved over the MgCl2/Res/EG (0.1:1:2) DES, which enables it to be a potential NH3 absorber for further investigations. 相似文献
3.
4.
Rotating-bending uniaxial fatigue tests and micro-fatigue crack initiation tests were carried out using a permanent mold cast
(PMC) and semi-solid die cast (SDC) with Al−7%Si−0.35%Mg composition in order to examine the relationship between solidification
structures and fatigue behaviors. The crack length was measured using a replication method. Fatigue strength was improved
in SDC, which was almost consistent with the predicted fatigue strength using the size of Si particle cluster. Resistance
to fatigue crack initiation and fatigue strength were improved in SDC owing to the finer Si cluster and to higher ultimate
tensile strength. Fatigue crack in PMC was preferentially initiated at pores. For SDC, the fatigue crack was initiated at
the Si particle/matrix interface, and then sucessively grew along eutectic cell boundaries. 相似文献
5.
A. Vahid Shahidi I. Shih T. Araki C. H. Champness 《Journal of Electronic Materials》1985,14(3):297-310
Structural investigation on monocrystalline CuInSe2 samples has been made. From the single crystal results, the space group of CuInSe2 was confirmed to be Iˉ42d and the crystal solidification direction was investigated. Compositional uniformity of the ingots
was established by EPMA and it was found that the indium concentration was greater than that for copper. Systematic annealing
experiments were carried out in vacuum at different temperatures (as low as 160° C) and for different times. Large variation
in resistivity was observed after the annealing treatment. P-type samples were found to convert to n-type after the heat-treatments. 相似文献
6.
Nano-particulate copper and indium metal layers of 1-2 μm have been deposited by non-vacuum techniques such as doctor blade, screen printing and electrospray using alcoholic suspension pastes. Electrospray showed a high efficiency of material usage and yielded the most uniform morphology. The metal precursor layers were subjected to a thermal treatment (500-600 °C) in selenium vapor to convert the porous metal layers into CuInSe2 compound layers. The chemical conversion, investigated by X-ray diffraction, showed the presence of the In2O3 impurity phase in the precursor as well as in the selenized layers. 相似文献
7.
Cu, In and Se have been codeposited in thin films by potentiostatic one-step electrodeposition. The as-deposited material has shown direct optical transitions attributable to the CuInSe2 semiconductor, but also additional absorption corresponding to another semimetallic phase. The secondary phases are selenium and copper selenide compounds which have been determined by composition measurements. In order to eliminate the semimetallic phases and to improve the semiconductor behaviour of the electrodeposited material, thermal and chemical treatments have been performed. After heat-treatment of the samples at 400°C in flowing argon, elemental selenium loss has been detected together with an enhancement of the allowed direct optical transition. The subsequent chemical etching of the layers in a KCN solution has showed to be successful in eliminating the copper selenide phases which were responsible of the remaining sub-bandgap absorption. 相似文献
8.
V. G. Khoruzhaya K. E. Kornienko P. S. Martsenyuk T. Ya. Velikanova 《Powder Metallurgy and Metal Ceramics》2006,45(5-6):251-258
Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are
used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic
composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility
of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l
⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method
of forming phases in the field of composition rich in aluminum given in publications are confirmed.
__________
Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006. 相似文献
9.
10.
Hydrothermal Synthesis and Low-Temperature Sintering of Zinc Gallate Spinel Fine Particles 总被引:1,自引:0,他引:1
Nanosized powders of single-phase zinc gallate (ZnGa2 O4 ) spinel were hydrothermally synthesized from solutions in the presence of NaOH over the pH range of 1.9 to 7.0 and from solutions above pH 7.0, i.e., the very basic medium (pH of 13.85), by removing the residual ZnO phase by washing with aqueous H2 SO4 from the precipitate mixtures of zinc gallate spinel particles and ZnO. A very wide compositional range (Zn/2Ga = 0.705–1.157) of zinc gallate spinel solid solutions could be hydrothermally synthesized in the form of nanosized particles from acid and very basic mediums (pH of 2.4–13.85) in the presence of NaOH. These hydrothermally synthesized spinel powders showed good sinterability and almost full densification at 1100°C for 1 h. Dense sintered bodies consisting of single-phase zinc gallate spinel were fabricated at 1100°C using zinc gallate spinel powders having almost stoichiometric composition formed from the solution at pH 9.95 in the presence of aqueous ammonia. 相似文献