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排序方式: 共有3337条查询结果,搜索用时 15 毫秒
1.
AbstractBa0.95Ca0.05Ti1-xZrxO3 (BCTZO) ceramics were prepared by a solid state reaction method. The samples were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and X-ray absorption near edge structure (XANES). The ceramics exhibit a pure perovskite structure. The average grain size gradually decreases with increasing Zr concentration. XANES results indicate that the intensities of pre-edge peaks dropped with increasing Zr concentration. The BCTZO ceramic of x?=?0.05 has the optimum electrical properties with the maximum dielectric constant (ε'm), remanent polarization (2Pr), coercive electric field (2Ec) and piezoelectric charge constant (d33) of 7,244, 12.54 (μC/cm2), 5.29 (kV/cm) and 288 (pC/N), respectively. 相似文献
2.
《Ceramics International》2022,48(13):18278-18285
We report the improved energy storage density and efficiency after 2.5% of Samarium substitution in ferroelectric Pb[(Mg1/3Nb2/3)0.80Ti0.20]O3 (PMNT) electroceramic. The microstructure and surface morphology were analyzed and correlated with various functional properties. The energy storage density, leakage current density, ferroelectric and dielectric properties were investigated thoroughly, indicating that Samarium's substitution significantly modified the microstructure, the dielectric strength, breakdown electric field, and turned ferroelectric PMNT to relaxor ferroelectrics. Due to the relaxor nature, the gap between remanent polarization and maximum polarization increases with the substitution of Samarium in PMNT matrix, which further increases the recoverable energy storage density and energy efficiency. A nearly 100% increase in recoverable energy density and efficiency was obtained at an electric field strength of 35 kV/cm at room temperature (~296 K). The electroceramic shows maximum energy density near the ferroelectric phase transition temperature (325 K–345 K) region and provides a moderate energy storage density for possible applications in power microelectronics. 相似文献
3.
Yang Yang Yibei Zhou Juan Ren Qiaoji Zheng Kwok Ho Lam Dunmin Lin 《Journal of the European Ceramic Society》2018,38(2):557-566
Perovskite ferroelectrics possess the fascinating piezoelectric properties near a morphotropic phase boundary, attributing to a low energy barrier that the results in structural instability and easy polarization rotation. In this work, a new lead-free system of (1-x)BaTiO3-xCaHfO3 was designed, and characterized by a coexistence of ferroelectric rhombohedral-orthorhombic-tetragonal (R-O-T) phases. With the increase amount of CaHfO3 (x), a stable coexistence region of three ferroelectric phases (R-O-T) exists at 0.06 ≤ x ≤ 0.08. Both large piezoelectric coefficient (d33~400 pC/N), inverse piezoelectric coefficient (d33*~547 pm/V) and planar electromechanical coupling factor (kp~58.2%) can be achieved for the composition with x = 0.08 near the coexistence of three ferroelectric phases. Our results show that the materials with the composition located at a region where the three ferroelectric R-O-T phases coexist would have the lowest energy barrier and thus greatly promote the polarization rotation, resulting in a strong piezoelectric response. 相似文献
4.
铁电存储器的研究进展 总被引:1,自引:1,他引:0
介绍了铁电存储器的存储原理,同时对两种铁电存储器(铁电随机存取存储器和铁电场效应晶体管存储器)的研究进展、当前存在的问题以及我国目前在这一领域的研究现状进行了简单介绍,并对今后的技术发展进行了展望。 相似文献
5.
G. H. Palmir 《Journal of the Institute of Brewing》1987,93(4):332-333
The aleurone cells of barley, wheat, rice, rye, oats and triticale contained, comparatively, higher percentages of phosphorus than the aleurone cells of sorghum, maize or millet. The aleurone tissues of barley, wheat and rice had more phosphate than corresponding tissues of sorghum and maize. Phosphate was not detected in the aleurone tissue of maize but was found in trace amounts in the aleurone tissue of sorghum. 相似文献
6.
X7R弛豫复相铁电陶瓷的研究 总被引:1,自引:0,他引:1
以PZN-BT(低温相)、PMN-PT(高温相)为起始组元,采用混合烧结法制备了具有X7R介电特性电子瓷料,其介电温谱在55~+125℃范围内相当平坦,室温相对介电常数高达3 877,并从离子的键型分析了影响介电温度稳定性的原因,初步探讨了提高介电温度稳定性的机制。 相似文献
7.
8.
本文介绍溶胶-凝胶法制备均匀PbZr-Ti-B-Si凝胶玻璃,并通过适当热处理在凝胶玻璃中原位生长Pb(Zr;Ti)O3微晶的新工艺·利用IR谱考察了凝胶玻璃中的元素键合结构随温度的变化.结合热分析和XRD;SEM技术,研究了Pb(Zr,Ti)O3微晶在凝胶玻璃中的生长过程及该材料的结构特点.发现Pb2(Zr,Ti)2O6+x立方焦绿石介稳过渡相的纳米微晶首先出现于该体系中,并在更高的温度下先后完全转变成三方和四方Pb(Zr,Ti)O3钙钛矿相.电子显微观察结果表明,该工艺制备的Ph(Zr;Ti)O3玻璃陶瓷具有均匀的细晶结构. 相似文献
9.
应用铁电体极化反转的Orihara Ishibashi理论 ,讨论了圆形铁电薄膜和球形铁电体的开关电流以及开关时间对系统尺寸的依赖性。数值计算表明 ,不论是二维还是三维铁电系统 ,其铁电畴反转过程中产生的开关电流都随系统尺寸减少而下降 ,开关时间随系统尺寸减少而缩短 相似文献
10.
Owing to the rough warehouse handling of storage sacks in tropical areas in Africa, a suitable storage sack should not support de novo growth of fungal spores because this would reduce the tensile strength of the packaging material and act as a springboard for infecting grain contents. This paper reports the effect of activity of saprophytic fungi on the tensile strength of jute and woven polypropylene sacks. New woven polypropylene sacks carried lower levels of fungal spores (1.3×101 cfu/72 cm2) than jute sacks (3.0×103 cfu/72 cm2). The natural mould penetration and growth was examined on sections (4×5 cm) of both jute and woven polypropylene after previous incubation at relative humidities of 55, 60, 65, 70, 75, 80, 90 and 95% for 10 weeks by placing them on Sabouraud's Agar. There was a significant difference (P = 0.05 level of significance) between the higher penetration of mould growth on jute sacks and that obtained on woven polypropylene sacks. Saprophytic fungi (Aspergillus candidus, A. flavus, A. fumigatus, A. niger, A. japonicus, A. parasiticus, A. ustus, Fusarium oxysporium, F. moniliforme, Penicillium verucosum var. cyclopium, Rhizopus oryzae and Trichoderma viride) isolated from jute sacks reduced tensile strength, measured by an Instron Model 1026, by 50–75% after 10 weeks at 90% R.H. Same fungal species on woven polypropylene sacks did not alter the tensile strength. Woven polypropylene sacks did not absorb moisture whilst the moisture content of jute sacks increased by 5.3–6.0% in 10 weeks at 90% R.H. with concomitant increase in mould and yeast counts by 1–2 log cycles. Evidence is presented to show that there was a positive correlation between the final mycoflora on jute sacks and loss in tensile strength. No correlation, however, was found between the total aerobic bacteria on jute sacks and the concomitant reduction in tensile strength. Fungi therefore play a major role in the reduction of tensile strength of jute sacks. Sterilization by gamma irradiation (8.0 kGy) of jute and woven polypropylene sacks did not affect their intrinsic tensile strength. Woven polypropylene sacks therefore have many microbiological and physical advantages over the traditional jute sacks to merit their use for grain storage in tropical areas like Ghana. 相似文献