PZT／Terfenol-D／PVDF层状复合磁电材料谐振特性

采用热压法制备出二层锆钛酸铅(PZT)／聚偏氟乙烯(PVDF)与1层Tb0.28Dy0.72Fe2(Terfenol-D)／PVDF叠层结构的三元复合磁电材料，研究了不同PVDF含量，以及不同层厚比tp／L对样品的介电常数、介电损耗、电阻率、谐振频率以及磁电转换系数αE33，αE31的影响规律，结果显示PVDF的含量和层厚比都存在最佳值(最佳值出现在产0．5，tp／L=2／7)，并且在这个最佳值处，磁电转换系数达到最大。     

环面槽球笼式同步万向联轴器共轭曲面原理

采用共轭曲面原理对应用广泛的环面槽球笼同步万向联轴器,进行了分析;建立了球笼万向轴器实现同步运动时,各接触面的运动关系、曲面方程以及共轭运动关系,推导出了球笼万向联轴器瞬时同步的必要充分条件为两对啮合付的偏心值ε1T=ε1的结论.     

Magnetoelectric voltage coefficients of magnetoelectric composites

The magnetoelectric（ME） effect of the particulate magnetostrictive/piezoelectric composite was theoretically studied. The dependence of the ME voltage coefficients on the material properties of the magnetostrictive phase was discussed. The permittivity, permeability and the elastic modulus of the magnetostrictive phase generally have obvious influences on the ME voltage coefficients. The magnetostrictive phase with a large permittivity, large permeability or stiffer modulus will respectively contribute to the higher ME voltage coefficients. For a certain kind of piezoelectric matrix, the ME voltage coefficients can be improved to some extent by choosing those magnetostrictive materials with large permittivity, permeability or high elastic modulus.     

(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3-Co0.85Cu0.15Fe2O4复合陶瓷的磁电性能研究

以压电体(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3和压磁体Co0.85Cu0.15Fe2O4为原料,通过传统的固相反应法制备了(1-x)[(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3]-xCo0.85Cu0.15Fe2O4多铁性复合陶瓷,并使用X射线衍射仪、扫描电子显微镜、压电测试仪、铁电测试仪和磁电耦合测试仪对物相、显微结构、压电、铁电、磁电耦合性能进行了分析。结果表明,复合陶瓷的相结构保持为(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3和Co0.85Cu0.15Fe2O4两种物相,但两者之间发生了轻微的化学反应。随着Co0.85Cu0.15Fe2O4压磁相含量的增加,复合陶瓷的压电系数从56pC/N减小到21pC/N,剩余极化强度略有降低。在压磁相含量为0.2时可获得4.3mV·cm-1·Oe-1的最佳磁电耦合系数。     

An internal model principle is necessary and sufficient for linear output synchronization

Output synchronization of a network of heterogeneous linear state–space models under time-varying and directed interconnection structures is investigated. It is shown that, assuming stabilizability and detectability of the individual systems and imposing very mild connectedness assumptions on the interconnection structure, an internal model requirement is necessary and sufficient for synchronizability of the network to polynomially bounded trajectories. The resulting dynamic feedback couplings can be interpreted as a generalization of existing methods for identical linear systems.     

汽轮机低压转子与发电机转子联轴器上的缺陷分析

针对国产引进西屋技术制造的600MW汽轮机由于制造上的原因，Ⅱ号加长轴与低压转子及发电机转子的联轴器上存在缺陷，在运行中使相邻轴瓦振动增大，联轴器螺栓承受剪切应力，影响机组的安全运行，提出具体处理意见及措施。     

Sensing Magnetic Field and Intermolecular Interactions in Diamagnetic Solution Using Residual Dipolar Couplings of Zephycandidine

An unusual residual dipolar coupling of methylene protons was recorded in NMR spectra because aromatic zephycandidine has preferential orientation at the external magnetic field. The observed splitting contains contribution from the dipole–dipole D-coupling and the anisotropic component of J-coupling. Absolute values of the anisotropy of magnetic susceptibility |Δχ_ax| are larger for protic solvents because of the hydrogen-bonding compared to aprotic solvents for which polar and dispersion forces are more important. The energy barrier for the reorientation due to hydrogen-bonding is 1.22 kJ/mol in methanol-d_4, 0.85 kJ/mol in ethanol-d₆ and 0.87 kJ/mol in acetic acid-d₆. In dimethyl sulfoxide-d₆, 1.08 kJ/mol corresponds to the interaction of solvent lone pair electrons with π-electrons of zephycandidine. This energy barrier decreases for acetone-d₆ which has smaller electric dipole moment. In acetonitrile-d₃, there is no energy barrier which suggests solvent ordering around the solute due to the solvent-solvent interactions. The largest absolute values of the magnetic anisotropy are observed for aromatic benezene-d₆ and tolune-d₈ which have their own preferential orientation and enhance the order in the solution. The magnetic anisotropy of “isolated” zephycandidine, not hindered by intermolecular interaction could be estimated from the correlation between Δχ_ax and cohesion energy density.     

衬底同步加热溅射BST薄膜的研究

介绍了一种衬底同步加热射频磁控溅射制备BST(BaxSr1-xTiO3)薄膜的新方法,讨论了BST薄膜的晶化效果对介电常数的影响,分析了薄膜的居里温度和εr-V铁电性能.XRD测试结果表明制备的BST薄膜具有完整的钙钛矿晶体结构,相对介电常数超过150,介质击穿强度大于1.3 MV/cm.使用这种方法不需要专门的退火工艺,就可以制备晶体结构完整的高介电常数BST薄膜.     

Mechanical behavior and microstructural analysis of NiTi-40Au shape memory alloys exhibiting work output above 400 °C

Substituting Ni with Au in NiTi leads to dramatic increases in transformation temperatures, meeting one of the requirements for a viable high temperature actuator material. Consequently, four alloys containing between 49 and 51 at.% Ti, a fixed 40 at.% Au, and balance Ni, were prepared and investigated in detail using load-biased thermal cycling (LBTC), scanning electron microscopy (SEM), aberration corrected scanning transmission electron microscopy (STEM), and X-ray energy dispersive spectroscopy (XEDS). LBTC experiments demonstrated work output well above 400 °C, with full recovery up to 100 MPa. The alloys exhibit minimal variation in shape memory properties despite the relatively large composition range from Ti-lean to Ti-rich, in stark contrast to most other NiTi-based systems, which demonstrate extreme compositional sensitivity. Electron beam analysis revealed the presence of two types of secondary phases present in all compositions, which are subsequently characterized. Differences in secondary phase content as a function of alloy composition is shown to have a moderating effect on the transforming matrix composition - an important asset for this alloy system - potentially easing processing requirements and opening up shape memory alloys to new fabrication techniques. Unrecovered strain during cycling at higher loads is analyzed from a theoretical perspective to gain insight into the mechanisms of defect formation responsible for functional fatigue.