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1.
《Advanced Powder Technology》2020,31(12):4585-4597
Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg0.5NixZn0.5-xFe2O4 (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg0.5Ni0.4Zn0.1Fe2O4 (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O2− radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification. 相似文献
2.
《Ceramics International》2021,47(19):27050-27057
Emulsion processed polymer derived ceramic (PDC) nanobeads are used for Methylene Blue dye removal from aqueous solutions. The PDC nanobeads, produced at 600 °C and 1200 °C pyrolysis, are subsequently coated with titania (anatase). Titania-coated nanobeads show less than 35%, i.e., limited dye adsorption capability in dark. Instead, enhanced total removal efficiency (∼97%) is obtained when the initial adsorption is succeeded by photodegradation under UV. Direct reusability tests show that even after the third cycle, very high regeneration efficiencies being above 92% are observed for titania-coated nanobeads. 相似文献
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《International Journal of Hydrogen Energy》2020,45(1):849-860
The glassy carbon electrode is modified by poly(brilliant cresyl blue) (PBCB) to be applied as a new green and efficient platform for Pt and Pt–Ru alloy nanoparticles deposition. Surface composition, morphology and catalytic activity of these modified electrodes towards methanol oxidation are assessed by applying X-ray diffraction, field emission scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy techniques. The X-ray diffraction patterns reveal that the highly crystalline Pt and Pt–Ru alloy and RuO2 nanoparticles with low crystallinity are deposited on the PBCB modified glassy carbon electrodes. The microscopic images indicate smaller size and better distribution of deposited nanoparticles on the surface of PBCB modified electrodes. Cyclic voltammetry and electrochemical impedance spectroscopy results reveal that PBCB supported Pt and Pt–Ru nanoparticles have better electrocatalytic performance and durability towards methanol oxidation rather than the unsupported nanoparticles. From the obtained results it can be concluded that the presence of PBCB not only improves the stability of nanoparticles on the surface, but also leads to the formation of smaller size and more uniform distribution of nanoparticles on the surface, which, in turn, cause the nanoparticles to provide a higher accessible surface area and more active centers for the oxidation of methanol. The results will be valuable in extending the applications of this polymer in surface modification steps and in developing promising catalyst supports to be applied in direct methanol fuel cells. 相似文献
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John Bensted 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(4):181-184
Characterisation of raw materials for Portland cement manufacture by use of the methylene blue adsorption method is discussed. The method is shown to be a simple, convenient ‘rule of thumb’ procedure. It provides a guide to the quantity and type of argillaceous minerals present in a given raw material sample. 相似文献
7.
Qin‐Tao Liu Malcolm R Clench Judith L Kinderlerer 《Journal of the science of food and agriculture》2002,82(5):553-558
Structural isomers of monoacylglycerols (monoglycerides, MAGs) were identified and compared after degradation of butter oil by two strains of Penicillium roquefortii and a commercial lipase from P roquefortii (EC 3.1.1.3) at pH 7.0 and 10 °C. The conditions were selected as they were comparable with those used in the manufacture of blue mould‐ripened cheese. The commercial lipase was selected to compare with the fungal strains in terms of acyl migration. Results showed that the main isomers formed by lipolysis with the commercial lipase were sn‐2 MAGs (64 mol%), whilst spores and emerging mycelia of P roquefortii produced mainly sn‐1(3) MAGs (83–90 mol%). The work reported here may lead to further assessment of different MAG structural isomers as natural preservatives in foods and dairy products. © 2002 Society of Chemical Industry 相似文献
8.
Comments on the article "A house divided? The psychology of red and blue America" by D. C. Seyle and M. L. Newman (see record 2006-11202-001). Seyle and Newman concluded that the red and blue metaphor is inaccurate and proposed a purple America strategy to better convey that the majority of people do not align themselves with political extremes. There is interdisciplinary agreement on this. Although not cited by Seyle and Newman, the findings by Professor Fiorina of Stanford University were reported by the APA Monitor on Psychology in its coverage of the 2005 APA State Leadership Conference (Murray Law, 2005). In contrast to their social psychological analysis, Seyle and Newman were incorrect in concluding that "[a]s psychologists, we are not in a position to change either the elements of the American political system that may spur this conflict or even the decisions made by pundits, politicians, and reporters about the terms they choose to use in political discussion" (p. 579). (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
9.
现代民间青花与现代陶艺 总被引:1,自引:0,他引:1
现代民间青花与现代陶艺都是火与土的艺术,都具有粗犷,质朴、自然、大方的共同艺术特点。前者在传统民间青花的基础上,汲取了现代陶瓷科技成就和现代文化艺术成果,而发展成为富有现代艺术意蕴和现代审判内涵的新型民间青花艺术;而后者则是从传统陶艺延伸、扩展、蜕变为纯粹艺术表达和具有独特审判内涵的一门现代艺术。 相似文献
10.
The nature of the interaction of monomer, and the early stages of growth of oligomers of ethylene on a rather more uniform surface of Cr/SiO2 catalyst than hitherto studied has been investigated by differenceFTIR spectroscopy using C2D4 and C2H4 as reactants both with and without subsequent treatment of the catalyst with CO andTHF. The active catalyst was prepared by reaction of vapour phase CrO2Cl2 with the vicinal hydroxyls of the silica surface. Three distinct kinds of methylene groups were detected. Arguments are given for assigning the peaks at 2935 and 2860 cm–1 to CH2 groups directly bound to the active site and those at 2920 and 2850 to CH2s in the growing chain well removed from the Cr. The peaks at 2160 and 2165 cm–1 are attributed to CD2 groups hydrogen bonded to surface hydroxyls. 相似文献