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Injun Lee Taeseong Jung Junggi Kim Suho Ro Chulsu Kim Yeji Lee Youngmi Kim Juhyun Lee Misook Kang 《Journal of Industrial and Engineering Chemistry》2008,14(6):869-873
This study focuses on the relationship between photo-catalytic performance and optical property over Si-incorporated TiO2. The Si-incorporated TiO2 particles exhibited a pure structure of anatase having a particle size of less than 20 nm and surface area of more than 190 m2/g. The absorbance did not shift to a higher wavelength in spite of the incorporation of the Si ions, but the intensity of the photoluminescence (PL) curve was the smallest in the case of the 2.0 mol% Si-TiO2, which was related to the recombination between the excited electrons and holes. Based on these results, the photodecomposition of methyl orange in the liquid reaction was enhanced over the 2.0 mol% Si-incorporated TiO2 compared with that over pure TiO2: Methyl orange at 10.0 ppm was completely decomposed after 100 min when 1.0 g of the 2.0 mol% Si-incorporated TiO2 was used. 相似文献
4.
The nature of the interaction of monomer, and the early stages of growth of oligomers of ethylene on a rather more uniform surface of Cr/SiO2 catalyst than hitherto studied has been investigated by differenceFTIR spectroscopy using C2D4 and C2H4 as reactants both with and without subsequent treatment of the catalyst with CO andTHF. The active catalyst was prepared by reaction of vapour phase CrO2Cl2 with the vicinal hydroxyls of the silica surface. Three distinct kinds of methylene groups were detected. Arguments are given for assigning the peaks at 2935 and 2860 cm–1 to CH2 groups directly bound to the active site and those at 2920 and 2850 to CH2s in the growing chain well removed from the Cr. The peaks at 2160 and 2165 cm–1 are attributed to CD2 groups hydrogen bonded to surface hydroxyls. 相似文献
5.
Photocatalytic degradation of methyl orange using heteropolytungstic acid-encapsulated TiSBA-15 总被引:1,自引:0,他引:1
Heteropolyphosphotungstic acid (H3PW12O40) (HPA)-encapsulated titanium-supported SBA15 nanoporous materials (HPA-TiSBA-15) were synthesized as a new photocatalyst, and they were characterized by FT-IR and 31P NMR MAS spectroscopic methods. Their photocatalytic effects on degradation of methyl orange in water were investigated under natural conditions, and it was found that a 4-fold increase in the photodegradation rate is observed in the presence of HPA-TiSBA-15 as compared to the rate observed in the presence of titanium-supported SBA15 nanoporous materials (TiSBA-15) without HPA. 相似文献
6.
Nanocrystalline thin films of important surface roughness and complexity were prepared by screen-printing of commercial TiO2 powder. The screen-printed titania films were tested in the photocatalytic decomposition reaction of methyl orange under UV light (350 nm). The photocatalytic activity strongly depends on the titania paste components and especially on the presence of a surface modifier (acetyl acetone) combined with a rheology controlling agent (ethyl cellulose). This results in improvement of the paste viscosity and optimization of the films morphology. Experiments under direct full sunlight illumination prove the importance of the screen-printed films for practical applications. 相似文献
7.
Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1. 相似文献
8.
Mostafa Moussaid Stphane Caillet Josphine Nketsia‐Tabiri Cheikh Boubekri Monique Lacroix 《Journal of the science of food and agriculture》2004,84(13):1657-1662
The study evaluated the effects of waxing, irradiation dose and post‐irradiation storage time on the essential oils in orange peel. Mature oranges (Maroc late) waxed or unwaxed were treated with 1 or 2 kGy radiation and stored for 9 weeks at 20 °C and 40–50% RH. Essential oils from the peel were extracted and analysed by GC. Results showed that D ‐limonene was significantly lower in waxed oranges; levels in samples treated with 2 kGy were higher than those in non‐irradiated or treated with 1 kGy. Linalool, methyl anthranilate and 3,7‐dimethyl‐2,6‐octadienal decreased as the dose increased. Levels of linalool increased with storage time but D ‐limonene was unaffected. These results may aid in guaranteeing the quality of orange essential oils during storage time. Copyright © 2004 Society of Chemical Industry 相似文献
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10.
Sean R. Tachibana Longteng Tang Liangdong Zhu Yuka Takeda Keiji Fushimi Yoshibumi Ueda Takahiro Nakajima Yuto Kuwasaki Moritoshi Sato Rei Narikawa Chong Fang 《International journal of molecular sciences》2021,22(10)
Cyanobacteriochromes (CBCRs) are promising optogenetic tools for their diverse absorption properties with a single compact cofactor-binding domain. We previously uncovered the ultrafast reversible photoswitching dynamics of a red/green photoreceptor AnPixJg2, which binds phycocyanobilin (PCB) that is unavailable in mammalian cells. Biliverdin (BV) is a mammalian cofactor with a similar structure to PCB but exhibits redder absorption. To improve the AnPixJg2 feasibility in mammalian applications, AnPixJg2_BV4 with only four mutations has been engineered to incorporate BV. Herein, we implemented femtosecond transient absorption (fs-TA) and ground state femtosecond stimulated Raman spectroscopy (GS-FSRS) to uncover transient electronic dynamics on molecular time scales and key structural motions responsible for the photoconversion of AnPixJg2_BV4 with PCB (Bpcb) and BV (Bbv) cofactors in comparison with the parent AnPixJg2 (Apcb). Bpcb adopts the same photoconversion scheme as Apcb, while BV4 mutations create a less bulky environment around the cofactor D ring that promotes a faster twist. The engineered Bbv employs a reversible clockwise/counterclockwise photoswitching that requires a two-step twist on ~5 and 35 picosecond (ps) time scales. The primary forward Pfr → Po transition displays equal amplitude weights between the two processes before reaching a conical intersection. In contrast, the primary reverse Po → Pfr transition shows a 2:1 weight ratio of the ~35 ps over 5 ps component, implying notable changes to the D-ring-twisting pathway. Moreover, we performed pre-resonance GS-FSRS and quantum calculations to identify the Bbv vibrational marker bands at ~659,797, and 1225 cm−1. These modes reveal a stronger H-bonding network around the BV cofactor A ring with BV4 mutations, corroborating the D-ring-dominant reversible photoswitching pathway in the excited state. Implementation of BV4 mutations in other PCB-binding GAF domains like AnPixJg4, AM1_1870g3, and NpF2164g5 could promote similar efficient reversible photoswitching for more directional bioimaging and optogenetic applications, and inspire other bioengineering advances. 相似文献