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Hüseyin Enis Karahan Kunli Goh Chuanfang Zhang Euntae Yang Cansu Yıldırım Chong Yang Chuah M. Göktuğ Ahunbay Jaewoo Lee Ş. Birgül Tantekin-Ersolmaz Yuan Chen Tae-Hyun Bae 《Advanced materials (Deerfield Beach, Fla.)》2020,32(29):1906697
MXenes are emerging rapidly as a new family of multifunctional nanomaterials with prospective applications rivaling that of graphenes. Herein, a timely account of the design and performance evaluation of MXene-based membranes is provided. First, the preparation and physicochemical characteristics of MXenes are outlined, with a focus on exfoliation, dispersion stability, and processability, which are crucial factors for membrane fabrication. Then, different formats of MXene-based membranes in the literature are introduced, comprising pristine or intercalated nanolaminates and polymer-based nanocomposites. Next, the major membrane processes so far pursued by MXenes are evaluated, covering gas separation, wastewater treatment, desalination, and organic solvent purification. The potential utility of MXenes in phase inversion and interfacial polymerization, as well as layer-by-layer assembly for the preparation of nanocomposite membranes, is also critically discussed. Looking forward, exploiting the high electrical conductivity and catalytic activity of certain MXenes is put into perspective for niche applications that are not easily achievable by other nanomaterials. Furthermore, the benefits of simulation/modeling approaches for designing MXene-based membranes are exemplified. Overall, critical insights are provided for materials science and membrane communities to navigate better while exploring the potential of MXenes for developing advanced separation membranes. 相似文献
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Functional Materials in Food Nanotechnology 总被引:12,自引:1,他引:11
Jochen Weiss Ph.D. Paul Takhistov Ph.D. D. Julian McClements Ph.D. 《Journal of food science》2006,71(9):R107-R116
The Institute of Food Technologists has issued this Scientific Status Summary to update readers on the applications of nanotechnology in the food industry. 相似文献
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Homogeneous plasticity in metallic glasses is generally only observed at high temperatures or in very small structures (less than ≈100 nm), so their applications for structural performance have been very limited. Here, nanolaminates with alternating layers of Cu50Zr50 metallic glass and nanocrystalline Cu are synthesized and it is found that samples with an optimal composition of 112‐nm‐thick metallic‐glass layers and 16‐nm‐thick Cu layers demonstrate a maximum strength of 2.513 GPa, a value 33% greater than that predicted by the rule‐of‐mixtures and 25% better than that of pure Cu50Zr50 metallic glass. Furthermore, ≈4% strain at fracture is achieved, suppressing the instantaneous catastrophic failure often associated with metallic glasses. It is postulated that this favorable combination of high strength and deformability is caused by the size‐dependent deformation‐mode transition in metallic glasses, from highly localized plasticity, leading to immediate failure in larger samples to homogeneous extension in the smaller ones. 相似文献
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Optical and microstructural properties of ZnO/TiO2 nanolaminates prepared by atomic layer deposition
Yu-Zhu Gu Hong-Liang Lu Yang Geng Zhi-Yuan Ye Yuan Zhang Qing-Qing Sun Shi-Jin Ding David Wei Zhang 《Nanoscale research letters》2013,8(1):107
ZnO/TiO2 nanolaminates were grown on Si (100) and quartz substrates by atomic layer deposition at 200°C using diethylzinc, titanium isopropoxide, and deionized water as precursors. All prepared multilayers are nominally 50 nm thick with a varying number of alternating TiO2 and ZnO layers. Sample thickness and ellipsometric spectra were measured using a spectroscopic ellipsometer, and the parameters determined by computer simulation matched with the experimental results well. The effect of nanolaminate structure on the optical transmittance is investigated using an ultraviolet–visible-near-infrared spectrometer. The data from X-ray diffraction spectra suggest that layer growth appears to be substrate sensitive and film thickness also has an influence on the crystallization of films. High-resolution transmission electron microscopy images show clear lattice spacing of ZnO in nanolaminates, indicating that ZnO layers are polycrystalline with preferred (002) orientation while TiO2 layers are amorphous. 相似文献
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Hyeunseok Cheun Canek Fuentes‐Hernandez Jaewon Shim Yunnan Fang Ye Cai Hong Li Ajaya K. Sigdel Jens Meyer Julia Maibach Amir Dindar Yinhua Zhou Joseph J. Berry Jean‐Luc Bredas Antoine Kahn Kenneth H. Sandhage Bernard Kippelen 《Advanced functional materials》2012,22(7):1531-1538
Atomic layer deposition is used to synthesize Al2O3:ZnO(1:x) nanolaminates with the number of deposition cycles, x, ranging from 5 to 30 for evaluation as optically transparent, electron‐selective electrodes in polymer‐based inverted solar cells. Al2O3:ZnO(1:20) nanolaminates are found to exhibit the highest values of electrical conductivity (1.2 × 103 S cm?1; more than six times higher than for neat ZnO films), while retaining a high optical transmittance (≥80% in the visible region) and a low work function (4.0 eV). Such attractive performance is attributed to the structure (ZnO crystal size and crystal alignment) and doping level of this intermediate Al2O3:ZnO film composition. Polymer‐based inverted solar cells using poly(3‐hexylthiophene) (P3HT):phenyl‐C61‐butyric acid methyl ester (PCBM) mixtures in the active layer and Al2O3:ZnO(1:20) nanolaminates as transparent electron‐selective electrodes exhibit a power conversion efficiency of 3% under simulated AM 1.5 G, 100 mW cm?2 illumination. 相似文献
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S. A. Firstov É. P. Pechkovskii I. I. Ivanova N. P. Brodnikovskii V. F. Gorban’ A. N. Demidik 《Strength of Materials》2006,38(6):624-636
By the methods of micro-and macroindentation, uniaxial compression, and scanning electron microscopy, we study the behavior
of the structure and mechanical properties of mono-and biphase Ti3SiC2, Ti3AlC2, and Ti4AlN3 titanium nanolaminates (in-situ composites) prepared by the method of reaction sintering in compact and porous states. The
regularities, specific features, and mechanisms of deformation and fracture processes are established for each material within
the temperature range 20–1300°C. The temperature-strain and force boundaries of their existence in the plastic state are determined.
The comparative analysis of the mechanical properties of nanolaminates is performed. It is shown that the strength characteristics
of nanolaminates and their strain and creep resistance at medium and high temperatures increase in the following sequence:
Ti3AlC2-Ti4AlN3-Ti3SiC2. The obtained picture of high-temperature properties of these materials is explained. It is shown that the procedure of prestraining
of a porous material by ε = 4–8% may result in a significant increase in its specific high-temperature strength up to values
higher than those typical of the compact material.
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Translated from Problemy Prochnosti, No. 6, pp. 79–94, November–December, 2006. 相似文献
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Mohit Kumar Seung-Ik Han Yeonghwan Ahn Yerin Jeon Jiyeong Park Hyungtak Seo 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(25):2206736
Nontrivial topological polar textures in ferroelectric materials, including vortices, skyrmions, and others, have the potential to develop ultrafast, high-density, reliable multilevel memory storage and conceptually innovative processing units, even beyond the limit of binary storage of 180° aligned polar materials. However, the realization of switchable polar textures at room temperature in ferroelectric materials integrated directly into silicon using a straightforward large area fabrication technique and effectively utilizing it to design multilevel programable memory and processing units has not yet been demonstrated. Here, utilizing vector piezoresponse force and conductive atomic force microscopy, microscopic evidence of the electric field switchable polar nanotexture is provided at room temperature in HfO2-ZrO2 nanolaminates grown directly onto silicon using an atomic layer deposition technique. Additionally, a two-terminal Au/nanolaminates/Si ferroelectric tunnel junction is designed, which shows ultrafast (≈83 ns) nonvolatile multilevel current switching with high on/off ratio (>106), long-term durability (>4000 s), and giant tunnel electroresistance (108%). Furthermore, 14 Boolean logic operations are tested utilizing a single device as a proof-of-concept for reconfigurable logic-in-memory processing. The results offer a potential approach to “processing with polar textures” and addressing the challenges of developing high-performance multilevel in-memory processing technology by virtue of its fundamentally distinct mechanism of operation. 相似文献
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