涂镀钢铁产品发展近况

随着带钢生产技术的日益进步,涂镀钢铁产品已由传统产品向具有高性能的新型产品发展,无铬钝化板、氟碳板、耐指纹板及自清洁板等应运而生.介绍了部分涂镀钢铁产品近期发展的概况,指出在发展过程中需要注意并加以解决的一些问题.     

An Investigation of Passivatior of Cerium for Red Copper

The paperis studied and probed into the cerium application in the passivators of red copper. Through the experimentation of single factor we knoew that ithas remarkable quality influence among red copper passivators by Ce3 , determined that there is obvious function in its small content. And we educed a best technology through the orthogonal test. Research shows: there are obvious changes in the molecular structure of the passivating films after adding the Ce compounds and anticorrosive performance is improved.     

不同钝化剂处理下镉和铅在土壤-杭白菊体系中富集迁移特性及菊花品质的变化

为综合评价生物质炭、调理剂和腐殖酸3种不同钝化剂对杭白菊镉（Cd）和铅（Pb）含量降解的影响,通过土壤盆栽实验研究了钝化剂处理下Cd和Pb在2种土壤-杭白菊体系中的富集迁移特性及菊花品质的变化。结果表明：在2种不同程度Cd和Pb污染土壤中添加3种钝化剂杭白菊整体对Cd富集系数均降低,其中添加生物质炭降幅最显著（54.70%、72.27%）;添加生物质炭相较于其它2种钝化剂对抑制Cd和Pb在茎-花间的迁移以及菊花茶茶渣中的残留量效果均最显著,茶渣中两者的残留在土壤1中分别下降48.91%、56.10%,土壤2中分别下降62.77%、86.00%。土壤1中添加生物质炭花中绿原酸、木犀草苷和异绿原酸A含量与对照相比增幅最显著,分别为154.93%、77.11%和99.09%;而土壤2中添加3种钝化剂,3种有效成分含量均极显著提高。综合分析,生物质炭对Cd和Pb在杭白菊植株中的降解,降低菊花茶中的残留以及提升菊花品质方面效果最佳,可作为杭白菊种植区土壤钝化修复首选材料。     

Ni-Cr-Fe系高温合金的渗氮工艺研究

对Inconel 718、GH4145、R26三种不同成分的高温合金进行了渗氮处理,采用金相法和硬度梯度法研究了不同化学成分和不同工艺对气体渗氮层深度的影响.结果表明,随着合金中镍含量的增加,渗氮层深度减小,减少幅度达到50%～100%.     

化学清洗后的钝化处理

介绍化工设备在化学清洗后进行钝化处理的必要性以及相关的钝化处理技术的原理、钝化剂性能、处理工艺。并指出使用环保型的钝化剂是今后钝化工艺的发展方向。     

锌铁合金电镀层的油光黑亮钝化工艺

介绍锌铁合金电镀层的黑钝化工艺,分析影响钝化质量的诸因素,指出钝化膜耐蚀性能优异之所在。     

二步钝化法处理黄铜制品的研究

介绍了不同处理方式对黄铜制品经二步钝化法处理后形成钝化膜外观，色泽及结构的影响，并通过扫描电镜对钝化膜结构进行了表征，试验结果表明，黄铜制品在酸蚀后经1号钝化液钝化15s，2号钝化液钝化30s所形成的钝化膜结构致密、性能优良。     

一种增强镀锌黑色钝化膜附着力的改良工艺

度针对镀锌层黑色钝化膜干燥之前柔软易脱落等问题，提出了一种基于硫酸盐－磷酸盐型的银盐黑色钝化工艺，采用单因素试验对黑色钝化溶液组成，操作条件进行了优化，并用SEM、NSS等方法评价了黑色钝化膜的性能，研究结果表明，改良后的黑色钝化工艺完全能够满足镀锌件（特别是滚镀件）黑色钝化的实际生产需要。     

聚酰亚胺与溅射SiO_2双层介质的钝化技术

本文介绍我们采用聚酰亚胺与溅射SiO_2双层介质进行表面钝化的研究.这种技术克服了单一聚酰亚胺介质层进行表面钝化时难于微细加工的缺点,以其特有的流平性、与金属层良好的粘附性而成为集成电路表面钝化及多层布线的新途径.     

FA0.88Cs0.12PbI3−x(PF6)x Interlayer Formed by Ion Exchange Reaction between Perovskite and Hole Transporting Layer for Improving Photovoltaic Performance and Stability

Interface engineering to form an interlayer via ion exchange reaction is reported. A FA_0.88Cs_0.12PbI₃ formamidinium (FA) perovskite layer is first prepared, then FAPF₆ solution with different concentrations is spin‐coated on top of the perovskite film, which leads to a partial substitution of iodide by PF₆^? ion. The second phase with nominal composition of FA_0.88Cs_0.12PbI_3?x(PF₆)_x is grown at the grain boundary, which has island morphology and its size depends on the FAPF₆ solution concentration. The lattice is expanded and bandgap is reduced due to inclusion of larger PF₆^? ions. The power conversion efficiency (PCE) is significantly enhanced from 17.8% to 19.3% as a consequence of improved fill factor and open‐circuit voltage (V_oc). In addition, current–voltage hysteresis is reduced. Post‐treatment with FAPF₆ reduces defect density and enhances carrier lifetime, which is responsible for the improved photovoltaic performance and reduced hysteresis. The unencapsulated device with post‐treated perovskite film demonstrates better stability than the pristine perovskite, where the initial PCE retains over 80% after 528 h exposure under relative humidity of around 50–70% in the dark and 92% after 360 h under one sun illumination.