全文获取类型
收费全文 | 73篇 |
免费 | 6篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 1篇 |
综合类 | 1篇 |
化学工业 | 15篇 |
金属工艺 | 6篇 |
建筑科学 | 1篇 |
能源动力 | 18篇 |
无线电 | 17篇 |
一般工业技术 | 26篇 |
冶金工业 | 2篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 9篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 5篇 |
2013年 | 4篇 |
2012年 | 7篇 |
2011年 | 13篇 |
2010年 | 4篇 |
2009年 | 2篇 |
2008年 | 1篇 |
2006年 | 1篇 |
2004年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1985年 | 1篇 |
排序方式: 共有87条查询结果,搜索用时 15 毫秒
1.
David J. Lawrence Brianna L. Smith Cameron D. Collard Keyton A. Elliott Kyle L. Fakhoury Jeffery D. Mangold Anna N. Soyka 《International Journal of Hydrogen Energy》2021,46(2):1642-1655
Monolithically-integrated tandem photoanodes were fabricated on substrates consisting of epitaxial n-GaAs1-xPx (x ? 0.32) grown on n+-GaAs wafers. A p+-n junction photovoltaic (PV) cell was first formed by zinc diffusion into the n-GaAs0.68P0.32 from a deposited ZnO coating. After diffusion the ZnO serves as a transparent electrical contact to the resulting p+-GaAs0.68P0.32 surface layer. Transparent, conducting SnO2:F provides chemical and mechanical protection for the ZnO and the underlying PV cell, and it electrically connects this cell to a top BiVO4 photocatalyst layer. In some photoanodes, a WO3 thin film was interposed between the SnO2:F and BiVO4. All oxide coatings were produced by ultrasonic spray pyrolysis except WO3, which was spin coated. Unassisted (unbiased) solar water splitting was achieved, with a solar-to-hydrogen efficiency approaching 2%, without addition of any co-catalyst to the BiVO4 surface. This work can provide insights to other researchers regarding scalable, low cost approaches for the planar monolithic integration of oxide photoanode materials with PV cells to create new tandem devices. 相似文献
2.
3.
4.
《International Journal of Hydrogen Energy》2019,44(33):17611-17621
Constructing heterojunction was an efficient way to promote photoelectrochemical (PEC) water splitting performance of TiO2-based nano-photoanode. In this work, we demonstrated the feasible preparation of oxygen vacancies-induced In2O3 (In2O3-x) nanorods/black Si-doped TiO2 (Ti–Si–O) nanotubes heterojunction photoanode for enhanced PEC water splitting. Black Ti–Si–O nanotubes were fabricated through Zn reduction of the as-annealed Ti–Si–O nanotubes, followed by In2O3-x nanorods coupling by a facile electrodepositing and Ar heat treatment. Solar to hydrogen conversion efficiency of the heterojunction photoanode reached as high as 1.96%, which was almost 10 times that of undoped TiO2. The improved PEC properties were mainly attributed to co-doping effects of Si and Ti3+/oxygen vacancy as well as In2O3-x decoration, which resulted in enhanced optical absorption and facilitated separation-transport process of photogenerated charge carriers. Charge transfer process in the composite system and hydrogen production mechanism were proposed. This work will facilitate designing TiO2-based nano-photoanodes for promoting water splitting by integrating with elements doping, oxygen vacancies self-doping and semiconductors coupling. 相似文献
5.
A versatile phase transformation strategy was proposed to synthesize novel BiVO4 nanosheets (NSs)@WO3 nanorod (NR) and nanoplate (NP) arrays films. The strategy was carried out by following a three-step hydrothermal process (WO3→WO3/Bi2WO6→WO3/BiVO4). According to the characterization results, plenty of BiVO4 NSs grew well on the surface of WO3 NR and NP arrays films, thus forming the WO3/BiVO4 heterojunction structure. The prepared WO3/BiVO4 heterojunction films were used as the photoanodes for the photoelectrochemical (PEC) water splitting. As indicated by the results, the photoanodes exhibited an excellent PEC activity. The photocurrent densities of the WO3/BiVO4 NR and NP photoanodes at 1.23 V (vs RHE) without cocatalyst under visible light illumination reached up to about 1.56 and 1.20 mA/cmbrespectively. 相似文献
6.
Photoelectrochemical decomposition of bio-related compounds such as amino acids was investigated with a biophotochemical cell comprising a mesoporous TiO2 thin film photoanode and an O2-reducing cathode. It was concluded that a kind of Schottky junction formed at the surface of the TiO2 (called as liquid junction) induced the photodecomposition followed by generation of photocurrent/photovoltage. Complete photodecomposition was investigated by the CO2 formation yield. The photocurrent-photovoltage (J-V) characteristics of amino acids and other typical bio-related compounds were investigated, and the short circuit photocurrent (Jsc), open circuit photovoltage (Voc), and Fill factor (ff) were exhibited. Effect of pH on the photodecomposition of phenylalanine and cysteine were studied; for cysteine alkaline conditions gave a high efficiency, which was interpreted by the high electron-donating ability of the dissociated -S− group. The incident light-to-current conversion efficiency (IPCE) of cysteine was 25% at 350 nm. It was for the first time shown that organic acids gave high internal quantum efficiency (η′) over 8 (=800%) in the photodecomposition; for oxalic acid it was 9.3 (=930%) and for butyric acid 8.2. The alternating current impedance spectroscopy of glycine showed that the cell performance is determined by the chemical reactions at TiO2 or Pt electrodes. 相似文献
7.
The preparation of titania nanotubes and its application in flexible dye-sensitized solar cells 总被引:1,自引:0,他引:1
Yaoming Xiao Gentian Yue Guixiang Xie Jianming Lin Miaoliang Huang 《Electrochimica acta》2010,55(15):4573-627
Anatase titania nanotube (TNT) is prepared by two-steps hydrothermal growth method. Using the TNTs and titania particles (P25), a highly stable and uniform titania colloid without any sedimentation in 180 days is prepared by hydrothermal treatment. Based on the titania colloid, a flexible dye-sensitized solar cell (DSSC) is fabricated at low temperature. The influence of preparation conditions on the properties of TNTs and titania colloid is discussed by transmitting electron microscopy, scanning electron microscopy, selected area electron diffraction, X-ray diffraction, UV-vis absorption spectra, and Brunauer-Emmet-Teller surface area measurements. Under an optimized condition, a flexible DSSC with light-to-electric energy conversion efficiency of 4.0% is achieved under a simulated solar light irradiation of 100 mW cm−2 (AM 1.5). 相似文献
8.
Utilization of visible light is of crucial importance for exploiting efficient semiconductor catalysts for solar water splitting. In this study, an advanced ion implantation method was utilized to dope Cu ions into ZnO nanorod arrays for photoelectrochemical water splitting in visible light. X-ray diffraction (XRD) and X-ray photo-electron spectroscopy (XPS) results revealed that Cu^+ together with a small amount of Cu^2+ were highly dispersed within the ZnO nanorod arrays. The Cu ion doped ZnO nanorod arrays displayed extended optical absorption and enhanced photoelectrochemical performance under visible light illumination (A 〉 420 nm). A considerable photocurrent density of 18 μA/cm^2 at 0.8 V (vs. a saturated calomel electrode) was achieved, which was about 11 times higher than that of undoped ZnO nanorod arrays. This study proposes that ion implantation could be an effective approach for developing novel visible-light-driven photocatalytic materials for water splitting. 相似文献
9.
Dye-sensitized solar cells (DSSCs) based on nanocrystalline semiconductors such as TiO2 are of great interest as an alternative to the conventional solar cells because of their high performance, low-cost production, and environmental advantages. The DSSCs consist of dye molecule coated wide bandgap semiconductor layer, electrolyte, and transparent conducting oxide (TCO) film. When the DSSCs are exposed to solar light, an incident photon creates a bound electron-hole pair in dye sensitizers. Electrons then flow into the oxide nanoparticle anode due to a difference in the energy levels. On the other hand, holes move to the counter electrode through sequential redox reactions in the electrolyte. Therefore, the cell performance is influenced by parameters such as the morphology and optical properties of nanocrystalline oxide films, the electrochemical characteristics of redox electrolytes, and the photochemical properties of molecular sensitizers. In this article, we review the major components of DSSCs such as the oxide semiconductor film, sensitizing dyes, electrolytes, and TCO and discuss their progress to maximize light harvesting and charge injection efficacy. Their electrical, optical, and chemical properties are well correlated to optimize the light harvesting and charge injection of DSSCs. We have also shown recent efforts to improve the energy conversion efficiency, long term stability, sustainability and affordability by modifying or revolutionizing the components of DSSCs. This includes a prospect on the potential commercialization of DSSCs. 相似文献
10.