化学交联聚酰亚胺隔膜增强锂离子电池性能研究

隔膜作为锂离子电池的重要组成部分,用于阻隔阴极和阳极直接接触,同时为锂离子在电极间的传输提供有效通道。聚酰亚胺隔膜因其具有充放电循环寿命长、机械强度适中、良好的电绝缘性能以及自熄能力等优点,而受到广泛关注。以对苯二甲胺作为交联剂,将聚酰亚胺隔膜进行化学交联,研究了交联时间与隔膜形貌、结构及性能之间的构效关系。随着交联时间的增加,隔膜的孔隙率和吸液率逐渐降低,电解液接触角和机械强度逐渐增大。电化学测试表明,随着交联时间的增加,隔膜的本体阻抗逐渐增大,进而离子电导率逐渐降低,而交联隔膜的界面阻抗均远小于未交联隔膜,且交联隔膜的电化学窗口也均大于未交联隔膜。通过组装半电池测试发现,交联隔膜所组装电池的倍率性能和循环性能均优于未交联隔膜,当交联时间为48 h时,电池性能表现最优,循环100次以后,放电比容量为130.2 mA·h/g,容量保留率为91.1%。     

碱性蓄电池隔膜用非织造布探析

介绍了碱性蓄电池隔膜用非织造布在电池生产中的作用和要求,对碱性蓄电池隔膜用非织造布的纤维原料、生产方法进行了比较分析。     

Approximately counting locally-optimal structures

In general, constructing a locally-optimal structure is a little harder than constructing an arbitrary structure, but significantly easier than constructing a globally-optimal structure. A similar situation arises in listing. In counting, most problems are #P-complete, but in approximate counting we observe an interesting reversal of the pattern. Assuming that #BIS is not equivalent to #SAT under AP-reductions, we show that counting maximal independent sets in bipartite graphs is harder than counting maximum independent sets. Motivated by this, we show that various counting problems involving minimal separators are #SAT-hard to approximate. These problems have applications for constructing triangulations and phylogenetic trees.     

提高汽车蓄电池性能的探讨

为提高汽车蓄电池性能，通过对比试验的方法，对偏极耳（极耳偏离板栅中心线，相对于传统的边极耳而言）矮形板栅、PE隔板、紧装配进行了探讨和分析，认为偏极耳矮形板栅、使用PE隔板、紧装配的蓄电池能提高综合性能，同时指出了偏极耳板栅适用于蓄电池1×6单格排列，而不适用于2×3排列。     

分离器——一种新型的物料分离装置

该分离器是用于粉料或物料的分离 ,用于储料罐、料斗、混料器及挤出机等设备自动上料分离粒状物料或粉状物料。根据操作条件和输送物料的情况不同 ,分离器可配备不同的过滤器和排放装置。通过 6个月试运行实验 ,确认了该装置应用的可行性     

Supercritical carbon dioxide extraction of lithium-ion battery electrolytes

Two different separator materials (polyethylene fleece – Freudenberg 2190 and porous glass fiber – Whatman^® GF/D) and two different lithium-ion battery electrolytes have been investigated regarding their behavior in an autoclave extraction with supercritical helium head pressure carbon dioxide (sc HHPCO₂). Mixtures of dimethyl carbonate (DMC)/ethylene carbonate (EC) and ethylmethyl carbonate (EMC)/EC, each with 1 mol/L LiPF₆ were used.In addition to these proof of principle experiments, the developed extraction method was further applied to real battery samples. Commercial 18650 cells (after formation and aging) were opened and the jelly roll was extracted with sc HHPCO₂. Extracts were analyzed with gas and ion chromatography (GC, IC). Recovery rates and extract compositions strongly depend on the material of which the electrolyte is extracted. Further structure determination of electrolyte aging products was performed with different ionization modes in GC–mass spectrometry (GC–MS) experiments. Diethyl carbonate (DEC), dimethyl-2,5-dioxahexane dicarboxylate (DMDOHC), ethylmethyl-2,5-dioxahexane dicarboxylate (EMDOHC) and diethyl-2,5-dioxahexane dicarboxylate (DEDOHC) are aging products of electrolyte degradation which were successfully extracted and identified. Their concentrations correlate with solid electrolyte interphase (SEI) growth on the negative electrode which was investigated with scanning electron microscopy (SEM).     

新型锂电池隔膜材料研究进展

锂电池在电子储能领域的应用越来越广泛,市场需求量越来越大。隔膜作为锂电池的核心部件,其性能直接关系到锂电池的电化学性能和安全性。本文介绍了间位芳纶（PMIA）、纤维素、聚偏氟乙烯（PVDF）、聚酰亚胺（PI）、聚丙烯腈（PAN）和聚对苯二甲酸乙二醇酯（PET）基新型隔膜的制备方法,总结了以这些隔膜材料为基础改性的复合隔膜的研究成果,探讨了各类新型隔膜的优缺点。最后,提出了锂电池隔膜面临的挑战及解决方法,并对锂电池隔膜未来的发展方向进行了展望。     

水热合成勃姆石纳米棒及其改性复合膜

商用锂离子电池隔膜遭受高温时,会发生热收缩现象,通过涂覆无机颗粒对隔膜进行改性,可以有效地提高隔膜的热稳定性能,从而提高锂离子电池的安全性能,而勃姆石纳米棒具有耐热性好和弹性模量大等特点,适用于涂覆改性隔膜.本研究利用AlCl3和NaOH与NH4 OH混合沉淀剂,通过水热法制备了勃姆石纳米棒,并使用线棒涂布工艺制备了涂...     

SLon脉动与振动高梯度磁选机新进展

脉动与振动高梯度磁选是细粒弱磁性矿物的高效选矿技术。介绍了高梯度磁选机的有关基本理论及SLon周期式和连续式脉动高梯度磁选机、SLon周期式和连续式振动高梯度磁选机的发展现状。并对SLon-2500立环脉动高梯度磁选机和SLon—1000立环振动高梯度磁选机新设备作了简介。目前,SLon型高梯度磁选机已有500多台在国内外使用,显著地提高了高梯度磁选技术水平。     

稳流系统的动态分析

回旋加速器、静电加速器及同位素电磁分离器等物理装置,其磁场是由磁场电流稳定系统供电及稳定的。本文叙述电磁分离器的稳流系统的瞬变过程、动态品质的两个指标(σ_(max)、t_p)。指出在稳态电流准确度较高(2×10~(-4))时系统是一个稳定的但又是一个欠阻尼的系统。在串入一个比例—积分校正环节(PI环节)后,系统的动态品质得到很大的改善,同时也提高了稳态电流准确度。