Effects of interphase on tensile strength of polymer/CNT nanocomposites by Kelly–Tyson theory

The micromechanics models for composites usually underpredict the tensile strength of polymer nanocomposites. This paper establishes a simple model based on Kelly–Tyson theory for tensile strength of polymer/CNT nanocomposites assuming the effect of interphase between polymer and CNT. In addition, Pukanszky model is joined with the suggested model to calculate the interfacial shear strength (τ), interphase strength (σ_i) and critical length of CNT (L_c).The proposed approach is applied to calculate τ, σ_i and L_c for various samples from recent literature. It is revealed that the experimental data are well fitted to calculations by new model which confirm the important effect of interphase on the properties of nanocomposites. Moreover, the derived equations demonstrate that dissimilar correlations are found between τ and B (from Pukanszky model) as well as L_c and B. It is shown that a large B value obtained by strong interfacial adhesion between polymer and CNT is adequate to reduce L_c in polymer/CNT nanocomposites.     

CVD金刚石工具膜生长特征SEM观察

本文用不热形变栅状直丝化学气相沉积（ＣＶＤ）法生长金刚石膜，在Ｓｉ及ＷＣ－Ｃｏ硬质合金衬底上金刚石膜晶面显露规律随衬底温度和甲烷浓度而异，经适当表面处理及选择合适的工艺条件，当生长初期衬底上就呈现出良好晶形的沉积膜，衬底与膜之间的粘结力能得到提高。Ｒａｍａｎ谱分析表明此膜仅具有特征金刚石１３３２ｃｍ￣（－１）峰，通过ＳＥＭ观察揭示出盒刚石膜可在表面、侧面及棱上生长，并与衬底有良好的联结。     

Ionic liquids as electrolytes

Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors.     

空间直线拟合的一种方法

首先介绍数据拟合的最小二乘法,提出空间直线拟合的最小二乘法。理论分析和数值实验表明,新方法对解决空间直线的数据拟合问题很有效。     

拉压变形对B(N)掺杂碳纳米管Al吸附性能的影响

为了研究(5,5)碳纳米管的B(N)环状掺杂效应,以及拉压变形对B(N)环状掺杂碳纳米管Al吸附性能的影响,采用基于密度泛函理论的平面波赝势和广义梯度近似方法,对B(N)环状掺杂碳纳米管Al吸附模型进行了几何优化,计算了B(N)环状掺杂碳纳米管的形成能,并确定了Al原子的最稳定吸附位置.结果表明,B(N)环状掺杂(5,5)碳纳米管的结构较为稳定.B(N)环状掺杂可以增加碳纳米管与Al之间的吸附能;一定范围内的拉伸和压缩变形则会降低碳纳米管与Al之间的大部分吸附能.     

大直径直缝焊管生产工艺

介绍了大直径直缝焊管生产的UOE工艺、辊弯工艺、改进式模压工艺和改进式折弯工艺。不同的成型工艺，其装备、规格范围、生产规模和基本建设投资均不同，但产品质量相当。大直径直缝焊管主要用于管线建设，市场具有阶段起伏性，我国在机组选型时应结合国情，综合考虑。     

基于无瞬心包络法的砂轮磨削圆弧直槽的研究

基于无瞬心包络法,提出一种使用CBN圆弧砂轮精确磨削圆弧直槽的方法。从砂轮圆弧母面与工件直槽圆弧面的空间啮合关系出发,采用无瞬心包络法,以两曲面间接触点法矢量方向相同建立啮合方程,通过啮合方程求解得到砂轮初始安装角,以磨削后的工件端截面圆弧圆度和半径误差满足精度要求为目标,设计砂轮安装角调整和控制流程,确定砂轮最终的安装位置和安装角。仿真和实际加工结果表明用圆弧砂轮磨削圆弧直槽工件,通过调整砂轮安装位置和安装角可以控制磨削精度,砂轮不用修形也能实现精确磨削。该方法实现用一种砂轮磨削不同尺寸的工件,减少砂轮的种类,提高生产效率,为注塑机螺杆转子的高效磨削提供了一种可行的方法。     

ERW直缝焊管内毛刺清除装置的发展

简述了ERW直缝焊管清除内毛刺的方法及设备构成;重点介绍了内毛刺清除装置尤其是刀架的发展进程,在使用过程中经常会发生的问题及消除方法;同时还指出了未来发展方向。     

Straight‐Line Tracking Control of an Agricultural Vehicle with Finite‐Time Control Technique

For the agricultural vehicle straight‐line tracking system, three control algorithms based upon the finite‐time control technique have been proposed to force the vehicle to track a straight line. Without considering the lumped disturbance, a backstepping‐like finite‐time state‐feedback controller is first developed. On this basis, an adaptive state‐feedback controller in conjunction with integral sliding mode is further developed in the presence of the lumped disturbance. Finally, a sliding mode disturbance observer is given to estimate the lumped disturbance, and the composite control scheme is presented. Under the composite controller, the lumped disturbance can be compensated and thus the disturbance rejection property has been significantly improved. Simulation results verify the proposed control algorithms.     

使用非均匀量化的Hough空间进行直线段检测

分析图像中最近邻直线间距离和夹角的非均匀性,得到这两个参数与线段方向和长度的相关关系,并由此提出了非均匀量化Hough空间的直线检测算法NUHT (Nonuniform Hough Transform).实验结果表明,NUHT在不降低运算效率的情况下,有2倍于标准Hough变换SHT (Standard Hough Transform)的直线段检测能力,同时误报率低于SHT的1/2.