Phase behavior of ternary blends containing dimethylpolycarbonate,tetramethylpolycarbonate and poly[styrene‐co‐(methyl methacrylate)] copolymers (or polystyrene)

The miscibility and phase behavior of ternary blends containing dimethylpolycarbonate (DMPC), tetramethylpolycarbonate (TMPC) and poly[styrene‐co‐(methyl methacrylate)] copolymer (SMMA) have been explored. Ternary blends containing polystyrene (PS) instead of SMMA were also examined. Blends of DMPC with SMMA copolymers (or PS) did not form miscible blends regardless of methyl methacrylate (MMA) content in copolymers. However, DMPC blends with SMMA (or PS) blends become miscible by adding TMPC. The miscible region of ternary blends is compared with the previously determined miscibility region of binary blends having the same chemical components and compositions. The region where the ternary blends are miscible is much narrower than that of binary blends. Based on lattice fluid theory, the observed phase behavior of ternary blends was analyzed. Even though the term representing the Gibbs free energy change of mixing for certain ternary blends had a negative value, blends were immiscible. It was revealed that a negative value of the Gibbs free energy change of mixing was not a sufficient condition for miscible ternary blends because of the asymmetry in the binary interactions involved in ternary blends. Copyright © 2004 Society of Chemical Industry     

三元吸收制冷的研究进展

氨—水和溴化锂—水是目前使用最广泛的两种二元吸收工质对，但各有缺陷，为此人们希望采用三元吸收工质克服这两种二元工质对的不足。国外许多学者对三元吸收制冷尤其是氨—水—溴化锂三元吸收制冷作了大量理论和试验研究，国内未见这方面的文献发表，该文从物性和循环两方面对这些研究作简单介绍，并对三元吸收制冷研究简单展望。     

Composition Range of Amorphous Mg-Ni-Y Alloys

Based on the thermodynamic point of view, a method for predication of the composition range of amorphous ter-nary alloys was proposed. The composition range of amorphous ternary alloys is determined by the comparison of the excess free energy of the amorphous alloy and the free energy of competing crystalline states. The free energy is extrapolated from the data of three binary alloys by using Toop‘s model. The method was applied to predict the composition range of amor-phous Mg-Ni-Y alloys. The theoretical results are in good agreement with the available experimental results. It indicates that the present method can be used to predict the composition range for amorphous ternary alloys.     

Decreasing miscibility with greater heterogeneity in ternary polymer blend: poly(cyclohexyl methacrylate), poly(α‐methyl styrene) and poly(4‐methyl styrene)

A ternary blend system comprising poly(cyclohexyl methacrylate) (PCHMA), poly(α‐methyl styrene) (PαMS) and poly(4‐methyl styrene) (P4MS) was investigated by thermal analysis, optical and scanning electron microscopy. Ternary phase behaviour was compared with the behaviour for the three constituent binary pairs. This study showed that the ternary blends of PCHMA/PαMS/P4MS in most compositions were miscible, with an apparent glass transition temperature (T_g) and distinct cloud‐point transitions, which were located at lower temperatures than their binary counterparts. However, in a closed‐loop range of compositions roughly near the centre of the triangular phase diagram, some ternary blends displayed phase separation with heterogeneity domains of about 1 µm. Therefore, it is properly concluded that ternary PCHMA/PαMS/P4M is partially miscible with a small closed‐loop immisciblity range, even though all the constituent binary pairs are fully miscible. Thermodynamic backgrounds leading to decreased miscibility and greater heterogeneity in a ternary polymer system in comparison with the binary counterparts are discussed. © 2003 Society of Chemical Industry     

Application d'une méthodologie expérimentale à l'étude du diagramme ternaire d'un gel

Nous avons montré sur l'exemple d'un gel, mélange de trois constituants (C12–C15 Alcohols Benzoate, Cyclomethicone et Ethylene Vinyl Acetate Copolymer) qu'il est possible d'optimiser une formulation en un nombre preécis d'essais en faisant appel à une stratégic expérimentale optimale. Le gel avait déjàétéétudié par Chang,¹ mais par approches successives.
Nous avons utlisé les matrices d'expériences développées dans le cas des mélanges par Scheffe sous le nom de 'reseaux-simplex'. Prévoyant des intéractions de 2éme ordre entre les constituants nous avons retenu le modéle appelé'cubique réduit'. Cette approche permet l'exploration systémique de tout le domaine.
Les réponses étudiées sont la compatibilité (gel homogène ou non), la consistance, la blancheur et le coût. Le meilleur gel étant celui qui se rapproche le plus de la vaseline.
A partir des résultats, nous avons tracé des courbes d'isoréponse en blancheur, consistance et coût. La superposition des diagrammes conduit à la détermination d'une zone où les réponses sont optimales.
En ajoutant la réponse supplémentaire: 'facilité d'étalement sur la peau'on arrive au meilleur gel avec un nombre réduit d'essais.
La même méthode s'appliquerait à des mélanges de plus de trois constituants.
Study of a ternary diagram gel according to a methodology of experimental research     

一类三元线性分组码的译码

Ｐｌｅｓｓ［１］证明了三元（１２，６，６）Ｇｏｌａｙ码具有一种双层结构，并据此给出了该码的快速硬判决译码算法。本文推广了Ｇｏｌａｙ码的Ｐｌｅｓｓ结构，给出了由三元（ｎ，ｋ，ｄ）线性分组码构造的三元（３，ｎ＋ｋ，≥ｍｉｎ（ｎ，２ｄ，６））线性分组码，其中包括（１２，６，６）Ｇｏｌａｙ码和（１８，９，６）码，并以三元（１８，９，６）码为例给出了这类码的最大似然软判决译码算法。     

燃烧合成三元碳化合物Ti2AlC1-x

采用Ti，Al和C元素粉末为反应物原料，通过燃烧合成法首次成功地制备出了单相三元碳化合物Ti2AlC1-x。实验结果表明：若以“理想”晶体结构化学式Ti2AlC化学计量比为起始反应原料配比，燃烧产物主晶相为Ti2AlC2；以缺碳的非化学计量比(Ti2AlC1-x)为反应原料配比，即Ti：Al：C=3：1．5：1=2：1：0．7(摩尔比)，得到单相的燃烧产物Ti2AlC1-x。从热力学原理的角度探讨了不同原料摩尔配比对燃烧产物相组成的影响机理。     

强化三元混合熔盐的传热性能的实验研究

太阳能发电技术中传热性能的优劣影响着太阳能的利用程度。选用石墨作为强化相变材料传热性能的添加剂与三元混合熔盐（K₂CO₃-NaCl-Li₂CO₃）按照石墨质量分数为5%、10%、15%进行混合制备,使用TC3000通用型导热系数测试仪测定16种试样的导热系数。并测试经历300次循环储能、释能实验试样的导热系数循环稳定性。实验结果表明：添加石墨后的混合相变材料导热系数最高可提升至原混合材料的3.38倍,当石墨的质量分数为15%时,混合相变材料的导热系数最大。在经历300次储能、释能实验后,材料的导热系数基本保持稳定,变化浮动不高于15%。石墨作为强化材料的添加剂,可有效提升强化材料的传热性能,具有实际工程的应用价值。     

Bi-Pb-Tl三元系相图

用室温、高温X射线衍射及淬火的方法,测定了Bi-Pb-Tl三元系25℃的等温截面及该体系中的相结构。