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1.
《International Journal of Hydrogen Energy》2022,47(40):17737-17748
Due to problems such as pores on surface-treated coatings, the corrosion resistance of pure titanium bipolar plates for proton-exchange membrane fuel cells can be further improved by increasing the corrosion resistance of pure titanium by using differential speed-rolling (DSR); however, these materials have not yet reached the standard requirements of bipolar plates (corrosion current density icorr<103 nA·cm?2). In this work, the corrosion resistance of pure titanium was improved by optimizing the DSR process while the strength was maintained. The best corrosion resistance of the DSR pure titanium was achieved when the roller speed ratio was 2, while icorr was 429 nA·cm?2 in a solution of 0.5 M H2SO4 and 2 mg/L HF at room temperature. The formability of the DSR pure titanium for bipolar plates was verified. The optimal holding pressure range was 6.8–7.0 kN. 相似文献
2.
《Ceramics International》2022,48(18):25975-25983
This work reports the innovative development of a borosilicate glass/Al2O3 tape for LTCC applications using an eco-friendly aqueous tape casting slurry. Polyvinylpyrrolidone (PVP) and polyacrylic acid (PAA) were the respective dispersants, while carboxymethyl cellulose (CMC) and styrene acrylic emulsion (SA) were the respective binders. The results showed that PVP was more suitable than PAA as the dispersant for the aqueous casting slurry, and that 1.5 wt% PVP would achieve well dispersion of CABS glass/Al2O3 powder in the aqueous slurry. Moreover, a small amount of 2.0 wt% CMC binder could yield smooth CABS glass/Al2O3 tapes crack free. A high-quality CABS glass/Al2O3 tape with a smooth surface was made from an aqueous slurry containing 1.5 wt% PVP dispersant, 2.0 wt% CMC binder, and 2.0 wt% PEG-400 plasticizer. The density, tensile strength, and surface roughness of the green tape were 2.05 g/cm3, 0.87 MPa, and 148 nm, respectively. The resulting CABS glass/Al2O3 composites sintered at 875 °C exhibited a bulk density of 3.14 g/cm3, a dielectric constant of 8.09, a dielectric loss of 1.0 × 10?3, a flexural strength of 213 MPa, a thermal expansion coefficient of 5.30 ppm/°C, and a thermal conductivity of 3.2 W m?1 K?1, thus demonstrating its broad prospects in LTCC applications. 相似文献
3.
This study deals with the anodisation of titanium grade 2 in 0.5-M sulphuric acid using a pulsed signal in a unipolar regime. The electrical parameters investigated are voltage, frequency and duty cycle. The use of duty cycles with a high percentage of anodic polarisation (90%), combined with high frequencies (1000 Hz) and the higher voltage tested (220 V), favoured the establishment of a plasma regime involving strong dielectric discharges, allowing the growth of thicker oxides but with rough architecture. The corrosion resistance of the formed film has been characterised by potentiodynamic tests in 0.5-M NaBr for localised corrosion resistance and by immersion tests in 10% v/v sulphuric acid solution for a uniform corrosion assessment. Current–time curves, visual observations and electron microscope analysis (scanning electron microscopy, energy-dispersive X-ray spectroscopy) were the tools selected to provide a correlation between technological parameters and oxide growth mechanism. For localised and uniform corrosion, anodisation at 220 V with a high level of anodic polarisation (90%) and frequency (1000 Hz) was verified to be particularly advantageous. 相似文献
4.
《Ceramics International》2022,48(8):10733-10740
Multivalent ion-conducting ceramics are required for the manufacture of high-safety, high-capacity rechargeable batteries. However, the low ionic conductivity of solid electrolytes and discrepancies in the thermal expansion between the battery components limit their widespread application. Furthermore, anisotropic thermal expansion in crystals during battery manufacturing and the charge-discharge cycles causes the formation of microcracks, which degrade the battery performance. The physical properties of ceramic materials with anisotropic crystal structures can be modified by varying the crystallographic orientation of their grains. In this study, a co-precipitation approach was used to synthesize an Mg2+-conducting (Mg0.1Hf0.9)4/3.8Nb(PO4)3 solid electrolyte, and the grain orientation in the bulk sample was controlled using strong magnetic fields during the slip casting process. The results showed that inducing an orientation along the c-axis enhanced the apparent ionic conductivity of the bulk sample. It was also observed that (Mg0.1Hf0.9)4/3.8Nb(PO4)3 crystal has a negative volumetric thermal expansion despite a positive linear thermal expansion along its c-axis. By adjusting the c-axis orientation of the grains, (Mg0.1Hf0.9)4/3.8Nb(PO4)3 electrolytes with negative or positive linear thermal expansion coefficient have been produced. The findings of this study suggest that solid-electrolytes with negative, positive, or zero linear thermal expansion can be produced to create more compatible and higher-performance solid-state devices. 相似文献
5.
Waveguide configurations of hierarchical system are proposed as new microstructures for composites in absorbing enhancement. Supercritical fluid (SCF) one-pot exfoliation of layered graphite and manganese oxide mixing materials is developed to obtain a hierarchical system, containing graphene nanosheets (GNS) and exfoliated manganese oxides (EMO) in different sizes. Composites with GNS–EMO embedded in epoxy resin matrix are produced for a design of dielectric and magnetic loss integrated absorber. Volume fraction of GNS–EMO in composites is given for an optimal quantity of resin epoxy in fixation and formation. The effect of mixing ratios between electric and magnetic components is provided for the design of dielectric and magnetic loss integrated absorbers. Frequency shifting phenomena are revealed in the component adjusting course. Excluding the offsetting sizes, reflection loss of composites is enhanced as thickness increases. Synergistic effect of electric and magnetic coordinated materials demonstrates the superiority of micro-waveguide structures in GNS–EMO composite absorber. 相似文献
6.
The effect of Li2O on the crystallization properties of CaO-Al2O3-SiO2-Li2O-Ce2O3 slags was investigated. With increasing the Li2O content, LiAlO2 and CaCeAlO4 were the main crystalline phases. LiAlO2 formed for the charge compensating of Li+ ions to [AlO45?]-tetrahedrons, and CaCeAlO4 formed as a result of the charge balance of Ce3+ ions, Ca2+ ions, and [AlO69?]-octahedrons. Increasing the content of Li2O to 10%, the crystallization temperature was the highest, and the incubation time was the shortest. The crystallization ability was strong due to the three factors of strengthening the interaction between ions and ion groups, decreasing the polymerization degree, and increasing the melting temperature. Further increasing the content of Li2O, the crystallization performance was obviously suppressed, because the melting temperature and the force between the cations and the anion groups decreased. 相似文献
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9.
Sonika Sahu Mohd. Zahid Ansari Dehi Pada Mondal Chongdu Cho 《Materials Science & Technology》2019,35(7):856-864
In this paper, cenosphere particles embedded in AA2014 aluminium matrix are used to fabricate syntactic foam by stir casting method. The particle size is about 100?µm and foam density is about 1990?kg?m?3. Compression tests at strain rate 0.001/s are performed on foam samples to characterise their mechanical properties which are then used in numerical analysis on commercial finite element analysis software ABAQUS/CAE with isotropic elastic-plastic material model. Experimental and numerical results show good conformity in deformation behaviour with elastic and plateau zones showing average deviations less than 5% and 20%, respectively. Foams showed high yield stress and energy absorption capabilities that can be useful in making blast and impact resistant structures. 相似文献
10.