新型Al/Mo底电极的顶发射有机发光二极管性能研究

提出了一种新型底电极结构,使用铝钼双层薄膜作为顶发射有机发光二极管的底电极。同时分别从底电极结构、顶电极结构、空穴注入以及出射光谱等方面对器件性能进行分析和优化,最终得到的器件电流效率达到6Cd/A以上,比优化前的器件效率提高了5倍以上,加强了对TEOLED器件的性能影响因素的理解。同时也比Mo作为底电极时的器件性能实现了提高,展示了此电极结构在顶发射OLED中的应用潜力,为下一步在硅基OLED显示器件中的应用打下基础。     

基于Alq3光耦合层的新型顶发射蓝光有机电致发光器件

研制了一种结构为Ag/Glass/ITO/TAPC/mCP/mCP∶Firpic/TPBi/LiF/Al/Ag/Alq₃的顶发射有机电致发光器件,通过在ITO玻璃衬底背面生长一层Ag反射膜,使器件发出的蓝光被反射膜反射到顶电极出射。利用顶电极表面的Alq₃光耦合层有效地提升了金属复合阴极的透射率,降低了器件的微腔效应。实验结果表明,当光耦合层厚度为30nm时,获得了最大电流效率和最大亮度分别为8.91cd/A和5758cd/m²的蓝光顶发射有机电致发光器件(TEOLED);同时,在10V电压下,其色坐标为(0.157,0.320),当亮度从1cd/m²变化到5000cd/m²时,其色坐标仅漂移(0.002,0.010),表现出良好的色稳定性。     

具有微腔结构的有机顶发射电致发光器件的光谱分析

摘要: 制做了具有微腔结构的蓝色和白色有机顶发射电致发光器件。利用TBADN:3%DSAPh和Alq3:DCJTB/TBADN:TBPe/Alq3:C545材料为发光层,在玻璃基片上,依次制备薄膜：Ag为阳极反射层, CuPc作为空穴注入层,NPB作为空穴传输层,ITO为光程调节层; Al/Ag作为半透明阴极,电极的透射率在30%左右。通过改变ITO层的厚度,TBADN:3%DSAPh器件获得了深蓝色发光光谱,色坐标为(0.141, 0.049),半高宽为17nm发光光谱,实现了窄带发射,Alq3:DCJTB/TBADN:TBPe/Alq3:C545器件得到了不同颜色（红、蓝、绿）的发光光谱,实现了对光谱的调节作用。文章对微腔顶发射器件的发射强度和发光光谱半高宽的结果进行了分析。     

Organic light-emitting diodes on shape memory polymer substrates for wearable electronics

Green electrophosphorescent organic light-emitting diodes (OLEDs) with inverted top-emitting structures are demonstrated on bio-compatible shape memory polymer (SMP) substrates for wearable electronic applications. The combination of the unique properties of SMP substrates with the light-emitting properties of OLEDs pave to the way for new applications, including conformable smart skin devices, minimally invasive biomedical devices, and flexible lighting/display technologies. In this work, SMPs were designed to exhibit a considerable drop in modulus when a thermal stimulus is applied, allowing the devices to bend and conform to new shapes when its glass transition temperature is reached. These SMP substrates were synthesized using 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (TATATO), trimethylolpropane tris(3-mercaptopropionate) (TMTMP), and tricyclo[5.2.1.0^2,6]decanedimethanol diacrylate (TCMDA), and show a low glass transition temperature of 43 °C, as measured using dynamic mechanical analysis (DMA). The OLEDs fabricated on these substrates exhibit high performance with a maximum efficacy of 33 cd/A measured at a luminance of 1000 cd/m², and a peak luminance of over 30,000 cd/m².     

基于PEN柔性衬底的顶发射微腔OLED性能研究

设计了结构为Ag/MoOx空穴注入层(HIL)/有机层/LiF/Al/Ag/Alq3的柔性有机电致发光器件(FOLED),研究通过改变HIL层的厚度改变腔长实现对微腔效应的调节,制备了性能优化的微腔FOLED。通过器件性能的对比,得到了可用Ag作为反射阳极的顶发射微腔FOLED全彩显示器件优化结构,即蓝、绿和红FOLED对应的优化HIL层厚度分别为100nm、120nm和160nm。     

Low Temperature DC Sputtering Deposition on Indium-Tin Oxide Film and Its Application to Inverted Top-emitting Organic Light-emitting Diodes

Indium tin oxide （ITO） ultrathin films were prepared on glass substrate by DC （direct current） magnetron sputtering technique with the assistance of H2O vapor to avoid potential surface damage. The film properties were characterized by X-ray diffraction （XRD） technique, four-point probe method and spectrophotometer. The results show that the deposited ITO film with introduced H2O during sputtering process was almost amorphous. The average visible light transmission of 100 nm ITO film was around 85% and square resistivity was below 80 Ω/square. The film was used as the transparent anode to fabricate an inverted top-emitting organic light-emitting diodes （IT-OLEDs） with the structure of glass substrate/Alq3 （40 nm）/NPB （15 nm）/CuPc （x nm）/ITO anode （100 nm）, where the film thickness of CuPc was optimized. It was found that the luminance of this IT-OLEDs was improved from 25 cd/m^2 to more than 527 cd/m^2 by increasing the thickness of CuPc, and luminance efficiency of 0.24 lm/W at 100 cd/m^2 was obtained, which indicated that the optimized thickness of CuPc layer was around 15 nm.     

硅基倒置型顶发射有机发光二极管

利用n型硅作为阴极制备了倒置型顶发射有机发光二极管.通过在 n-Si 阴极和电子传输层(Alq3)之间插入1 nm厚的 Ba 作为电子注入层,将器件的开启电压从20 V降低到9 V,并且将器件的效率提高了13倍.器件性能的提高主要是因为1 nm厚的 Ba 有效的降低了电子注入的势垒.     

Viewing-angle independence of white emission from microcavity top-emitting organic light-emitting devices with periodically and gradually changed cavity length

We demonstrate a broad-bandwidth and viewing-angle independent white emission from top-emitting organic light-emitting devices (TOLEDs) by integrating a microstructured cavity with a periodically and gradually changed cavity length. The results indicate that the microstructured cavity can resolve the viewing angle-dependence effect persisted in the conventional planar TOLEDs. The viewing-angle independence in both broad-band emission spectra and Commision Internationale de L’Eclairage coordinates are obtained. Moreover, the microstructured white TOLEDs show comparable luminance and current efficiency to that of the planar TOLEDs.     

白光有机发光器件研究及进展

有机电致发光技术被认为是可能替代液晶的新一代显示技术，白光有机发光器件由于可应用于液晶显示的背光源、普通照明、特殊光源以及实现全彩色有机发光显示而倍受瞩目。本文对白光有机电致发光器件的结构、工作原理等进行了简单的概述并总结了白光有机发光器件的最新进展。