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1.
针对钢材在高温高压下性能降低等问题,提出在钢材中加入Y、Ce、Zr等稀土元素,通过拉伸实验、高温氧化实验等方法对实验钢进行处理,利用SEM等表征手段观测样品氧化试样的表面形貌,截面形貌及显微组织等情况,最终得出,稀土元素Y、Ce、Zr可以改变钢体组织结构,细化晶粒,增强硬度,提高拉伸强度及屈服强度。 相似文献
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Yan Jianhui Zhang Houan Tang Siwen Li Yimin 《中国稀土学报(英文版)》2006,24(5):548-548
The oxidation behavior of 0. 8% La2O3- Mo5Si3/MoSi2 composites at 1200℃ in air was investigated. The results reveal that the oxidation resistance of the material with 0. 8% La2O3 and Mo5Si3 is impaired. The oxidation resistance is decreased with increasing Mo5Si3 content. The mass loss follows a linear law in the initial oxidation. With oxidation time prolonging, a continuous and dense oxidation scale prevents oxygen from diffusing increasing when and leads to mass change a Mo5Si3 content is less than 30%. However, the composite shows "PEST" with the addition of 40% Mo5Si3. With increasing Mo5Si3 content, the oxidation resistance of 0.8% La2O3- Mo5Si3/MoSi2 decreases. This attributes to the poor oxidation resistance of M05Si3 and the relative density decreasing of 0. 8% La2O3-Mo5Si3/MoSi2 composite. 相似文献
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稀土元素在陶瓷中的应用 总被引:1,自引:1,他引:0
从稀土元素的原子结构和化学特性出发,介绍了稀土元素的应用领域,阐述了稀土元素在陶瓷色釉料、各种氧化物陶瓷和非氧化物陶瓷中的应用. 相似文献
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The formation of aluminum matrix composites fabricated by exothermic dispersion reaction in A1-TiO2-B2O3 system was investigated. The thermal analysis results show that the reactions are spontaneous and exothermic. The Gibbs free energy of α-Al2O3 is the lowest among all the combustion products, followed by TiB2 and Al3Ti. It is noted that when the B2O3/TiO2 mole ratio is below 1, the reaction products are composed of particle-like α-Al2O3, TiB2 and rod-like Al3Ti. The α-Al2O3 crystallites, resulting from the reaction between A1 and TiO2 or B2O3, are segregated at the grain boundaries due to a lower wettability with the matrix. SEM micrographs show that rod-like Al3Ti phase distributes uniformly in the matrix. When the BEO3/TiO2 mole ratio is around 1, the Al3Ti phase almost disappears in the composites, and the distribution of α-Al2O3 particulates is improved evidently. 相似文献
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鄂尔多斯盆地西缘三叠系物源认识对油气石油勘探具有重要指导作用。本文通过大量的野外、井下采样,室内分析化验对比研究,发现西部环县地区与六盘山盆地、河西走廊地区延长组有着相似的重矿物组合,砂岩骨架组分普遍有较高的石英含量,稀土、微量元素特征也较为相似,具有属同一沉积体系的特征,花岗岩类是环县三角洲沉积体系的主要物源之一。认为现今概念的鄂尔多斯盆地西部晚三叠世与六盘山盆地及走廊地区不具明显的分割性,盆地很可能向西开口延伸。 相似文献
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段晓芳 《国内外石油化工快报》2006,36(1):28-29
通常加入传统的、商业可得到的纳米填充物会使弹性纳米复合物体系弹性变差,并具有更高的硬度。澳大利亚Queensland大学利用纳米粒子开发了一种新型软质热塑性聚氨酯(TPU)弹性体复合物,据称该复合物具有优异的拉伸强度和抗撕裂性能。 相似文献
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A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system. 相似文献
10.
Ba1.03 Ceo.8Euo.2O3-a solid electrolyte with nonstoichiometric composition was prepared by high temperature sol-id-state reaction. Phase composition, surface and fracture morphologies of the specimen were characterized by using XRD and SEM, respectively. Ionic conduction was researched by gas concentration cell, the performance of hydrogen-air fuel cell was measured in the temperature range of 600-1000℃, and compared them with those of BaCeo.8Euo.203-a and Bao.98Ceo.8Euo.2O3-a. The results indicate that Bat.03Ceo.8Euo.2O3-a is a single-phase perovskite-type orthorhombic system. It is a pure proton conductor in the temperature range of 600-1000℃ in hydrogen atmosphere, and its proton con-duction is superior to that of BaCeo.8 Euo.203-a and Bao.98Ceo.8Euo.203-a, It is a mixed conductor of oxide ion and electron hole in oxygen atmosphere. At 1000℃, the performance of the fuel cell in whieh Ba1.03Ceo.sEuo.2O3-a as electrolyteis higher than that of BaCeo.8Euo,2O33-a or Bao.98Ceo.sEuo.203-a. 相似文献