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1.
Polymers play an important role in the advancement of materials for use in cutting-edge applications. A direct consequence of an increased demand for more sophisticated materials has been a drive toward developing polymers that exhibit a higher level of structural control, especially in terms of the number and type of functionalities provided within the polymer framework. A family of polymers that meets such a challenge is based on the readily available AB2 monomer 2,2-bismethylolpropionic acid (bis-MPA) building block. Due to the ease with which the monomers can be synthesized, an array of multifunctional polymers have been produced including monodisperse dendrimers and dendrons and well-defined linear polymers as well as linear-dendritic hybridizations. This review outlines the evolution of the synthetic strategies for developing novel polymeric architectures based on bis-MPA and their assessment in both solution and substrate-based innovative applications. 相似文献
2.
《Ceramics International》2022,48(4):5040-5053
Using tailings as material to prepare glass-ceramic is an excellent way to achieve the resource utilization of solid waste. However, at present, researches on the solidification and migration of heavy metals are limited. Therefore, in this study, ten groups of samples were prepared by controlling sintering temperatures. The solidification, migration, and leaching behavior of non-volatile and volatile heavy metals were studied. The research showed that, with the increase of temperature, the properties of the samples were improved. Fe participated in the phase transformation and evolved into insoluble iron pyroxenes solid solution, while Pb was homogeneously distributed in the glass matrix of glass-ceramics. The leaching concentrations of Fe and Pb in the glass-ceramics were 0.055 mg/L ~0.087 mg/L and 0.074 mg/L ~0.140 mg/L, which were far below the threshold value. The results showed that heavy metals can be effectively solidified in glass-ceramics and have good environmental benefits. 相似文献
3.
An experimental procedure was developed to study directly the process by which liquid bridges between small particles in a granule form and solidify. The evolution of saturated solutions of such pharmaceutical excipients as lactose and mannitol in a liquid bridge was studied on a system situated on a microscope slide. Solidification and crystallization kinetics and phase composition during and immediately following bridge formation were observed directly. It was shown that bridges on the microscope slide and in the granule behave very much the same regardless of the different length and diffusion-scales of the two systems.We found that solid bridge formation takes place in several consecutive but distinct steps. In the case of lactose, considerable shrinkage of the initial liquid bridge takes place prior to the onset of crystallization. Further bridge solidification at ambient conditions occurs via simultaneous crystallization and vitrification within minutes. As a result, a “solid” bridge usually contains both a crystalline and a non-crystalline phase, the crystalline phase being predominately α-lactose monohydrate. Most of the non-crystalline phase eventually converts to crystalline β-lactose but the process may take many hours or even days. Results for this process are compared for samples obtained from different manufacturers of commercially available lactose. In the case of mannitol, different polymorphic forms crystallize as the drying/crystallization process progresses. A formed “solid” bridge usually contains several polymorphs of mannitol. The relevance of the behavior of the two model systems (pure lactose and pure mannitol) to a real granulation and tabletting process is discussed. 相似文献
4.
It is essential to automate the scanning path generation process to effectively implement the micro-stereolithography. However, a scanning path that is generated based only on a 3D CAD model introduces dimensional inaccuracies. In micro-stereolithography, the photopolymer solidification is affected by fabrication conditions, such as the optical properties (laser power, laser scanning speed, laser scanning pitch focusing condition, etc.) and material properties of the photopolymer. Thus, the photopolymer solidification phenomena must be considered when generating a laser scanning path. In this paper, a scanning path generation algorithm that uses 3D CAD data and considers the photopolymer solidification phenomena is proposed to improve the dimensional accuracy in micro-stereolithography. Multi-line photopolymer solidification experiments were performed for various laser scanning conditions to examine the photopolymer solidification phenomena. From these experiments, linear relations between the solidification length (width) and scanning length (width) were acquired and stored in a database. Subsequently, these data were utilized to compensate the scanning path of the laser beam. In addition, experiments for determining the layer thickness in the z-direction were performed and these results were also used in the scanning path generation algorithm.This research was supported by the Highly Advanced National Project (http://www.most.go.kr), which performs some of the National R&D Program, and sponsored by the Korean Ministry of Science and Technology under the contract project code M10214000116-02B1500-02010. 相似文献
5.
An isotropic model for creep damage of concrete under uniaxial compression is proposed, where the combined effect of nonlinear viscous strain evolution and crack nucleation and propagation at high stress levels is considered. Strain splitting assumption is used for creep and damage contributions. Creep is modeled by a modified version of solidification theory. As usual in the modeling of damage of concrete, a damage index based on positive strains is introduced. As particular cases, the proposed model reduces to linear viscoelasticity for long time low stress levels whereas, for very high stresses, tertiary creep causing failure at a finite time can be described. The effect of strength variation with time is also included. The model is numerically implemented to perform time integration of nonlinear equations by means of a modified version of exponential algorithm. The model is validated through comparison with experimental results. Some numerical examples are also presented, where the roles of concrete ageing and strength variation with time are investigated. 相似文献
6.
Tree-shaped flow structures designed by minimizing path lengths 总被引:1,自引:0,他引:1
S. LorenteW. Wechsatol A. Bejan 《International Journal of Heat and Mass Transfer》2002,45(16):3299-3312
This paper outlines a direct route to the construction of effective tree-shaped flow structures. Dendritic flow structures dominate the design of natural and engineered flow systems, especially in thermal and fluid systems. The starting point is the optimization of the shape of each elemental area or volume, such that the length of the flow path housed by the element is minimized. Proceeding toward larger and more complex structures - from elements, to first constructs, second constructs, etc. - the paper develops tree-shaped flow structures between one point and a straight line, one point and a plane, a circle and its center, and a point and many points distributed uniformly over an area. In the latter, the construction method is applied to a fluid flow configuration with laminar fully developed flow. The constructions reveal several features that are supported by empirical observations of natural tree-shaped flows: asymmetry, flow rate imbalance, pairing or bifurcation, angles between branches, and Y-shaped constructs that lie in a plane. It is shown that these basic features are necessary because of “packing”, i.e., assembling optimized elements into a fixed space, and filling the space completely. For the flow between an area and one point, the best elemental shape is the regular hexagon. It is shown that the emergence of string-shaped links that connect two or more elements are necessary features, which are also required by packing. Strings cover some of the inner zones of the tree network, particularly the inner zones of large and complex trees. Dichotomous Y-shaped constructs dominate the tree structure, especially the peripheral zones of the tree canopy. The practical importance of the simplified design method is discussed. 相似文献
7.
Morphology and Forming Mechanism of Rare Earth Inclusions During Solidification of Steel 总被引:2,自引:0,他引:2
翟启杰 《中国稀土学报(英文版)》1994,(3)
MorphologyandFormingMechanismofRareEarthInclusionsDuringSolidificationofSteel¥ZhaiQi-Jie(DepartmentofMetallurgy,UniversityofS... 相似文献
8.
Patterns in the solidification of a pure material are dealt with in this article. Results, deduced from a simple model based on heat conduction in the two phases and the effect of surface tension on the equilibrium temperature at the moving front, present a guide for experimental work. By introducing far-field conditions imitating what can be achieved in an experiment, we explain how the depths of the phases and the width of the container influence the patterns that can be seen if one advances the control variable to the critical point and then just beyond. Our new result is the existence of a third critical point. It occurs at small wave numbers and it is independent of surface tension. It appears because we take the depths of the phases into account. These depths are input values that offer the possibility of controlling crest-to-trough conduction, stabilizing in the solid, destabilizing in the liquid. The new critical point, and the patterns attending its appearance, can be found in cells of easily attainable widths. 相似文献
9.
Study on Numerical Simulation of Mold Filling and Solidification Processes under Pressure Conditions
The mold filling and solidification simulation for the high pressure die casting (HPDC) and low pressure die casting (LPDC) processes were studied.A mathematical model considering the turbulent flow and heat transfer phenomenon during the HPDC process has been established and paralled computation technique was used for the mold filling simulation of the process.The laminar flow characteristics of the LPDC process were studied and a simplified model for the mold filling process of wheel castings has been developed.For the solidification simulation under pressure conditions,the cyclic characteristics and the complicated boundary conditions were considered and techniques to improve the computational efficiency are discussed.A new criterion for predicting shrinkage porosity of Al alloy under low pressure condition has been developed in the solidification simulation process. 相似文献
10.
介绍第二届环太平洋先进材料及工艺国际会议情况,重点报导韩国钢铁工业、早期凝固过程研究、喷射成形、非晶合金、纳米材料和第三代单晶铸造高温合金等内容。 相似文献