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1.
Nan Wu Xiaodong Li Mu Zhang Yi Ren Qi Zhu Haijun Peng Hongqiang Ru Xudong Sun 《Journal of the European Ceramic Society》2021,41(4):2898-2907
Refining ceramic microstructures to the nanometric range to minimize light scattering provides an interesting methodology for developing novel optical ceramic materials. In this work, we reported the fabrication and properties of a new nanocomposite optical ceramic of Gd2O3-MgO. The citric acid sol-gel combustion method was adopted to fabricate Gd2O3-MgO nanocomposites with fine-grain sizes, dense microstructures and homogeneous phase domains. Nanopowders with low agglomeration and improved sinterability can be obtained by elaborating Φ values. Further refining of the microstructure of the nanocomposites was achieved by elaborating the hot-pressing conditions. The sample sintered at 65 MPa and 1300 °C showed a quite high hardness value of 14.3 ± 0.2 GPa, a high transmittance of 80.3 %–84.7 % over the 3?6 μm wavelength range, due mainly to its extremely fine-grain size of Gd2O3 and MgO (93 and 78 nm, respectively) and high density. 相似文献
2.
《Journal of the European Ceramic Society》2020,40(13):4396-4402
The response of nanocrystalline silicon carbide (nc-SiC) to nanoindentation is investigated using molecular dynamics (MD) simulation. It is found that the hardness of the nc-SiC decreases with decreasing grain size, showing an inverse Hall-Petch relationship. The behavior is primarily attributed to the reduced number of intact covalent bonds with grain refinement. Dislocation nucleation and growth in nc-SiC are strongly suppressed by the grain boundaries (GBs). In addition to the dislocation region in the grains, the indentation-induced amorphization of nanograins proceeds preferentially from the GBs, leading to grain shrinkage until the grains are fully amorphized. The results provide an improved understanding of the mechanical properties in nc-SiC and other nanostructured covalent materials. 相似文献
3.
化学镀非晶态Ni—B合金的研究 总被引:1,自引:0,他引:1
本文通过化学镀方法在铜和钢上沉积非晶态Ni-B合金。着重讨论了还原剂浓度、络合剂浓度对化学镀沉积速率的影响;分析了它的耐蚀原因和其显微硬度随退火温度的变化情况并就其应用和发展略作说明。 相似文献
4.
The Label-Cover problem, defined by S. Arora, L. Babai, J. Stern, Z. Sweedyk [Proceedings of 34th IEEE Symposium on Foundations of Computer Science, 1993, pp. 724-733], serves as a starting point for numerous hardness of approximation reductions. It is one of six ‘canonical’ approximation problems in the survey of Arora and Lund [Hardness of Approximations, in: Approximation Algorithms for NP-Hard Problems, PWS Publishing Company, 1996, Chapter 10]. In this paper we present a direct combinatorial reduction from low error-probability PCP [Proceedings of 31st ACM Symposium on Theory of Computing, 1999, pp. 29-40] to Label-Cover showing it NP-hard to approximate to within 2(logn)1−o(1). This improves upon the best previous hardness of approximation results known for this problem.We also consider the Minimum-Monotone-Satisfying-Assignment (MMSA) problem of finding a satisfying assignment to a monotone formula with the least number of 1's, introduced by M. Alekhnovich, S. Buss, S. Moran, T. Pitassi [Minimum propositional proof length is NP-hard to linearly approximate, 1998]. We define a hierarchy of approximation problems obtained by restricting the number of alternations of the monotone formula. This hierarchy turns out to be equivalent to an AND/OR scheduling hierarchy suggested by M.H. Goldwasser, R. Motwani [Lecture Notes in Comput. Sci., Vol. 1272, Springer-Verlag, 1997, pp. 307-320]. We show some hardness results for certain levels in this hierarchy, and place Label-Cover between levels 3 and 4. This partially answers an open problem from M.H. Goldwasser, R. Motwani regarding the precise complexity of each level in the hierarchy, and the place of Label-Cover in it. 相似文献
5.
The infiltration of compacted cubic BN (cBN) with molten aluminum has been investigated as a potential route for a cheap and easy method of manufacturing cBN/metal composites. CBN compacts have been infiltrated with molten Al at a temperature between 670 and 800 °C and pressure of 15 MPa in vacuum. At these temperatures no pronounced interactions between hexagonal and cubic BN with Al was observed, allowing the complete infiltration of cBN with 12 μm mean grain size. After infiltration at 800 °C, the temperature was increased without pressure to convert aluminum into borides and AlN. The hardness of the resulting materials depends on the content of hexagonal, cubic BN and the rate of conversion of Al into borides and AlN. The infiltration height of less than 1 mm obtained from infiltrating the 3 μm cBN powder green compacts gave a hardness of 22.0 ± 0.6 GPa after heat treatment. 相似文献
6.
D. Srinivasa Rao H. Suresh Hebbar M. Komaraiah 《Materials and Manufacturing Processes》2007,22(7):825-829
Burnishing is used increasingly as a finishing operation which gives additional advantages such as increased hardness, fatigue strength, and wear resistance. Experimental work based on 34 factorial design was carried out to establish the effects of ball burnishing parameters on the surface hardness of high-strength low alloy steels (HSLA) dual-phase (DP) steel specimens. Statistical analysis of the results shows that the speed, feed, lubricant and ball diameter have significant effect on surface hardness. 相似文献
7.
Wenzhong Zhu John J. Hughes Nenad Bicanic Chris J. Pearce 《Materials Characterization》2007,58(11-12):1189
This paper reports a study to assess nanoindentation mapping of mechanical properties of cement paste and natural rocks. Initial work seems to show that mechanical property mapping by nanoindentation is feasible and can be related to microscopic information. Further work is however required on the effect of indent size and spacing. Such a testing technique can be very useful for materials with different phases to study the intrinsic properties of each component, and also the interaction and properties of the interfacial regions of different phases. The values of Young's modulus and hardness of the individual mineral phases were also determined by statistically analysing a large number of experimental data. 相似文献
8.
The AlCoCrCuFeNi high-entropy alloy system was synthesized using a well-developed arc melting and casting method. Their elemental effect on microstructures and hardness was investigated with X-ray diffraction, scanning electron microscopy and Vickers hardness testing. The alloys exhibit quite simple FCC and BCC solid solution phases. Co, Cu and Ni elements enhance the formation of the FCC phase while Al and Cr enhance that of the BCC phase in the alloy system. BCC phases form a spinodal structure during cooling. Copper tends to segregate at the interdendrite region and forms a Cu-rich FCC phase. Low copper content renders the interdendrite as a thin film and the as-cast structure like recrystallized grain structure. The formation of BCC phases significantly increases the hardness level of the alloy system. The strengthening mechanism is discussed. 相似文献
9.
铝对W9Mo3Cr4V高速钢组织和硬度的影响 总被引:8,自引:2,他引:6
用X-射线仪,扫描电镜和透射电镜系统研究了铝对钨钼系高速钢铸态,退火以及淬回火组织的影响,铝含量超过2.0%,淬火组织中出现含析出合金的铁素体组织和晶界屈氏体,导致钢硬的降低。 相似文献
10.
The objective of the present study is to develop multi-functioned coating to the components, which are made of copper with electroplated Ni and are widely used for steel making industry. In this paper, we report the mechanical and thermal properties of Ni based superalloys with carbide sprayed by high velocity oxygen fuel (HVOF), and the detailed effects of sprayed material, spraying conditions, and initial powder structure on these properties. It was found that, among commercial Ni self-fluxing alloys (without fusing treatment), coating with a carbon content of 0.58 mass% had the most preferable properties, with a good balance of the hardness, strength, and thermal shock resistance. The thermal shock resistance depended not only on the strength of the coating but also on the volume contraction when tested at high temperatures. For the several developed Ni based superalloys with carbide, Ni20Cr8Mo5Fe–WC and Ni16Cr15Mo3–WC demonstrated the prominent adhesion strength and thermal shock resistance with high Galvanic corrosion resistance through optimized spraying condition. Also, 20 mass% NiCr–Cr3C2 coating sprayed by using employed relatively small primary particle succeeded in achieving the multi-superior properties; high adhesion strength, high corrosion resistance and thermal shock resistance. 相似文献