Thermal and transport properties of as-grown Ni-rich TiNi shape memory alloys

Electrical resistivity, Seebeck coefficient, specific heat and thermal conductivity measurements on the Ti_50−xNi_50+x (x = 0.0–1.6 at.%) shape memory alloys are performed to investigate their thermal and transport properties. In this study, anomalous features are observed in both cooling and heating cycles in all measured physical properties of the slightly Ni-rich TiNi alloys (x ≤ 1.0), corresponds to the transformation between the B19′ martensite and B2 austenite phases. Besides, the transition temperature is found to decrease gradually with increasing Ni content, and the driving force for the transition is also found to diminish slowly with the addition of excess Ni, as revealed by specific heat measurements. While the signature of martensitic transformation vanishes for the Ni-rich TiNi alloys with x ≥ 1.3, the characteristics of strain glass transition start to appear. The Seebeck coefficients of these TiNi alloys were found to be positive, suggesting the hole-type carriers dominate the thermoelectric transport. From the high-temperature Seebeck coefficients, the estimated value of Fermi energy ranges from ∼1.5 eV (Ti_48.4Ni_51.6) to ∼2.1 eV (Ti₅₀Ni₅₀), indicating the metallic nature of these alloys. In addition, the thermal conductivity of the slightly Ni-rich TiNi alloys with x ≤ 1.0 shows a distinct anomalous feature at the B19′ → B2 transition, likely due to the variation in lattice thermal conductivity.     

Purification of Ellagic Acid by UF Membranes

Ellagic acid (2, 3, 7, 8‐tetrahydroxy(1)benzopyrano(5, 4, 3‐cde)(1)benzopyran‐5, 10‐dione) was selected as a model pollutant which is present in the tannic fraction of cork processing wastewater. The ultrafiltration of aqueous ellagic acid solutions through three membranes was studied in tangential UF laboratory equipment. Two of the membranes were polyethersulfone (Biomax10K and Biomax5K, with MWCO of 10000 and 5000 Da, respectively), and the third made of regenerated cellulose (Ultracel5K, with MWCO of 5000 Da). The water hydraulic permeability was evaluated for each membrane. The evolution of the permeate flow rate with processing time was followed, and the influence of the main operating variables (feed flow rate, trans‐membrane pressure and nature of the membranes) on the permeate flux was also established. According to the hypothesis of the film theory, the intrinsic and apparent rejection coefficients, as well as the mass transfer coefficients, were also determined, and the values obtained were discussed as a function of the operating conditions used.     

高纯超细氧化铝的制备

介绍一种利用氧化铝生产过程的中间物料———铝酸钠溶液 ,生产高纯超细氧化铝的方法 ,即利用钡盐净化铝酸钠溶液 ,得到A/S >10 0 0 0的精制溶液 ,再进行种分分解 ,得到超细Al(OH) 3 ,经过酸洗 ,最终得到纯度达 99 99% ,粒度 90 %小于 2 μm高纯超细氧化铝。     

含钒废水净化回收技术研究

本文讨论了五氧化二钒生产过程中所排出废水的处理方法。认为采用焦亚硫酸钠及硫酸亚铁联合还原中和法为最佳,其技术关键为联合还原剂投料比、pH值、时间及含钒污泥提钒。年处理18万吨废水,可消除80余吨Cr~(+6)、V、Cu等重金属离子污染黄浦江上游水源,能回收粗红钒和含钒污泥提钒,使金属回收率提高4％。     

淋病奈瑟菌外膜蛋白Ⅰ的分离提纯及鉴定

在CaCl2存在下，以CTB提取淋球菌的OMP，再以Z3，14萃取PI，然后经DEAESepharoseCl－6B层析柱提纯，获得纯PI10．97毫克。SDS－PAGE显示纯PI为单一蛋白区带，分子量为35KD，经可见光扫描，其纯度达96.21％。用ELISA间接法检测证明，纯PI保持完好的抗原活性。亚类特异性鉴定证实为WI群PIA。     

MnCl2对镁合金废旧料组织性能的影响

利用等离子发射光谱仪、金相分析、电镜、万能电子材料试验机、腐蚀试验等方法研究了含有不同量的MnCl2熔剂对镁合金废旧料的力学性能、组织、断口形貌以及腐蚀行为的影响。研究表明,MnCl2可以降低镁合金废旧料中的Fe含量,同时会增加镁合金的Mn量,使用含MnCl2的熔剂可将镁废旧料中的Fe含量降到0 0072%以下。采用含MnCl2的熔剂可以提高试样的σb和δ。当合金中的Mn量超过一定程度后,对镁合金的力学性能会产生不利的影响。金相观察表明,净化处理对断口形貌无明显的影响,不改变AZ91镁合金的断裂机理,断口均成准解理断裂。腐蚀试验表明,采用含30%MnCl2的熔剂可以使试样的腐蚀速率从20 9mg/(cm2·d)降到6 4mg/(cm2·d)。     

重组人EC-SOD包涵体的稀释复性及重折叠后蛋白的纯化

目的确定重组人ECSOD包涵体体外稀释复性和复性后蛋白纯化的适宜方法。方法通过对pH、温度、包涵体蛋白浓度、尿素和精氨酸浓度及氧化还原对比率的定性定量分析,研究重组人ECSOD包涵体体外稀释复性的基本条件。采用金属离子亲和柱(IMAC)和肝素亲和柱(Heparinsepharose)对复性蛋白进行纯化,比较纯化效率的差异。结果最佳复性条件为pH8.5,尿素浓度为1.5molL,精氨酸浓度大于0.3molL,GSH∶GSSG=4∶1;复性温度及包涵体蛋白终浓度越高,复性效率越低。IMAC和Heparinsepharose亲和柱均可用来纯化复性蛋白溶液,但Heparinsepharose纯化效率较高。结论确定了重组人ECSOD包涵体体外稀释复性的最佳条件及复性后蛋白纯化的方法。     

人血浆蛋白C的纯化与鉴定

目的　建立人血浆蛋白C的纯化与鉴定方法。方法　利用DEAE SephadexA 5 0代替氯化钡 ,对血浆进行预处理 ,再经DEAE SepharoseFF离子交换和肝素 SepharoseCL 6B亲和层析进行分离纯化 ,用活化的部分凝血活酶时间 (APTT)测定组分活性 ,非还原型SDS PAGE测定其相对分子质量 ,Westernblot鉴定其特异性。结果获得相对分子质量为 6 2 0 0 0的蛋白条带 ,此条带可与人蛋白C单克隆抗体发生特异性反应。结论　已成功地从血浆中分离到蛋白C ,为其规模化生产奠定了基础。     

发酵工厂中空气净化工艺的合理选择

从节能、降低成本、优化工艺的角度，对无菌空气制备过程中，空气预处理流程的选择、空气净化设备、过滤介质以及设备的遴选进行探讨，以实现工艺和工程设计的优化结合。     

破伤风毒素及其片段的纯化

本文报道了破伤风毒素及其片段AB、BC、A和C的纯化方法。应用硫酸铵沉淀和Ultrogel AcA_(34)凝胶过滤制备的纯化毒素,于SDS-PAGE和PAGE中均形成单一的蛋白带,分子量为15万,pI为5.95,毒力为1～3×10~4MLD/μg。毒素经DTT还原、尿素处理、再用Ultrogel AcA_(44)凝胶过滤制备A和BC片段。A片段的分子量为54000,pI为4.8。BC片段的分子量为98 000,pI为7.2。木瓜酶处理毒素后用高压液相层析制备AB和C片段。纯化的AB片段分子量为98 000,于等电聚焦中为2条主要区带,pI为5.3和5.5,另有数条小区带;纯化的C片段分子量为51000,于PAGE中形成5条蛋白带,于等电聚焦中主要区带的等电点为7.3,另有几条小区带。