Catalytic behavior in CH4 decomposition of catalysts derived from red mud: Impact of residual Na2O

Catalyst samples for CH₄ decomposition were prepared from red mud (RM) by an acid-leaching neutralization precipitation approach. Water-washing the resultant precipitates multiple times, followed by drying at 105 °C and calcination at 500 °C, resulted in a threshold of residual Na₂O, equivalent to 96% Na₂O removal. Drying the precipitate at a higher temperature of 200 °C, followed by repeated water washing, provided a deeper Na₂O removal of 99% and made the resultant samples more active for the targeted reaction. Subsequently, four catalyst samples with a simulated red mud composition and NaOH contents from 0 to 0.3 wt% were prepared and the catalytic test results revealed that the Na₂O remaining in the RM-derived catalysts did not only inhibit their activation in CH₄ but also lower their maximal activities for CH₄ decomposition. Finally, two catalysts with the same simulated red mud composition and their Na impregnated respectively on Fe₂O₃ and a mixture support of Al₂O₃-SiO₂-TiO₂ were prepared and tested to explore the effect of Na distribution on the activation behavior of RM-derived catalysts for CH₄ decomposition. The activity testing results showed that it was the Na residual dispersed on iron oxides in the RM-derived samples to significantly inhibit the activation of CH₄ decomposition.     

A review of phosphorescent and fluorescent phosphors for fingerprint detection

Currently, the efficient detection of fingerprints is essential for the crime investigations. Revealing fingerprints is commonly achieved with fluorescent organic compounds but they are not efficient for fingerprint detection on porous or reflective surfaces. In order to solve the problem of collecting fingerprints on porous/reflective surfaces, inorganic phosphors have been employed, since they have characteristics of variable color emission, afterglow, high chemical stability and nano-size, which allow the fingerprint detection on any porous or non-porous surfaces. Due to these last properties, this review presents a summary about the use of phosphorescent and fluorescent phosphors for the detection of latent fingerprints. First, we discussed the main physical and chemical characteristics of the fingerprints which permit their detection and collection from any surface. After this, we presented the main morphological, structural and luminescent properties of the phosphorescent and fluorescent phosphors that allow their use for fingerprint detection. Later, we demonstrated with pictures of fingerprints (with and without light emission from the phosphors deposited on them) that both, phosphorescent and fluorescent phosphors can be used to visualize fingerprints with high resolution and high contrast without interference of the background surface, which is ideal for its collection and registration in the Automated Fingerprint Identification System (AFIS). We believe that this review could be useful to understand how to select an appropriate phosphorescent or fluorescent material for fingerprint detection depending on the type of surface (porous or non-porous, reflective or not reflective) where the fingerprint is deposited.     

Tuning of emission by effect of local symmetry in BaLaLiWO6:Dy3+/Eu3+ for WLEDs

The luminescence center energy transfer, crystal field strength, and covalency are limited by the crystal structure of the host and subsequently affect the luminescence efficiency, color, and intensity. Here, we report an excellent red phosphor BaLaLiWO₆:0.40Eu³⁺ and the dependence between symmetry and luminous performance. A model for changing symmetry is drawn by analyzing the Coulomb potential and structure for the application of a double-perovskite phosphor BLLWO: Dy³⁺, Eu³⁺ in white light LEDs. The addition of Dy³⁺/Eu³⁺ makes the W-O bond formed by the B-site and oxygen ion longer and the Li-O bond shorter, and the difference between the eight octahedral around the A-site is reduced, increasing the symmetry of the A-site. Local symmetry was successfully modulated by changing the Eu³⁺ concentration to control the Y/B ratio of Dy³⁺ and the R/O ratio of Eu³⁺ and smoothly achieved (0.382, 0.373) warm white light color coordinate. The phosphor has excellent thermal stability and still has 92.3% intensity at 475 K. The above results show that the wavelength composition of the luminescence is tunable by changing the symmetry of the environment in which the doped ions are located. It applies to single hosts for the regulation of white light emission.     

Improved quantum efficiency of Sr(Al,Si)5(O,N)7:Ce3+ by selection of Ce raw material

The luminescence properties of yellow-emitting Ce³⁺-doped Sr-containing sialon phosphor Sr(Al,Si)₅(O,N)₇:Ce³⁺ were notably improved by the Ce raw material selection. By changing the Ce raw material from oxides to nitrides or chlorides, the emission wavelength shifted to above 560 nm, which is beneficial for higher color rendering index white light-emitting diodes. This result from an increase in the covalency of the host crystal being associated with a decrease in the oxygen content. When Ce chloride was used, both the absorption and internal quantum efficiency increased, resulting in an increase in the external quantum efficiency up to 65%–72%. Inductively coupled plasma mass spectrometry, X-ray diffraction, and electron spin resonance measurements showed that the reason for the absorption increase is an increase in Ce³⁺ content and suppression of the generation of the second phase, and the reason for the increase in the internal quantum efficiency is a decrease in the host crystal absorption via suppression of anion vacancy generation. It was found that Ce chloride not only suppresses oxygen impurities but also acts as a flux that results in improved crystallinity.     

Sol-Gel Preparation and Luminescence Properties of BaMgAl10O17∶Eu2+ Phosphors

The synthesis of BaMgAl10O17∶ Eu2 (BAM) phosphors using the sol-gel method and their luminescence properties were reported. The blue-light emitting BAM was synthesized using citric acid and ethylene glycol as chelating materials. Emission of blue-light was obtained from these phosphors. The luminescent intensity increases as the temperature of heat treatment is increased. This study investigated the effects of the molar ratio of ethylene glycol to citric acid (Φ value), with respect to the phase formation and luminescence properties of BAM. The variation of the Φ value resulted in the change of the sol-gel reaction mechanism and the microstructures of the resultant powders. An increase in Φ value leads to an increase in the rate of BAM phase formation. The photoluminescent intensity of the prepared phosphors increases with heating temperatures because of enhanced crystallization.     

新型磷系膨胀阻燃剂

介绍了一种新型磷酸盐,通过试验分析了其作为膨胀型阻燃剂对聚烯烃及热固性塑料的阻燃机理与阻燃效果;红磷 酚类体系在高温聚合物中有较好阻燃效果     

长期酸化对红壤中活性固相铝库大小及亏损程度的影响

用连续分级提取和反复多次酸提取方法研究了长期土壤酸化对红壤固相铝库中铝含量及亏损程度的影响。研究结果表明:嵊县红壤的活性铝库大于永春红壤和屯溪红壤;因永春红壤和屯溪红壤的酸化程度大于嵊县红壤,前两者的有机铝库和无机铝库都比嵊县红壤的亏损,因此反复酸提取过程中铝的释放量也比嵊县红壤少;当高强度酸输入土壤后,弱键合的有机络合态铝可快速活化并亏损,剩余铝库因活性小而释放速率减小,但长期酸化过程中,动力学控制的低活性铝库的活化可能对铝的溶解量仍有重要贡献。     

Red clays from Central and Eastern Crete: geochemical and mineralogical properties in view of provenance studies on ancient ceramics

The existing geochemical diversity of clay deposits consists the underlying assumption for the determination of provenance of archaeological ceramics on the basis of their chemical composition. This assumption was tested on Quarternary red clayey alluviums from Central and Eastern Crete (Greece), an area rich in archaeological pottery and very popular for ceramics provenance studies. This type of clay has been used for pottery production on the island since the antiquity and it is still in use by traditional workshops. Altogether, 17 samples of clayey raw materials were collected from 7 different locations in Central and Eastern Crete, and characterised by chemistry, mineralogy and petrography. The study was focussed on the internal variability within deposits and the diversity among different deposits.It was possible to distinguish all seven deposits from each other on the basis of their chemical composition, taking into account the available mineralogical and petrographical information, although some deposits presented compositional relations. Compared to Neogene clay deposits in the same area, the variability among the examined red clayey deposits was clearly higher and exceeded by far the intra-deposit variability.     

发光体MAl2O4:Eu2+,RE3+的长余辉形成机理

提出了Eu^2 激活的MAl2O4:Eu^2 ,RE^3 （M＝Ca,Sr,Ba;RE=Dy,Nd,Ho,Er,Pr,Tb等稀土元素）系列铝酸盐发光体的长余辉发光机理。认为O^2-空位Vo是一种电子俘获陷际，是形成余辉的根本原因，RE^3 的引入使陷阱深度适宜而使余辉时间延长。缺陷在晶格中成簇分布，Vo和碱土金属离子空位VM在高温下可相互缔合。利用电子陷阱模型解释了实验中的一些普遍现象并提出了固相反应法合成此类发光体的工艺改进措施。