Characteristic tryptic peptides and gelling properties of porcine skin gelatin affected by thermal action

Thermal action in extraction process had effects on characteristic tryptic peptides identification and gelling properties of porcine gelatin. SDS-PAGE, HPLC-LTQ/Orbitrap high-resolution mass spectrometry, texture analyser and rheometer were used to evaluate collagen depolymerisation degree, characteristic tryptic peptides and gelling properties of gelatins prepared in various thermal actions. Results showed that with increasing temperature and time, depolymerisation degree enlarged, while gel strength, gelling and melting temperature decreased. Mass spectra showed that 47 and 49 common characteristic tryptic peptides were identified in gelatins extracted at 50 °C and 100 °C with various times, respectively. Moreover, 34 common characteristic tryptic peptides were identified in all gelatin samples. Further comparison between this work and our previous investigations yielded 20 common characteristic tryptic peptides, which stably exist in various thermal actions. These common characteristic tryptic peptides may be very helpful for the accurate authentication of porcine gelatin.     

Effect of sintering temperature on solidification and migration of non-volatile and volatile heavy metals in glass-ceramic

Using tailings as material to prepare glass-ceramic is an excellent way to achieve the resource utilization of solid waste. However, at present, researches on the solidification and migration of heavy metals are limited. Therefore, in this study, ten groups of samples were prepared by controlling sintering temperatures. The solidification, migration, and leaching behavior of non-volatile and volatile heavy metals were studied. The research showed that, with the increase of temperature, the properties of the samples were improved. Fe participated in the phase transformation and evolved into insoluble iron pyroxenes solid solution, while Pb was homogeneously distributed in the glass matrix of glass-ceramics. The leaching concentrations of Fe and Pb in the glass-ceramics were 0.055 mg/L ～0.087 mg/L and 0.074 mg/L ～0.140 mg/L, which were far below the threshold value. The results showed that heavy metals can be effectively solidified in glass-ceramics and have good environmental benefits.     

焊膏工艺性要求及性能检测方法

焊膏是SMT工艺中不可缺少的钎焊材料,广泛应用于再流焊中;它是由一定的合金粉末和助焊剂均匀混合而成的膏状体。主要对SMT中焊膏的组成及焊膏性能检测方法进行了简要分析。     

Evolution and structure of drying material bridges of pharmaceutical excipients: studies on a microscope slide

An experimental procedure was developed to study directly the process by which liquid bridges between small particles in a granule form and solidify. The evolution of saturated solutions of such pharmaceutical excipients as lactose and mannitol in a liquid bridge was studied on a system situated on a microscope slide. Solidification and crystallization kinetics and phase composition during and immediately following bridge formation were observed directly. It was shown that bridges on the microscope slide and in the granule behave very much the same regardless of the different length and diffusion-scales of the two systems.We found that solid bridge formation takes place in several consecutive but distinct steps. In the case of lactose, considerable shrinkage of the initial liquid bridge takes place prior to the onset of crystallization. Further bridge solidification at ambient conditions occurs via simultaneous crystallization and vitrification within minutes. As a result, a “solid” bridge usually contains both a crystalline and a non-crystalline phase, the crystalline phase being predominately α-lactose monohydrate. Most of the non-crystalline phase eventually converts to crystalline β-lactose but the process may take many hours or even days. Results for this process are compared for samples obtained from different manufacturers of commercially available lactose. In the case of mannitol, different polymorphic forms crystallize as the drying/crystallization process progresses. A formed “solid” bridge usually contains several polymorphs of mannitol. The relevance of the behavior of the two model systems (pure lactose and pure mannitol) to a real granulation and tabletting process is discussed.     

共面波导有限金属厚度效应的研究

用保角变换法对共面波导金属厚度效应进行了理论分析，编制了相应的计算机程序，给出了数值解，并对此进行了多元曲线拟合，导出了考虑金属厚度后的形状比k、有效介电常数、特征阻抗、损耗的闭定表达式。用此修正表达式求得特征阻抗及损耗的数值解，并与K．C．格普塔的修正值及实验测量值进行了详细比较，结果表明此修正公式与实验值相符较好。     

Nondestructive evaluation of the characteristics of degraded materials using backward radiated ultrasound

The frequency dependency of Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in two kinds of degraded specimens by scuffing or corrosion. Then, the frequency dependency is compared with the residual stress distribution or the corrosion-fatigue characteristics for the scuffed or corroded specimens, respectively. The width of the backward radiation profile increases with the increase of the variation in residual stress distribution for the scuffed specimens. In the corroded specimens, the profile width decreases with the increase of the effective aging layer thickness and is inversely proportional to the exponent, m, in the Paris’ law that can predict the crack size increase due to fatigue. The result observed in this study demonstrates high potential of backward radiated ultrasound as a tool for nondestructive evaluation of subsurface gradient of material degradation generated by scuffing or corrosion.     

漏斗贮料压力计算公式

本文从平衡条件和常系数假定出发，建立贮料压力微分方程，导出了正倒锥漏斗、倒锥漏斗贮料压力计算公式。文中说明，圆柱仓筒贮料压力微分方程为上述方程的特殊情形。本文成果可供筒仓工程设计使用，还可供确定斗口给料机贮料荷载参考。     

Laser scanning path generation considering photopolymer solidification in micro-stereolithography

It is essential to automate the scanning path generation process to effectively implement the micro-stereolithography. However, a scanning path that is generated based only on a 3D CAD model introduces dimensional inaccuracies. In micro-stereolithography, the photopolymer solidification is affected by fabrication conditions, such as the optical properties (laser power, laser scanning speed, laser scanning pitch focusing condition, etc.) and material properties of the photopolymer. Thus, the photopolymer solidification phenomena must be considered when generating a laser scanning path. In this paper, a scanning path generation algorithm that uses 3D CAD data and considers the photopolymer solidification phenomena is proposed to improve the dimensional accuracy in micro-stereolithography. Multi-line photopolymer solidification experiments were performed for various laser scanning conditions to examine the photopolymer solidification phenomena. From these experiments, linear relations between the solidification length (width) and scanning length (width) were acquired and stored in a database. Subsequently, these data were utilized to compensate the scanning path of the laser beam. In addition, experiments for determining the layer thickness in the z-direction were performed and these results were also used in the scanning path generation algorithm.This research was supported by the Highly Advanced National Project (http://www.most.go.kr), which performs some of the National R&D Program, and sponsored by the Korean Ministry of Science and Technology under the contract project code M10214000116-02B1500-02010.     

Nonlinear Creep Damage Model for Concrete under Uniaxial Compression

An isotropic model for creep damage of concrete under uniaxial compression is proposed, where the combined effect of nonlinear viscous strain evolution and crack nucleation and propagation at high stress levels is considered. Strain splitting assumption is used for creep and damage contributions. Creep is modeled by a modified version of solidification theory. As usual in the modeling of damage of concrete, a damage index based on positive strains is introduced. As particular cases, the proposed model reduces to linear viscoelasticity for long time low stress levels whereas, for very high stresses, tertiary creep causing failure at a finite time can be described. The effect of strength variation with time is also included. The model is numerically implemented to perform time integration of nonlinear equations by means of a modified version of exponential algorithm. The model is validated through comparison with experimental results. Some numerical examples are also presented, where the roles of concrete ageing and strength variation with time are investigated.     

高速供送螺杆动态性能评价体系的建构

随着设备高速化的日益发展，传统的螺杆设计方法及相应的供送特性评价体系已显落后。参照蜗型凸轮动力学性能的评价方法，建立了高速供送螺杆的动态性能评价体系，为高速化供送螺杆的设计提供了性能参照指标。