Coil‐Type Asymmetric Supercapacitor Electrical Cables

Cable‐shaped supercapacitors (SCs) have recently aroused significant attention due to their attractive properties such as small size, lightweight, and bendability. Current cable‐shaped SCs have symmetric device configuration. However, if an asymmetric design is used in cable‐shaped supercapacitors, they would become more attractive due to broader cell operation voltages, which results in higher energy densities. Here, a novel coil‐type asymmetric supercapacitor electrical cable (CASEC) is reported with enhanced cell operation voltage and extraordinary mechanical‐electrochemical stability. The CASECs show excellent charge–discharge profiles, extraordinary rate capability (95.4%), high energy density (0.85 mWh cm⁻³), remarkable flexibility and bendability, and superior bending cycle stability (≈93.0% after 4000 cycles at different bending states). In addition, the CASECs not only exhibit the capability to store energy but also to transmit electricity simultaneously and independently. The integrated electrical conduction and storage capability of CASECS offer many potential applications in solar energy storage and electronic gadgets.     

（S）-噻吗洛尔半水合物的合成及表征

为了开发β受体阻断剂新药（S）-噻吗洛尔半水合物，采用3-吗啉-4-氯-1，2，5-噻二唑为起始原料，经水解反应得到中间体1（3-吗啉-4-羟基-1，2，5-噻二唑）。中间体1与R-环氧氯丙烷发生醚化反应，经后处理及重结晶得到中间体2 {（R）-4-［4-（环氧乙烷-2-基甲氧基）-1，2，5-噻二唑-3-基］吗啉}。中间体2经胺化反应、马来酸成盐及重结晶得到（S）-马来酸噻吗洛尔。（S）-马来酸噻吗洛尔经游离、纯水转晶得到符合药典标准的（S）-噻吗洛尔半水合物，总收率14.05%且e.e.值为99.66%。最终成品经IR、1H-NMR、13C-NMR、MS、TGA、DSC表征，并优化各步反应条件。结果表明:以三乙胺为醚化反应缚酸剂75 ℃反应最佳；以乙醇为胺化反应溶剂46 ℃反应16 h最佳；S-噻吗洛尔的转晶拆分以水作溶剂，比传统不对称合成工艺安全稳定，操作简单，适合工业化生产。     

Crossing the Border: From Keto- to Imine Reduction in Short-Chain Dehydrogenases/Reductases

The family of NAD(P)H-dependent short-chain dehydrogenases/reductases (SDRs) comprises numerous biocatalysts capable of C=O or C=C reduction. The highly homologous noroxomaritidine reductase (NR) from Narcissus sp. aff. pseudonarcissus and Zt_SDR from Zephyranthes treatiae, however, are SDRs with an extended imine substrate scope. Comparison with a similar SDR from Asparagus officinalis (Ao_SDR) exhibiting keto-reducing activity, yet negligible imine-reducing capability, and mining the Short-Chain Dehydrogenase/Reductase Engineering Database indicated that NR and Zt_SDR possess a unique active-site composition among SDRs. Adapting the active site of Ao_SDR accordingly improved its imine-reducing capability. By applying the same strategy, an unrelated SDR from Methylobacterium sp. 77 (M77_SDR) with distinct keto-reducing activity was engineered into a promiscuous enzyme with imine-reducing activity, thereby confirming that the ability to reduce imines can be rationally introduced into members of the “classical” SDR enzyme family. Thus, members of the SDR family could be a promising starting point for protein approaches to generate new imine-reducing enzymes.     

Asymmetric Regulation System Fit for Chinese Telecom Market

After the new round of restructuring of Chinese telecom sector,it's pressing to formulate and implement asymmetric regulation policies so as to shape an effectively competitive market structure in a relatively short term.This paper reviewed the asymmetric regulation policies and practices carried out in foreign telecom market,and then according to the specific situations of Chinese telecom market,proposed the principles and corresponding policies for establishing an asymmetric regulation system fit for Chin...     

天铁炼钢厂四流中间包流场的水模实验及优化

介绍了天铁炼钢厂中间包水模实验原理和过程，分析了斜、直、圆三种型式挡渣墙模拟结果，提出了合理的挡渣控流方案，在生产实践中使用效果良好。     

微型灌注桩托换技术在地基基础加固工程中的应用

因场地淤泥等软土层深厚,在填方荷载作用下,软弱土层产生固结沉降,引起局部构筑物的不均匀沉降,发生结构破坏。采用微型灌注桩加固满足现场各个限制条件的要求,达到了加固目的。     

现金流量与公司投资决策--从公司规模角度的实证研究

根据现代公司金融理论，将融资因素引进公司的投资模型，研究不同规模的公司投资与现金流量的关系，并探寻不同规模公司投资决策行为差异的背后动机。实证研究发现：大规模公司投资对现金流量的敏感性要高于小规模公司，动因检验的结果表明大规模公司投资依赖于现金流量源于信息不对称理论，小规模公司源于自由现金流量的代理成本理论，这为我国完善资本市场、制定合理政策提供了借鉴的依据。     

中间包CaO质陶瓷过滤器滤除夹杂效果的研究

对鞍钢三炼钢厂中间包应用的CaO质陶瓷过滤器进行了实验研究，从装有陶瓷过滤器和未装陶瓷过滤器的挡墙侧水口上方及各自的连铸坯中取样，并用电解法和吸收光度法测定了夹杂物的总含量及分量。实验结果表明，陶瓷过滤器对于滤除钢液中的Al2O3、SiO2夹杂作用显著。     

新钢板坯连铸中间包采用控流槽的水模拟实验

通过板坯连铸中间包水模拟实验,表明新型控流装置--控流槽可大大改善中间包内流体的流动特征参数和流动轨迹,并具有防止卷吸气体作用.     

光学活性物质的工业生产方法

本文介绍了光学８活性牺牲垢几种工业规模的生产方法及最新的进展，分析了各种方法的特点及存在的问题。