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1.
《International Journal of Hydrogen Energy》2022,47(36):16121-16131
Ammonia is considered as a promising hydrogen or energy carrier. Ammonia absorption or adsorption is an important aspect for both ammonia removal, storage and separation applications. To these ends, a wide range of solid and liquid sorbents have been investigated. Among these, the deep eutectic solvent (DES) is emerging as a promising class of ammonia absorbers. Herein, we report a novel type of DES, i.e., metal-containing DESs for ammonia absorption. Specifically, the NH3 absorption capacity is enhanced by ca. 18.1–36.9% when a small amount of metal chlorides, such as MgCl2, MnCl2 etc., are added into a DES composed of resorcinol (Res) and ethylene glycol (EG). To our knowledge, the MgCl2/Res/EG (0.1:1:2) DES outperforms most of the reported DESs. The excellent NH3 absorption performances of metal–containing DESs have been attributed to the synergy of Lewis acid–base and hydrogen bonding interactions. Additionally, good reversibility and high NH3/CO2 selectivity are achieved over the MgCl2/Res/EG (0.1:1:2) DES, which enables it to be a potential NH3 absorber for further investigations. 相似文献
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Rotating-bending uniaxial fatigue tests and micro-fatigue crack initiation tests were carried out using a permanent mold cast
(PMC) and semi-solid die cast (SDC) with Al−7%Si−0.35%Mg composition in order to examine the relationship between solidification
structures and fatigue behaviors. The crack length was measured using a replication method. Fatigue strength was improved
in SDC, which was almost consistent with the predicted fatigue strength using the size of Si particle cluster. Resistance
to fatigue crack initiation and fatigue strength were improved in SDC owing to the finer Si cluster and to higher ultimate
tensile strength. Fatigue crack in PMC was preferentially initiated at pores. For SDC, the fatigue crack was initiated at
the Si particle/matrix interface, and then sucessively grew along eutectic cell boundaries. 相似文献
4.
V. G. Khoruzhaya K. E. Kornienko P. S. Martsenyuk T. Ya. Velikanova 《Powder Metallurgy and Metal Ceramics》2006,45(5-6):251-258
Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are
used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic
composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility
of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l
⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method
of forming phases in the field of composition rich in aluminum given in publications are confirmed.
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Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006. 相似文献
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原始组织及加热方式对Al-5.8wt%Cu合金熔化行为的影响 总被引:3,自引:0,他引:3
利用DSC分析手段,研究了具有3种不同凝固组织的Al-5.8wt%合金在7种不同加热方式下的熔化开始温度和熔化热,发现凝固组织中存在的非平衡共晶在加热过程中大部分扩散溶解,溶入基体,剩余部分参与共晶熔化,其熔化开始温度与组织状态无关,随加热速度的增大略有升高,溶解部分的体积分散与组织状态和加热方式有关,随加热时间和非平衡相表面积的增大而增大。 相似文献
9.
The behavior during creep in shear of eutectic indium-tin joints on copper and nickel substrates was examined in order to
determine the effect of creep deformation on the microstructure of the alloy. Primary creep was absent in all the samples
tested. The stress exponent at 20° C was much higher for samples on nickel than for those on copper, indicating a different
creep deformation mechanism. Also, the microstructure within the indium-tin joints differed significantly with a change of
substrate. Samples with a nickel substrate showed a colony microstructure that was not observed in those with a copper substrate.
Thus, eutectic morphology is important in determining deformation mechanism during creep. The microstructure within the joints
in tested and untested regions of the samples was effectively the same. This is quite distinct from the behavior of eutectic
lead-tin observed in previous work. Lead-tin formed a recrystallized band of material along a region of concentrated shear
deformation. While the deformation pattern in the indium-tin samples appeared to be the same as for lead-tin, the microstructural
changes did not occur. This implies that the behavior observed in lead-tin is not universal to eutectic alloys. 相似文献
10.
两相共晶NiAl-9Mo合金的蠕变行为 总被引:8,自引:0,他引:8
研究了热等静压态的NiAl-9Mo合金在850-950℃和50-100 MPa下的蠕变行为.在试验应力和温度下,该合金蠕变曲线呈现出较短的减速阶段和较长的稳态蠕变阶段;其稳态蠕变速率可用幂指数蠕变方程来描述,应力指数值为4.75±0.25,表观激活能为 410.5±4.5kJ/mol.加速蠕变阶段蠕变速率的增加是由于裂纹的形成和扩展,且其断裂数据遵循Monkman-Grant规律.蠕变断口呈现出塑性断裂和沿晶蠕变断裂的混合特征,但后者比例较大,同一温度下随着应力的增大,沿晶断裂的比例呈现下降的趋势. 相似文献