Process Intensification of Living Cationic Polymerization of Isobutylene by a Flow Reaction System

Increasing the reaction temperature of the living cationic polymerization of isobutylene is crucial for industrial production due to the cost of refrigeration. The reaction temperature increase was achieved with an accelerated reaction rate using a flow reaction system. The polymerization conditions, including the flow reactor design, were based on the results of kinetic studies. Utilizing a milli‐scale flow reactor, polyisobutylene, which has a narrow molecular weight distribution, was obtained within a considerably short residence time at a high temperature. Furthermore, it was confirmed that the value of M_w/M_n correlates with the product of the Reynolds number and the angle of collision.     

像增强型夜视系统的图像信息传递

在分析了像增强夜视系统信息传递的基础上，指出像增强器输出端荧光屏至人眼的图像传递过程，构成了像增强夜视系统信息传递量的限制．提出了采用系统信息传递量作为夜视系统设计与评价的方法，利用这种方法可以发现在像增强器增益足以补偿光谱选道衰减的条件下，采用彩色像增强可以大幅度增加夜视系统传输的信息量．     

Filtration of Non-Newtonian Hydrocarbon Fluid in a High-Frequency Electromagnetic Field

The paper gives the results of experimental investigations of the initial pressure gradient of bituminous oil and the time dependences of variation of the temperature in a formation model and of the well production rate in a microwave-frequency electromagnetic field. The effect of strong decay of the non-Newtonian properties of bituminous oil is revealed. The nonuniformity of temperature distribution over the formation thickness is demonstrated, which depends on the initial production rate of the well and on the duration of stimulation of the bottom-hole zone of formation.     

一种工艺过程流体强化装置

介绍了一种提高工艺过程效率的强化装置,即通过在过程设备上设置振荡装置,使过程设备内的流体产生扰动,破坏流动边界层,使流体获得附加雷诺数提高流动的湍流程度,达到强化过程设备内工艺过程的目的。该强化装置的调节弹性大,适应范围宽。调节强化装置中转子的转速、几何尺寸、空间位置和方向等参数或更换挡板形式,就能适应各种工艺过程条件。该装置可用于传热、传质及化学反应等多种过程,以提高过程效率,节约能源和资金,减小设备体积,并可将机械搅拌类的间歇过程转化为连续过程。     

钒钛磁铁精矿的烧结特性及强化措施

阐述了钒钛磁铁精矿的矿石特点，烧结特性及其与烧结矿质量之间的关系，并提出了强化烧结的措施。     

添加剂强化重油催化裂化的过程分析与应用

运用工程化学原理分析讨论了添加剂强化重油催化裂化的过程，包括分散稳定气泡、改善雾化、保护酸中心、抑制焦炭生成以及提高重油气化率的胶体结构改性、降低表面张力和改善微孔润湿，并用以指导强化重油催化裂化添加剂的筛选。建立小型固定流化床催化裂化实验装置评价了添加剂的强化效果。结果表明，添加剂强化重油催化裂化可降低催化剂生焦1．0％左右，提高总液体收率1．0％～2．8％。     

Q195冷轧板材轧制困难原因分析

针对部分Q195冷轧板材存在轧制困难的现象，进行了现场检验与分析。带状组织、混晶现象严重导致变形强化系数偏高是造成轧制困难的主要原因。     

水稻强化栽培下不同氮肥管理对产量与氮素利用的影响

以籼型单季超级杂交稻中浙优1号为材料,研究水稻强化栽培氮肥管理对产量与氮素利用率的影响。结果表明:水稻强化栽培与常规栽培对照比较,增产达11.1%-15.2%,氮肥回收率比对照高5.3%~26.9%,农学利用率比对照高67.2%~92.2%,生理利用率比对照高6.0%~80.5%。因此,在水稻生产上应用水稻强化栽培可以提高氮肥的利用,降低氮肥在环境中积累及对环境造成污染。此外,本文对水稻强化栽培下氮肥管理的高产机理进行了探讨。     

应用系统工程原理 促进炼铁技术进步

应用系统工程原理,从铁前抓起,不断进行技术改造,使焦化、烧结、炼铁工艺及设备系统不断优化,从而确保了300m~3高炉的强化冶炼。     

Integrated UV-based photo microreactor-distillation technology toward process intensification of continuous ultra-high-purity electronic-grade silicon tetrachloride manufacture

Ultra-high-purity silicon tetrachloride (SiCl₄) is demanded as an electronic-grade chemical to meet the stringent requirements of the rapidly developing semiconductor industry. The high requirement for ultra-high-purity SiCl₄ has created the need for a high-efficient process for reducing energy consumption as well as satisfying product quality. In this paper, a mass of production technology of ultra-high-purity SiCl₄ was successfully developed through chlorination reaction in the ultraviolet (UV)-based photo microreactor coupled with the distillation process. The influences of key operational parameters, including temperature, pressure, UV wavelength and light intensity on the product quality, especially for hydrogen-containing impurities, were quantified by the infrared transmittance of Fourier transform infrared spectroscopy (FT-IR) at 2185 cm⁻¹ and 2160 cm⁻¹ indicating that characteristic vibrational modes of SiH bonds, as well as the operating conditions of distillation were also investigated as key factors for metal impurities removing. The advanced intensification of SiCl₄ manufactured by the integration of photo microreactor and distillation achieves the products with superior specifications higher than the standard commercial products.