全文获取类型
收费全文 | 23085篇 |
免费 | 2011篇 |
国内免费 | 1115篇 |
专业分类
电工技术 | 1029篇 |
综合类 | 1688篇 |
化学工业 | 3959篇 |
金属工艺 | 1448篇 |
机械仪表 | 1424篇 |
建筑科学 | 1350篇 |
矿业工程 | 2156篇 |
能源动力 | 1182篇 |
轻工业 | 912篇 |
水利工程 | 663篇 |
石油天然气 | 5021篇 |
武器工业 | 228篇 |
无线电 | 681篇 |
一般工业技术 | 1672篇 |
冶金工业 | 1424篇 |
原子能技术 | 295篇 |
自动化技术 | 1079篇 |
出版年
2024年 | 81篇 |
2023年 | 279篇 |
2022年 | 557篇 |
2021年 | 670篇 |
2020年 | 714篇 |
2019年 | 511篇 |
2018年 | 519篇 |
2017年 | 670篇 |
2016年 | 734篇 |
2015年 | 797篇 |
2014年 | 1304篇 |
2013年 | 1515篇 |
2012年 | 1616篇 |
2011年 | 1719篇 |
2010年 | 1256篇 |
2009年 | 1280篇 |
2008年 | 1100篇 |
2007年 | 1321篇 |
2006年 | 1342篇 |
2005年 | 1187篇 |
2004年 | 996篇 |
2003年 | 926篇 |
2002年 | 824篇 |
2001年 | 747篇 |
2000年 | 606篇 |
1999年 | 558篇 |
1998年 | 441篇 |
1997年 | 370篇 |
1996年 | 327篇 |
1995年 | 264篇 |
1994年 | 208篇 |
1993年 | 135篇 |
1992年 | 108篇 |
1991年 | 97篇 |
1990年 | 113篇 |
1989年 | 76篇 |
1988年 | 43篇 |
1987年 | 36篇 |
1986年 | 32篇 |
1985年 | 23篇 |
1984年 | 23篇 |
1983年 | 10篇 |
1982年 | 15篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1964年 | 5篇 |
1959年 | 6篇 |
1957年 | 3篇 |
1956年 | 3篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(79):33765-33780
This work investigates selective Ni locations over Ni/CeZrOx–Al2O3 catalysts at different Ni loading contents and their influences on reaction pathways in ethanol steam reforming (ESR). Depending on the Ni loading contents, the added Ni selectively interacts with CeZrOx–Al2O3, resulting in the stepwise locations of Ni over CeZrOx–Al2O3. This behavior induces a remarkable difference in hydrogen production and coke formation in ESR. The selective interaction between Ni and CeZrOx for 10-wt.% Ni generates more oxygen vacancies in the CeZrOx lattice. The Ni sites near the oxygen vacancies enhance reforming via steam activation, resulting in the highest hydrogen production rate of 1863.0 μmol/gcat·min. In contrast, for 15 and 20-wt.% Ni, excessive Ni is additionally deposited on Al2O3 after the saturation of Ni–CeZrOx interactions. These Ni sites on Al2O3 accelerate coking from the ethylene produced on the acidic sites, resulting in a high coke amount of 19.1 mgc/gcat·h (20Ni/CZ-Al). 相似文献
2.
Sehar Tasleem Muhammad Tahir Wesam Alsayeh Khalifa 《International Journal of Hydrogen Energy》2021,46(27):14148-14189
Photocatalytic H2 generation using semiconductor photocatalysts is considered as a cost-effective and eco-friendly technology for solar to energy conversion; however, the present photocatalysts have been recognized to depict low efficiency. Currently, porous coordination polymers known as metal-organic frameworks (MOFs) constituting flexible and modifiable porous structure and having excess active sites are considered to be appropriate for photocatalytic H2 production. This review highlights current progress in structural development of MOF materials along with modification strategies for enhanced photoactivity. Initially, the review discusses the photocatalytic H2 production mechanism with the concepts of thermodynamics and mass transfer with particular focus on MOFs. Elaboration of the structural categories of MOFs into Type I, Type II, Type III and classification of MOFs for H2 generation into transition metal based, post-transition metal based, noble-metal based and hetero-metal based has been systematically discussed. The review also critically deliberate various modification approaches of band engineering, improvement of charge separation, efficient irradiation utilization and overall efficiency of MOFs including metal modification, heterojunction formation, Z-scheme formation, by introducing electron mediator, and dye based composites. Also, the MOF synthesized derivatives for photocatalytic H2 generation are elaborated. Finally, future perspectives of MOFs for H2 generation and approaches for efficiency improvement have been suggested. 相似文献
3.
4.
《Advanced Powder Technology》2022,33(8):103602
To operate a bag filter continuously, pulse-jet cleaning of dust particles from the filter medium is commonly required, and the pulse-jet pressure significantly affects the filter performance. In this study, the accumulation structure of residual dust particles inside and on the surface of a filter medium at different pulse-jet pressures was investigated by constructing a simple model, and the influence of the dust structure on the filter performance was clarified. Using a simple model, we determined the effective ratio of filtration area β, which represents the ratio of the filterable area to the total filtration area, the true resistance coefficient due to the primary dust layer ζp’ thinly deposited on the filter surface, and the true resistance coefficient inside the filter media itself ζf’. The effective ratio of filtration area β decreased with operation time for all pulse-jet pressures; however, it maintained a high value when the pulse-jet pressure was high. The validity of β analyzed by the model was verified using two different methods, and the results showed good agreement, indicating that the model is effective in identifying real conditions. The true resistance coefficient due to the primary dust layer ζp’ decreased as the pulse-jet pressure increased; however, the true resistance coefficient inside the filter media itself ζf’ was the highest at 0.5 MPa. In addition, the dust collection efficiency was different at each pulse-jet pressure, which was considered to be caused by the difference in the dust particle accumulation structure. 相似文献
5.
6.
《Journal of the European Ceramic Society》2021,41(15):7868-7877
In this work, 0.5TRPO•0.5Gd2Zr2O7 ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr2+ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms. 相似文献
7.
8.
Rectangular section control technology(RSCT)was introduced to achieve high-precision profile control during silicon steel rolling.The RSCT principle and method were designed,and the whole RSCT control strategy was developed.Specifically,RSCT included roll contour design,rolling technology optimization,and control strategy development,aiming at both hot strip mills(HSMs)and cold strip mills(CSMs).Firstly,through the high-performance variable crown(HVC)work roll optimization design in the upper-stream stands and the limited shifting technology for schedule-free rolling in the downstream stands of HSMs,a hot strip with a stable crown and limited wedge,local spot,and single wave was obtained,which was suitable for cold rolling.Secondly,an approximately rectangular section was obtained by edge varying contact(EVC)work roll contour design,edge-drop setting control,and closed loop control in the upper-stream stands of CSMs.Moreover,complex-mode flatness control was realized by coordinating multiple shape-control methods in the downstream stands of CSMs.In addition,the RSCT approach was applied in several silicon-steel production plants,where an outstanding performance and remarkable economic benefits were observed. 相似文献
9.
Adaptive robust boundary control of shaft vibrations under perturbations with unknown upper bounds
下载免费PDF全文
![点击此处可从《International Journal of Adaptive Control and Signal Processing》网站下载免费的PDF全文](/ch/ext_images/free.gif)
This paper presents robust and adaptive boundary control designs to stabilize the two‐dimensional vibration of hybrid shaft model. The hybrid shaft is mathematically represented by a set of partial differential equations, governing the shaft vibrations, coupled to ordinary differential equations, describing rigid body spinning and dynamic boundary conditions. The control objective is to stabilize the transverse vibrations of the perturbed shaft while regulating the spinning rate. To achieve this, the paper first establishes robust boundary control laws that fulfil the control objective in the presence of modeling uncertainties and external disturbances operating over the shaft domain and boundary. Lyapunov‐based analyses show that the proposed robust control exponentially stabilizes the shaft with vanishing distributive perturbations, while assuring ultimately bounded vibrations in the case of nonvanishing perturbations. Then, adaptive control philosophy is utilized to achieve redesigned robust controllers that only use online adaptation of control gains without acquiring the knowledge of bounds on perturbations, as well as dynamic parameters. An advantage of this design is avoiding an overconservative robust control law, which may induce poor stability and chattering in tackling system perturbations with unknown upper bounds. Simulations through finite element method illustrate the results. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
10.
Ivonne Sgura Amos S. Lawless Benedetto Bozzini 《Inverse Problems in Science & Engineering》2019,27(5):618-647
The process of electrodeposition can be described in terms of a reaction-diffusion partial differential equation (PDE) system that models the dynamics of the morphology profile and the chemical composition. Here we fit such a model to the different patterns present in a range of electrodeposited and electrochemically modified alloys using PDE constrained optimization. Experiments with simulated data show how the parameter space of the model can be divided into zones corresponding to the different physical patterns by examining the structure of an appropriate cost function. We then use real data to demonstrate how numerical optimization of the cost function can allow the model to fit the rich variety of patterns arising in experiments. The computational technique developed provides a potential tool for tuning experimental parameters to produce desired patterns. 相似文献