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V. G. Khoruzhaya K. E. Kornienko P. S. Martsenyuk T. Ya. Velikanova 《Powder Metallurgy and Metal Ceramics》2006,45(5-6):251-258
Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are
used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic
composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility
of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l
⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method
of forming phases in the field of composition rich in aluminum given in publications are confirmed.
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Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006. 相似文献
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Charles A. Bateman Lijie Zhang Helen M. Chan Martin P. Harmer 《Journal of the American Ceramic Society》1992,75(5):1281-1283
It is experimentally observed that the peritectic reaction, 211 + liquid → 123, can be driven essentially to completion in 1 h at an undercooling of only ∽30°C. The kinetic data, together with the observed microstructures, are inconsistent with the normal mechanism of the peritectic reaction. It is proposed that the mechanism of the reaction involves dissolution of 211 particles into the liquid and precipitation of solid 123. The aligned grain structure is explained through sympathetic nucleation of new 123 grains on existing grains. 相似文献
5.
定向凝固法制备YBC超导体的若干材料学问题 总被引:5,自引:0,他引:5
讨论了定向凝固法制备YBCO超导体涉及的包晶转变与包晶反应,成分过冷,扩散控制生长模型,界面效应及定向凝固YBCO生长晶体学等问题。 相似文献
6.
K.C. Mills 《北京科技大学学报(英文版)》2009,16(3):261-264
Crystallization properties play an important role in keeping a smooth running of continuous casting process and high sur-face quality of cast strands. To reduce fluorine pollution in slag, a new type of CaO-SiO2-Na2O (CSN) based mold flux was studied. The solidification and crystallization properties, including crystallization temperature, crystallization ratio and solidification minera-graphy, were measured, which were compared with the CaO-SiO2-CaF2 (GF) mold flux. The results show that the crystallization performance is equal to the high fluoride mold powder and CSN can be used for peritectic steel grades sensitive to longitudinal cracking in continuous casting. 相似文献
7.
1 INTRODUCTIONTb Dy Fealloy ,asarareearth (RE)magneticfunctionalmaterial,isofsignificanttechnologicalin terests ,becauseofitsgiantmagnetostrictionatroomtemperatureaswellashighenergydensityandfastresponsevelocityatlowfrequency[1] .Wideapplica tionfieldshavebeenidentifiedsincethematerialhadbeenexploited[2 ] .Thecompetitiongrowthbetweentheperitecticphase— (Tb Dy)Fe2 (REFe2 )andtheprimiaryphase— (TbDy)Fe3(REFe3)existsinthesolidificationprocessingoftheperitecticTb Dy Feal loys ,which… 相似文献
8.
NEW METHODS FOR CALCULATING ACTIVITIES OF COMPONENTS FROM PHASE DIAGRAMS IN BINARY PERITECTIC SYSTEMS 总被引:3,自引:0,他引:3
Zhang Yongjun Hunan Superior Tech Materials Company Ltd. Changsha Zhang Xunying The Fourth Smelter Shuikoushan Mineral Bureau Henyang Fu Chongyue Department of Nonferrous Metallurgy Central South University of Technology Chang 《中国有色金属学会会刊》1997,(2)
NEWMETHODSFORCALCULATINGACTIVITIESOFCOMPONENTSFROMPHASEDIAGRAMSINBINARYPERITECTICSYSTEMS①ZhangYongjunHunanSuperiorTechMateri... 相似文献
9.
Sn-Sb包晶合金的快速凝固 总被引:3,自引:0,他引:3
设计了一种用于Sn-Sb等滑动轴承合金的无容器接触深过冷快速凝固装置.并以热流分析为基础,利用传热模型和物理模型计算了Sn-16%Sb(质量分数)过包晶合金在本装置中的冷却速度.结果表明:在粒子直径为4mm时,粒子的冷却速度为3.1×102K/s;当粒子直径为0.1mm时,冷却速度达到了105K/s.Sn-Sb包晶合金组织显著细化,初生相SnSb化合物高度弥散化. 相似文献
10.
对攀钢Q235G钢连铸坯出现的角横裂缺陷进行了调查分析,在此基础上确定了连铸保护渣是引起角横裂的主要原因。并对保护渣的配方进行了改进,通过试验,研制出了适合攀钢普碳包晶钢用的连铸保护渣,有效地控制了Q235G钢连铸坯角的横裂缺陷。 相似文献