Evaluation of high Ni-Cr-Mo alloys for the construction of sulfur dioxide scrubber plants

Corrosion in wet lime/limestone systems used for flue gas desulfurization in thermal power plants is of great concern. The frequent variations in acidity and in chloride and fluoride ion concentrations experienced by such systems pose a serious threat to the materials of construction. Currently used materials mostly type 316L stainless steel often fail to meet their life expectancy. The present study evaluates the performance of advanced Ni- Cr- Mo alloys 59 and C- 276 in a simulated sulfur dioxide scrubber environment. Accelerated tests showed that high Ni- Cr- Mo alloys have little tendency to leach metal ions such as chromium, nickel, and molybdenum at different impressed potentials. Scanning electron microscopy was used to examine the morphology of pitting attack.     

Electrochemical anticorrosion performance evaluation of Al2O3 coatings deposited by MOCVD on an industrial brass substrate

Alumina (Al₂O₃) coatings of different thickness were deposited on OT59 brass substrate (BS) using the metal organic chemical vapour deposition (MOCVD) technique to evaluate the corrosion performance by EIS measurements. The used precursor was dimethyl-aluminium-isopropoxide. Electrochemical characterizations of the deposited films were performed in a standard very aggressive acidic solution (aerated 1N H₂SO₄ at 25 °C up to 168 h of immersion time) by means of direct current method (Tafel curves) and electrochemical impedance spectroscopy (EIS). The Rutherford backscattering spectroscopy (RBS) indicated that the films are very pure with the correct Al₂O₃ stoichiometry, while the IR absorption spectra showed that the films did not contain any OH groups. The surface film morphology was investigated by atomic force microscopy (AFM) and displayed a globular texture. The films were very smooth, with a maximum root mean square roughness, for example, of 14 nm for a 0.96 μm thick coating. The EIS data confirmed, as expected, that a 2.40 μm Al₂O₃ layer ensures the best corrosion protection after 168 h of immersion in the very acidic environment used.     

稀土硼锆在HPb59-1黄铜中的细化变质效果

研究了微量稀土、硼、锆对HPb59-1合金的细化变质作用.结果表明:0.0001%～0.001%的硼具有显著细化变质效果;0.03%～0.05%稀土也能消除铸态柱状晶,但细化晶粒能力远小于微量硼;微量锆细化变质效果不明显.高温(680℃×40min)组织显示,稀土、锆及过量硼的添加,均提高合金α→β转变温度,从而影响热加工性能.     

微量硼在HPb59-1黄铜中的细化变质作用

研究了微量硼对HPb59-1合金的细化变质作用。结果表明:0.0001%￣0.0010%的硼具有显著细化变质效果,使发达的柱状晶转化为30￣50μm的等轴晶;高温(680℃×40min)组织显示,微量硼的铸态细化变质组织在高温有较好的热稳定性,对α→β转变影响较小。但过量硼的添加,将减缓α→β转变,提高转变温度,从而影响热加工性能,为此,硼添加量应小于0.001%。     

新型铜合金铸造添加剂对HPb59-1组织和性能的影响

研制了一种新型铜合金铸造添加剂。研究了不同的添加剂加入量对HPb59-1铸态组织和性能的影响,及在不同截面尺寸和不同铸造方法条件下的使用效果。结果表明,不加铜合金铸造添加剂时HPb59-1的铸态组织主要由粗大的α和β相组成,加入添加剂后组织变为细小片状或等轴晶,明显改善铅黄铜的组织形态,有效的细化铅黄铜的组织;加入0.02%的添加剂可以提高铅黄铜的力学性能20%以上;添加剂对不同截面尺寸和不同铸造方法得到的铸件组织,均有较好的细化效果。     

HMN59-2-1合金的新型本构关系

HMN59－2－1是近年来轿车用的同步器齿环的主要合金之一。本文通过在Gleeble-1500热模拟机上的模拟试验，系统地研究了锻造热参数（变形速度、变形温度、变形程度）与HMN59－2－1合金流动应力的数值关系，并且通过其真实σ－ε曲线，采用数理统计原理科学地分析并回归出了能综合反映锻造热力参数对材料成形性能影响的本构方程，为HMN59－2－1合金锻造的数值模拟和锻造热力参数的合理制订了与控制提供了基础。     

On a new class of analytic functions associated with conic domain

The aim of this paper is to generalize the conic domain defined by Kanas and Wisniowska, and define the class of functions which map the open unit disk E onto this generalized conic domain. A brief comparison between these conic domains is the main motivation of this paper. A correction is made in selecting the range interval of order of conic domain.     

基于要素差值分析的探空系统比对研究

为比较59-701探空系统和L波段探空系统的探测性能,确定高空气象探测系统换型前后可能存在的系统差异,利用安徽省阜阳高空气象站60次的同步对比探测数据,运用计算两组数据平均差、标准差比较的方法,对实地探测的气象要素值进行分析,找出它们之间的性能差异.结果表明：两套探空系统,在位势高度和温度上差异较小,数据比较接近;在湿度上,59-701探空系统滞后误差较大,湿度变化比较平稳,曲线较均匀;在风向、风速指标上,L波段优于59-701探空系统,随着高度的增加,优势越明显;在测风精度、稳定性上,L波段探空雷达明显提高,59-701探空雷达的测风精度、稳定性相对较差.     

4πβ-4πγ符合外推法测量59Fe比活度

将小型4πβ流气式正比计数器置于大体积4π γNaI(T1)探测器中，组成4πβ-4πγ符合装置，采用效率外推法测量了^59Fe溶液的比活度．研究γ道探测效率很高时符合外推法活度测量准确度的改善情况。结果表明，γ道探测效率的提高，显著减少了活度测量的统计不确定度，有效地缩短效率外推全过程的时间，因此适用于较短寿命放射性核素活度的测量。