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排序方式: 共有678条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(15):21483-21491
To battle the high open-circuit voltage deficit (VOC,def) in kesterite (Cu2ZnSnS4 or CZTS) solar cells, a current field of research relates to point defect engineering by cation substitution. For example, by partly replacing Cu with an element of a larger ionic radius, such as Ag, the degree of Cu/Zn disorder decreases, and likewise does the associated band tailing. In this paper, solution-processed (Ag1-xCux)2ZnSnS4 (ACZTS) samples are prepared through the aprotic molecular ink approach using DMSO as the solvent. The successful incorporation of silver into the CZTS lattice is demonstrated with relatively high silver concentrations, namely Ag/(Ag+Cu) ratios of 13% and 26%. The best device was made with 13% Ag/(Ag+Cu) and had an efficiency of 4.9%. The samples are compared to the pure CZTS sample in terms of microstructure, phase distribution, photoluminescence, and device performance. In the XRD patterns, a decrease in the lattice parameter c/a ratio is observed for ACZTS, as well as significant peak splitting with Ag addition for several of the characteristic kesterite XRD reflections. In addition to the improvement in efficiency, other advantageous effects of Ag-incorporation include enhanced grain growth and an increased band gap. A too high concentration of Ag leads to the formation of secondary phases such as SnS and Ag2S as detected by XRD. 相似文献
2.
《Ceramics International》2019,45(15):18501-18508
The modification and tuning features of nanostructured films are of great interest because of controllable and distinctive inherent properties in these materials. Here, nanocrystalline MoS2 films were fabricated on the stainless steels by a radio frequency magnetron sputtering at ambient temperature. X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction and Raman scattering spectroscopy were used to study the chemical state, chemical composition, crystal structure and vibrational properties of the fabricated MoS2 films. The bias voltage dependent structural evolution and its influence on the optical properties of MoS2 nanocrystalline films were systematically investigated. Besides, the residual stresses of MoS2 nanocrystalline films were explored by employing sin2ψ approach. X-ray diffraction demonstrates that the nanocrystalline MoS2 films have single-phase hexagonal crystal structure. All MoS2 films are polycrystalline in nature. The bandgap values are found to be intensively dependent on bias voltage. Our findings show that the nanocrystalline MoS2 films with different physical properties and intense quantum confinement effect can be realized through adjusting bias voltages. This work may provide deep insight for realizing transitional metal dichalcogenide-based nanostructured film optoelectronic devices with tunable physical properties through a traditional, very cost-effective, and large-scale fabrication method. 相似文献
3.
Cadmium Sulfide and Ferrous doped Cadmium Sulfide thin films have been prepared on different substrates using an electrodeposition technique. Linear sweep voltammetric analysis has been carried out to determine deposition potential of the prepared films. X-ray diffraction analysis showed that the prepared films possess polycrystalline nature with hexagonal structure. Surface morphology and film composition have been analyzed using Scanning electron microscopy and Energy dispersive analysis by X-rays. Optical absorption analysis showed that the prepared films are found to exhibit Band gap value in the range between 2.3, 2.8 eV for Cadmium Sulfide and Ferrous doped Cadmium Sulfide. 相似文献
4.
Adem Sreedhar I. Neelakanta Reddy Qui Thanh Hoai Ta Gitae Namgung Eunbin Cho Jin-Seo Noh 《Ceramics International》2019,45(6):6985-6993
In this paper, novel morphology correlation between silver nanowires (AgNWs) and cobalt (Co)-doped ZnO (Co-ZnO) flake-like thin films (nanowire/flake-like) has been proposed for enhanced photoelectrochemical (PEC) water splitting activity. Here in, high-quality AgNWs/Co-ZnO heterostructures enabled superior visible light water splitting activity compared to the pure ZnO and AgNWs/ZnO. To address the strategic effect of AgNWs coupling and transition metal (Co-2?at%) doping into the ZnO host lattice, we have carried out the X-ray diffraction, field emission scanning microscopy, X-ray photoelectron spectroscopy, UV–Vis transmittance, water contact angle and PEC analyses. In this way, PEC water splitting activity was mainly examined by linear sweep voltammetry (I-V), amperometric I-t and photoconversion efficiency (η) studies. The experimental results provide clear evidence of morphology correlation between AgNWs and Co-ZnO flake-like structures for strong visible light absorption. Specifically, AgNWs/Co-ZnO composites exhibited significant enhancement in the photocurrent density (7.0?×?10?4 A/cm2) than AgNWs/ZnO (3.2?×?10?4 A/cm2) and pure ZnO (1.5?×?10?6 A/cm2). As a result, detailed AgNWs/Co-ZnO geometry has great potential for photoconversion efficiency (0.73%). In a word, the merits of controllable AgNWs/Co-ZnO heterostructure are proposed to improve the visible light harvesting and charge carrier generation for energy conversion devices. 相似文献
5.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
6.
Sun-Jung Kim Pyeong-Seok Cho Jong-Heun Lee Chong-Yun Kang Jin-Sang Kim Seok-Jin Yoon 《Ceramics International》2008,34(4):827-831
Various compositions of gas sensing films were prepared by the combinatorial deposition of SnO2, ZnO, and WO3 sol solutions and their gas sensing behaviors were investigated. The film composition could be manipulated conveniently via the alternate dropping of different oxide sol solutions. From the correlation between film compositions and gas sensitivities, the selective detection of C2H5OH and CH3COCH3 in the presence of CO, C3H8, H2, and NO2 could be attained. In addition, the discrimination between C2H5OH and CH3COCH3, which is a challenging issue due to their similar chemical nature, becomes possible. This research demonstrates the precise design of the sensor-material composition for the selective gas detection via the combinatorial approach. 相似文献
7.
8.
采用多层光刻工艺结合氩离子铣的混合刻蚀方法,刻蚀高Tc超导YBaCuO/ZrO2(100)薄膜图形,取得了较好的结果。在进行氩离子镜的工艺步骤中,使用普通氩离子铣设备(离子束斑极不均匀),但采取了一定的措施─-使被刻样品在刻蚀台座上可移动,模糊地实现了薄膜的相对"大面积"(直径φ≥20mm)均匀刻蚀─-可同时刻蚀2~3片6mm×10mm薄膜,并且被刻蚀部分表面起伏约在10nm左右。图形样品的最小线条达2μm,其Tc、Jc人与刻蚀前薄膜的Tc、Jc相当,即:TC为85~90K,Jc~106A/cm2(在77K下)。 相似文献
9.
YANG Guowei 《半导体光子学与技术》1995,(Z1)
DependenceofsurfacemorphologyofCVDdiamondfilmsondepositionconditionsYANGGuowei(Dept.ofPhys.,XiangtanUuiversity,Xiangtan411105... 相似文献
10.
用电流控制液相外延(CCLPE)方法首次在(100)InP衬底上成功地生长出In1-xGaxAsyP1-y(0.30<x<0.47,0.70<y<0.96)外延层,并对外延层特性进行了详细研究,提出在InP衬底上生长电外延层的机理,推导出生长动力学的理论模型,该模型与上述实验结果十分吻合。 相似文献