Electroactive polymers containing 3-arylcarbazolyl units as hole transporting materials for OLEDs

Monomers and their polymers containing 3-arylcarbazolyl electrophores have been synthesized by the multi-step synthetic route. The materials were characterized by thermo-gravimetric analysis, differential scanning calorimetry and electron photoemission technique. The polymers represent materials of high thermal stability having initial thermal degradation temperatures in the range of 331–411 °C. The glass transition temperatures of the amorphous polymeric materials were in the rage of 148–175 °C. The electron photoemission spectra of thin layers of monomers showed ionization potentials in the range of 5.6–5.65 eV. Hole-transporting properties of the polymers were tested in the structures of organic light emitting diodes with Alq₃ as the green emitter. The device containing hole-transporting layers of polyether with 3-naphthylcarbazolyl groups exhibited the best overall performance with a maximum current efficiency of 3.3 cd/A and maximum brightness of about 1000 cd/m².     

The effect of ambient temperature on the sensitivity of hot-cathode ionization gauges

We measured the sensitivities of five hot-cathode ionization gauges for ambient laboratory temperatures between 23 and 31 °C. All of the ionization gauges exhibited very similar behavior, and the sensitivity could be adequately modeled with a linear function of temperature. The slopes of the fits were smaller than one would expect due to changes in the calibration chamber number density. The thermal transpiration effect, due to local heating of the gauge structures, can account for this, and a characteristic gauge tube temperature can be inferred from the temperature dependence of the sensitivity. A recent comparison of the high vacuum standards of several National Metrology Institutes (NMIs) was performed over the range of 10⁻⁶-10⁻³ Pa using hot-cathode and spinning rotor gauges as transfer standards. Among the participants, laboratory temperatures varied by as much as 5 °C. It is necessary to know how laboratory temperature affects the sensitivity of the hot-cathode transfer standards (spinning rotor gauges explicitly account for the gas temperature) so that individual laboratory results can be corrected to a common temperature.     

Effect of gas mixing ratio on gas-phase composition and etch rate in an inductively coupled CF4/Ar plasma

In this work, we carried out investigations aimed at understanding the effect of gas mixing ratio on plasma parameters, gas phase composition and etch rate in CF₄/Ar inductively coupled plasma. For this purpose, a combination of experimental methods and modelling was used. Experiments showed that electron temperature and electron density are not very sensitive to variations of Ar content in CF₄/Ar plasma. From a zero-dimensional plasma model, the densities of both neutral and charged particles change monotonically. The analysis of surface kinetics based on an ion-assisted etching mechanism showed the possibility of non-monotonic etch rate behaviour due to a concurrence of chemical and physical etching pathways.     

峒室爆破CAD设计方法研究

本文对峒室爆破断面布药计算机辅助设计参数驱动方法进行了探讨围绕断面布药主要参数的变化，提出一种基于参数驱动的计算机辅助设计方法，利用ｗｉｎｄｏｗｓ操作系统下的动态数据交换特性，对断面布药进行布药参数优化，实现了交互调整布药，形成一套断面布的计算机软件，为工程爆破设计实现计算机提供了一种可行的方法。     

阴极爆炸发射电子电离气体原初过程的动力学模拟

基于阴极爆炸发射电子和电子对气体的碰撞电离模型 ,用胞中粒子 (PIC)模拟方法对单间隙冷阴极气体放电过程中阴极爆炸发射产生的电子和电子碰撞电离产生质子的动力学特性进行了研究。分别给出了在 1.33× 10 - 2 Pa氢气压和 10kV间隙电压下 ,气体放电过程中电子和质子的空间和相空间分布、速度统计分布以及轴线上电荷密度分布 ,分析了阴极爆炸发射电子电离过程。模拟结果表明 ,间隙中电子的最大速度达 5 .8× 10 7m/s ,而只有少数的气体电离产生的质子最大速度达到 1.3× 10 6 m/s。     

压水堆硼稀释事故的计算

一、概述核电厂压水堆的初始过剩反应性是通过控制捧、固体可燃毒物和溶解在主回路冷却剂中的硼酸等三种方式联合控制的。随着反应堆的燃耗和裂变毒物的积累,堆的过剩反应性不断减少,需要通过化容系统,控制硼酸的浓度来进行补偿。如果化容系统发生故障或操作员误操作,就会给回路注入无硼或低于规定浓度的补给水,给反应堆引入正反应性,造成硼稀释事故。按核安全法规的要求,应对换料、冷停堆、热停堆和启动等工况进行计算,并要求在这些     

HHD型核子秤电离室物理性能检测

HHD型核子秤电离室已成功地使用于HCS型核子秤.对它的各种物理性能指标进行了检测,各项性能指标都达到了设计要求。     

Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion

Eight diazoles were investigated as corrosion inhibitors of mild steel in 1 M hydrochloric acid using gravimetric and polarization techniques. It was found that the inhibition efficiency increased with the increase of organic substrate concentration, while the adsorption followed the Frumkin isotherm. A correlation between the electronic parameters (induction and mesomeric effects of the substituents, ionization potential values) as well as those of the chemical structure (molecular area) of diazoles molecules and their inhibiting properties was looked for. The results obtained show that a definite interdependence exists but it is not as simple and straightforward as might be expected.     

万家寨引黄南干线二级泵站出水压力平洞混凝土衬砌裂缝成因与处理

分析引黄南干二级泵站出水压力平洞混凝土村砌裂缝成因以及处理办法