全文获取类型
收费全文 | 216篇 |
免费 | 17篇 |
国内免费 | 81篇 |
专业分类
电工技术 | 3篇 |
综合类 | 6篇 |
化学工业 | 108篇 |
金属工艺 | 5篇 |
机械仪表 | 2篇 |
建筑科学 | 1篇 |
矿业工程 | 21篇 |
能源动力 | 2篇 |
轻工业 | 2篇 |
石油天然气 | 9篇 |
无线电 | 7篇 |
一般工业技术 | 5篇 |
冶金工业 | 30篇 |
原子能技术 | 109篇 |
自动化技术 | 4篇 |
出版年
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 3篇 |
2017年 | 12篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 43篇 |
2012年 | 23篇 |
2011年 | 18篇 |
2010年 | 7篇 |
2009年 | 17篇 |
2008年 | 14篇 |
2007年 | 4篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 14篇 |
1999年 | 8篇 |
1998年 | 5篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 3篇 |
1991年 | 8篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1980年 | 1篇 |
排序方式: 共有314条查询结果,搜索用时 15 毫秒
1.
大块液膜技术处理含六价铬废水 总被引:2,自引:0,他引:2
以磷酸三丁酯(TBP)为载体,煤油为稀释剂,NaOH为反萃剂,采用大块液膜技术处理含95~100mg/LCr(VI)的模拟废水。考察了液膜相用量、载体体积分数及反萃剂浓度对大块液膜过程中Cr(VI)传质过程的影响。结果表明,大块液膜技术对废水中Cr(VI)的去除效果较好。Cr(VI)迁移速率随TBP体积分数的提高而加快。当反萃剂NaOH浓度大于0.5mol/L时,反萃剂浓度对Cr(VI)传质过程的影响较小。处理后废水中Cr(VI)含量降至0.5mg/L以下,达到国家排放标准。 相似文献
2.
梯形波脉冲筛板萃取柱传质性能 总被引:1,自引:0,他引:1
本文以UO_2(NO_3)_2—30%TBP(KO)为实验体系,进行了梯形波脉冲筛板柱传质性能的研究。实验中测量了两组分的两相稳态浓度剖面共13组,以扩散模型为基础,求得了梯形波脉冲柱的“真实”传质单元高度HTU_(ox),分散单元高度HDU及表观传质单元高度HTU_(oxp)。通过对实验结果进行分析,选择出了适于本实验体系的较好的操作条件。 相似文献
3.
锝的TBP萃取化学行为研究 总被引:2,自引:0,他引:2
报道了在硝酸体系中用30%TBP-正十二烷萃取Tc(Ⅶ)的实验结果。详细研究了硝酸、硝酸铀酰、硝酸铀(Ⅳ)、硝酸铵、亚硝酸钠、硝酸锆、硝酸钚、硝酸铈,亚硝酰钌、硝酸羟胺、硝酸肼浓度及温度、相比等因素对Tc(Ⅶ)萃取化学行为的影响。实验结果表明,在不含铀的硝酸体系中,硝酸、硝酸铵、硝酸钚、硝酸锆、硝酸铈、亚硝酸酰钌浓度及萃取温度对Tc(Ⅶ)的分配比影响很大,而亚硝酸钠、硝酸肼及硝酸羟胺浓度对Tc(Ⅶ)的分配比影响较小;在含铀的硝酸体系中,硝酸浓度对Tc(Ⅶ)的分配比有影响,而萃取温度、硝酸钚、锆的影响较小。Tc(Ⅶ)在含或不含铀的硝酸体系中,与TBP分别形成UO2NO3·TcO4·2TBP和HTcO4·3TBP萃合物。 相似文献
4.
《Journal of Nuclear Science and Technology》2013,50(3):185-186
Fundamental investigations on valence control and solvent extraction of americium were carried out to develop a method for americium separation from reprocessing solution. In order to adjust americium valency from III to IV and VI, (NH4)10P2W 17O61 synthesized was used as complexant stabilizing Am(IV). Oxidation behavior of americium was investigated as a function of (NH4)10P2W 17O61 americium ratio. Using 0.1M (NH4)2S2O8 and 0.01M AgNO3 as oxidation reagent, Am(IV) was obtained quantitatively at the ratio of 15. On decreasing the ratio to 0.6, 92% of americium was adjusted to Am(VI). The concentration of (NH4)2S2O8 could be reduced to 1/15 compared to the previously reported method in which no complexant was used. Americium(IV) was also prepared by reacting O3 and AgNO3 but no Am(VI) was obtained even at low (NH4)10P2W 17O61 to americium ratio. Americium(VI) could be extracted by tri-n-butyl phosphate stably without influence of (NH4)10P2W 17O61. The distribution coefficient of Am(VI) was 4 between 100% tri-n-butyl phosphate and 1 M nitric acid, and separation factor from Nd(III) was 50. With regard to the americium separation method which implemented valence control followed by extraction, adding (NH4)10P2W 17O61 led to minimization of waste volume and improvement of extraction efficiency. 相似文献
5.
6.
7.
以铪钛富集渣为原料,经硝酸溶解后采用TBP进行铪的萃取分离试验,主要考察铪钛质量浓度、有机相初始酸度、萃取时间、水相初始酸度、相比等对铪钛分离的影响,同时进行了不同浓度硝酸洗涤试验,以萃取和洗涤得到数据为基础进行了分馏萃取理论级数的计算。结果表明,最优萃取条件为:铪钛总质量浓度2.8g/L、有机相初始酸度3.1mol/L、萃取时间6min、水相初始酸度6.5mol/L、相比1∶1,铪、钛萃取率分别为84.8%和5.1%,铪、钛分配比分别为5.6和0.054,萃取分离系数β_(Hf/Ti)=104。选用10mol/L硝酸洗涤TBP载铪有机相,得到洗涤β_(Hf/Ti)=105,基本与β_(Hf/Ti)保持一致,经计算分馏萃取分离铪钛需要萃取级数3级,洗涤级数4级。 相似文献
8.
A solution containing oxalate complexes of rare earths, yttrium and iron (III) is obtained during the processing of wet process phosphoric acid for uranium recovery by solvent extraction. A process is described to recover oxalic acid from such a solution. The process is based on the conversion of iron (III) oxalate into calcium oxalate by calcium chloride followed by the metathesis of calcium oxalate with sulphuric acid to produce calcium sulphate and free oxalic acid. Data is presented to illustrate the influence of various parameters such as pH, temperature, digestion time and amount of calcium chloride on effective conversion of calcium oxalate. Under optimized conditions of pH 1, digestion time 2 h, twice the stoichiometric ratio of calcium chloride at ambient temperature (30±1°C) the recovery of calcium oxalate was found to be >94%. An overall schematic material balance flow -sheet for treating the oxalate solution of rare earths, yttrium and iron (III) to oxalic acid recovery has been presented. An improvement in the second cycle of patented process flow-sheet based on 1.5 M D2EHPA + 0.2 M TBP incorporating oxalic acid scrubbing / recycle for uranium recovery from phosphoric acid has been tested and found to be simple in terms of operations and capable of meeting product specifications.. 相似文献
9.
Straight‐chain N,N‐dihexyloctanamide (DHOA) and branched‐chain N,N‐di(2‐ethylhexyl)isobutyramide (D2EHIBA) have been identified as promising alternatives to tri‐n‐butylphosphate (TBP) for the reprocessing of spent uranium based fuels, and selective extraction of 233U from irradiated thorium fuels, respectively. The present work deals with the effects of different hydrodynamic parameters such as viscosity, density, and interfacial tension (IFT) on the phase‐separation time (PST) under uranium and thorium loading conditions. The IFT values have been determined under varying experimental conditions such as the aqueous nitric acid concentration, n‐dodecane purity, ligand concentration, and thorium/uranium loading conditions. These studies have suggested that the quality of n‐dodecane affects the IFT values of different solutions. The IFT values of D2EHIBA changed marginally (23.3 ± 0.9 mNm?1) against THOREX feed solution for the wide range of D2EHIBA concentration (0.1–1.0 M). However, IFT, viscosity, and PST values increased with uranium loading of 1.1 M DHOA. These studies suggested that a lower phase‐disengagement rate with increased uranium loading was mainly due to the increased viscosity of the loaded 1.1 M DHOA solution. 相似文献
10.
A NEW PROCESS FOR THE EXTRACTION OF PENICILLIN G FROM THE FILTRATE OF FERMENTATION BROTH WITH TBP IN BUTYL ACETATE
下载免费PDF全文
![点击此处可从《中国化学工程学报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The mixture of neutral phosphorus esters and butyl acetate (BA) can be used, as the extractant for the extraction of penicillin G. The extraction equilibrium pH can be increased to pH3—4 due to the stronger extraction capability of the solvent mixture, instead of pH1.8—2.2 with butyl acetate as solvent. The experimental results indicate that the total recovery of penicillin G can reach 96.6% with the new extraction process, which is 5—6% higher than that obtained with the traditional process using BA as solvent at pH1.8—2.2. 相似文献