带语音功能的高精度可遥控测温仪设计

采用高精度数字温度传感器LM74和数字语音芯片ISD25120厦无线电收发模块设计了一种带语音功能的可遥控测温仪。文中介绍了测量记录仪的设计与应用，包括高精度数字温度传感器LM74的特点及其与单片机的接口技术，介绍了软件设计流程，并给出了部分参考程序。     

FTIR investigation of ethylene coordination and polymerization on reduced Cr/SiO2 catalyst

FTIR spectroscopy was applied to study the initial steps of ethylene polymerization on reduced chromia-silica (0.5 wt% Cr/SiO₂). To decrease the speed of the reaction small doses of gas were introduced to the catalyst in each run and C₂D₄ was used to confirm band assignments. At the initial steps of the reaction only ethylene molecules coordinated to probably Cr _A ²⁺ cations were observed. The concentration of such complexes was estimated to be about 50% of the total amount of Cr atoms in the sample. The FTIR spectrum of the polymer formed at the initial doses of C₂H₄ (when [C₂H₄] [Cr]) was found to be slightly different from that formed after excess ethylene was introduced onto the catalyst ([C₂H₄] > [Cr]).     

Detection of the First Epoxyalcohol Synthase/Allene Oxide Synthase (CYP74 Clan) in the Lancelet (Branchiostoma belcheri,Chordata)

The CYP74 clan cytochromes (P450) are key enzymes of oxidative metabolism of polyunsaturated fatty acids in plants, some Proteobacteria, brown and green algae, and Metazoa. The CYP74 enzymes, including the allene oxide synthases (AOSs), hydroperoxide lyases, divinyl ether synthases, and epoxyalcohol synthases (EASs) transform the fatty acid hydroperoxides to bioactive oxylipins. A novel CYP74 clan enzyme CYP440A18 of the Asian (Belcher’s) lancelet (Branchiostoma belcheri, Chordata) was biochemically characterized in the present work. The recombinant CYP440A18 enzyme was active towards all substrates used: linoleate and α-linolenate 9- and 13-hydroperoxides, as well as with eicosatetraenoate and eicosapentaenoate 15-hydroperoxides. The enzyme specifically converted α-linolenate 13-hydroperoxide (13-HPOT) to the oxiranyl carbinol (9Z,11R,12R,13S,15Z)-11-hydroxy-12,13-epoxy-9,15-octadecadienoic acid (EAS product), α-ketol, 12-oxo-13-hydroxy-9,15-octadecadienoic acid (AOS product), and cis-12-oxo-10,15-phytodienoic acid (AOS product) at a ratio of around 35:5:1. Other hydroperoxides were converted by this enzyme to the analogous products. In contrast to other substrates, the 13-HPOT and 15-HPEPE yielded higher proportions of α-ketols, as well as the small amounts of cyclopentenones, cis-12-oxo-10,15-phytodienoic acid and its higher homologue, dihomo-cis-12-oxo-3,6,10,15-phytotetraenoic acid, respectively. Thus, the CYP440A18 enzyme exhibited dual EAS/AOS activity. The obtained results allowed us to ascribe a name “B. belcheri EAS/AOS” (BbEAS/AOS) to this enzyme. BbEAS/AOS is a first CYP74 clan enzyme of Chordata species possessing AOS activity.     

7175铝合金锻件毛坯高温均匀化处理工艺研究

对7175铝合金大型锻件生产过程中的关键工艺－－高温均匀化处理进行了研究；分析了锻造毛坯经过高温处理和未经高温处理的锻件的组织、性能差别及其机理。     

Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings

Expandable graphite (EG) coating and ammonium polyphosphate-pentaerythritol-melamine (APP-PER-MEL) coating were prepared. Thermal degradation and char formation of the coatings were investigated by differential thermal analysis (DTA), thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results have shown that the anti-oxidation and fire-resistant properties of expandable graphite coating containing EG with size of 74 μm are better than those of APP-PER-MEL coating. The static immersion test was applied to study water resistance of the coatings, and the fire protection test and mechanical test were used to analyse heat insulation and mechanical properties of coatings before and after water immersion. The fire-resistant and mechanical properties of APP-PER-MEL coating were severely damaged by water immersion, whereas EG coating containing 8.5% EG with size of 74 μm could retain the good fire resistance even after 500 h water immersion.     

Synthesis, fabrication and characterization of poly[3-3′(vinylcarbazole)] (PVK) Langmuir-Schaefer films

Poly[3-3′(vinylcarbazole)] (PVK) was synthetized with N-vinylcarbazole as monomer by oxidative polymerization with ferric chloride. The resulting polymer was then deposited on various solid supports by using Langmuir-Schaefer (LS) method. The pressure-area isotherm of PVK revealed the possibility of compact monolayer formation at air-water interface. Different layers of PVK were doped with iodine vapours. Both scanning probe microscopy and optical microscopy images indicated a good uniformity of the films. The morphology and the thickness of PVK films were investigated using atomic force microscopy. The voltammetric investigation of I₂ doped PVK showed a distinctive electrochemical behaviour. The photoinduced charge transfer across a donor/acceptor (D/A) hybrid interface provided an effective method to study the photoelectrochemical properties of the composite LS films.     

NC74-1型氨合成催化剂的升温还原及应用

介绍了NC74-1氨合成催化剂在山东华鲁恒升化工股份有限公司大氮肥氨合成的装填、升温还原及使用情况。     

球缺形药型罩形成EFP的数值模拟及其优化设计

利用ANSYS/LS-DYNA软件对球缺形药型罩形成EFP的过程进行数值模拟,着重分析药型罩厚度和装药的长径比L/D对EFP成型的影响.通过观察EFP成型过程图和分析EFP节点的速度曲线图,得到EFP的成型过程与理论分析相符合.在药型罩厚度增加时EFP的速度不断减小、头部越来越钝,随着装药的长径比L/D增大,EFP的速度也在增大,达到L/D=1.75后速度增长减慢.在装药半径为6.5cm的EFP战斗部中的最优设计参数为：药型罩厚度为0.4cm,装药的长径比L/D为1.5.     

基于DS18B20的多点测温扩展模块

针对目前广泛应用的DALLAS公司的数字温度传感器DS18B20,分析了多点测温电路的缺陷,介绍了一个实现多点测温模块的实现方法。使用DS18B20,配合总线驱动双向三态门74LS245的电路成功实现了多点测温,并给出了编写模块驱动程序的流程,最后说明了多点测温模块适用的场合。     

基于OpenGL的树干模拟与实现

为了解决大自然中不规则的树干逼真模拟,用分形递归和L系统这经典算法实现植物的生长拓扑结构,同时调用OpenGL函数库进行绘制和反走样处理。在VS 2010的环境下,实现不规则树木形态的仿真,并通过实验结果来验证可行性。