Real‐time monitoring by proton relaxometry of radical polymerization reactions of acrylamide in aqueous solution

The potential of time‐domain nuclear magnetic resonance (TD‐NMR) for the real‐time monitoring of solution radical polymerizations is demonstrated. A model system composed of a redox‐pair initiator system, acrylamide as monomer and water as solvent was investigated. A second‐generation continuous wave free precession technique was employed to measure the longitudinal relaxation time constant (T₁) of the samples throughout the polymerization reactions. This parameter was shown to be sensitive to the reactant feed free‐radical enhancement of the water molecule relaxation time, making it a good probe to monitor monomer conversion in real time in an automated, non‐destructive fashion. It was found that the T₁ value was better than the transverse relaxation time constant (T₂) for describing the evolution of the polymerization reactions, due to its greater sensitivity to paramagnetic effects. The TD‐NMR signal variation observed was linked to the formation, propagation and termination steps of the radical polymerization kinetics scheme. These first results may contribute to the application of real‐time monitoring of radical polymerization reactions employing low‐cost and robust TD‐NMR spectrometers. © 2018 Society of Chemical Industry     

基于循环前缀的单载波直接序列扩频技术(CP/CDMA)

介绍了下行链路中基于循环前缀的单载波直接序列扩频技术(CP/CDMA)。这种技术结合了多载波系统中的循环前缀和频域均衡,具有较低的复杂度。同时保留了单载波系统发射端复杂度低的优点。在时变信道中,利用基于辅助数据的信道估计方法,即每隔一定帧数的数据帧发送一帧训练序列来估计信道。在仿真中使用了信道编码。     

微量Ag对CP276合金性能和组织的影响

研究添加不同含量的Ａｇ对ＣＰ２７６合金的拉伸性能和时效组织的影响。对拉伸强度、延伸率测试及透射电镜观察表明：０．１１ｗｔ％加入可促进Ｔ１相析出，使合金强度值升高；０．３５ｗｔ％Ａｇ的加入可在时效前期生成富Ａｇ、Ｍｇ的稳定的ＧＰ区，从而降低合金中Ｃｕ的固溶度，阻碍Ｔ１相析出，时效后期，ＧＰ区分解，生成大量Ｔ１相，使合金强度值显著升高。     

CDMA位置服务系统的本地定位平台建设

移动位置业务是移动通信网络的一项特色增值业务．将成为今后几年的业务增长亮点之一。中国联通总部的增值业务部于2002年采用集中设置方案，进行了CDMA位置服务系统一期工程的建设。本地定位平台建立于中国联通CDMA位置服务系统基础之上．其功能由以下的一项或多项组合而成：门户功能、中间件功能、GIS系统的的功能和对本地的CP进行管理和计费的功能。     

Effect of functional group of ferrocene redox substance on the transport properties of newly designed ion exchange membrane prepared from polymer gel

A different newly designed cationic exchange polymer membrane and anionic exchange polymer membrane were introduced, and also the transport properties of these polymeric membranes were investigated in this study. The transport properties of these polymer membranes in contact with ferrocene redox derivatives were estimated by using electrochemical techniques such as cyclicvoltammetry, chronopotentiometry, and chronoamperometry techniques, respectively. The used ferrocene redox substances, which have different functional groups, were (Ferrocenylmethyl) trimethylamonium iodide, FcMA, Ferrocenedimethanol, FcDM, and Ferrocene carboxylic acid, FcCA. It indicated that the performance of a membrane depended on the content of polymer gel, anionic exchange polymer site (20 wt % and 50 wt %) or cationic polymer exchange site (20 wt % and 50 wt %), and the efficiency of the functional groups of cationic and anionic exchange polymer site as well. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

基于Profibus-DP的西门子S7—300 PLC与ABB 800XA数据通信的实现

本文介绍基于Profibus—DP通信协议的西门子S7—300PLC与ABB 800XA系统之间的数据通信。详细描述了分别通过S7—300 PLC CPU的DP接口和CP342—5通信模块与ABB 800XA系统通信两种不同条件下的有关通信配置及实现数据通信的过程。     

西门子CP340与RKC温控仪表的ASC Ⅱ码通信

介绍西门子CP340与RKC温控仪表的ASCⅡ码通信方法，采用轮询方式访问RS-485网络上的每块温控仪表。使橡胶挤出机的温度控制系统处于西门子PLC系统管理之中，方便橡胶挤出机的温控系统的现场维护和监控。     

Photocurrents and degradation rates on particulate TiO2 layers: Effect of layer thickness, concentration of oxidizable substance and illumination direction

Different routes for immobilization of TiO₂ on conducting substrates were compared to find active and stable photocatalysts, which could either be operated in open circuit (photocatalysis) or with applied electric potential (photoelectrocatalysis). The advantage of applying an electric potential was investigated. Polarization curves and photoelectrochemical degradation reactions served to characterize catalysts and to find a way of predicting the optimum synthesis conditions. The difference between front side (EE) and back side (SE) illumination is discussed as a function of layer thickness, as well as the influence of oxidizable substance concentration on photocurrents. Stability of catalysts was investigated in repetitive degradation experiments.     

P(MMA-DBMEA)乳液聚合研究

甲基丙烯酸甲酯 ( MMA)在无皂乳化剂条件下 ,加入少量的功能性单体 N,N一二甲基 ,N-丁基 ,N-甲基丙烯酰氧乙基溴化铵 ( DBMEA) ,合成了稳定的 P( MMA-DBMEA)共聚物乳液 .该共聚物乳胶粒呈现单分散分布。同时用 NMR研究了共聚物 ,并对 P( MMA-DBMEA)聚合物13 C进行了全归属。