Free energy and confinement force of macromolecules in a slit at full equilibrium with a bulk solution

Nondilute athermal and theta solutions of nonadsorbing flexible macromolecules in equilibrium with repulsive slit-like pores were examined by the lattice Monte Carlo simulations. The free energy of confinement ΔA/kT and the force f/kT exerted by polymers on the slit were computed as a function of the slit width D in a wide range of bulk concentrations φ. The free energy and force profiles in nondilute solutions were found to deviate considerably from the ideal chain theory; the perturbation of chains by a presence of the slit walls were substantially reduced in nondilute solutions. The free energy and force functions appropriate for nondilute solutions were derived by fitting the simulation data. Further, the relative pressure p_I/p_E exerted by the nonadsorbing confined molecules on the slit walls was calculated. The depletion effect relevant to colloid stabilization was found in dilute solutions to be slightly weaker for excluded-volume chains than for ideal chains. The relative pressure equation was modified to cover semidilute solutions, by using the mean-field and scaling expressions of the osmotic pressure. Both the relative pressure p_I/p_E and the intra-slit concentration profiles φ_I(x) in tandem display a suppression of the depletion effect with increasing φ in simidilute solutions.     

Rock-breaking mechanism and experimental analysis of confined blasting of borehole surrounding rock

The rock-breaking mechanism and effect of confined blasting were analysed by blasting and impact dynamic mechanics, fluid dynamic mechanics, fracture mechanics as well as blasting experiment. The results showed that the fracturing of surrounding rock in confined blasting condition is the result of coaction of rock pre-cracking by shock wave and stress wave and the continuing expanding crackenhancement of confined medium, and the model of crack development of borehole surrounding rock in confined blasting condition was established. This study acquired the damage range of surrounding rock under the action of shock wave and stress wave, as well as the crack development characteristics of surrounding rock after the wedge-in confined medium into the crack space. Deep-hole confined blasting experiment on large rock showed that the high-efficient utilisation of in-hole explosive was achieved and the safety of rock blasting operation was ensured. Safe static rock-breaking under the action of high-efficient explosive blasting was achieved as well as the unification of super dynamic load of explosive blasting and static rock-breaking of water medium.     

Extraction of locked-up coal by strengthening of rib pillars with FRP——A comparative study through numerical modelling

In some of the coalfields in India, coal seams are only developed but no extraction of pillars is possible due to the presence of surface or sub-surface structures and also non-availability of stowing materials which leads to huge amounts of coal being locked-up underground. Spontaneous heating and fire, accumulation of poisonous gases, severe stability issues leading to unsafe workings and environmental hazards are the major problems associated with the developed coal pillars. So, there is a pressing need for a technology for the mining industry to extract the huge amount of coal locked-up under different constraints. In this study, the locked-up coal is proposed to be extracted by artificially strengthening the rib pillars. The detailed comparative study is carried out to know the increase of extraction percentage of locked-up coal by strengthening the rib pillars with FRP. Extraction methodology is designed and studied through numerical modelling for its stability analysis to evaluate its suitability of application in underground.     

Measurement and analysis of low-acceleration and long-duration longitudinal events using delivery van

This study investigates longitudinal acceleration events during freight transportation characterized as low-acceleration and long-duration using delivery van type vehicles. In the past several decades, there has been an increase in shipments requiring only single or small pallet load quantities and mixed palletized unit loads comprised of different goods. These loads are often transported in delivery vans without load securing devices, increasing the risk of product loss and damage due to load failures resulting from unit loads shifting. A field data acquisition system was used to observe and record the random acceleration events from five vehicles for 5 days, explicitly targeting the vehicles' braking and acceleration manoeuvres. The study aimed to understand the physical phenomenon and provide new information that can be used during preshipment tests to prevent damage to goods and ensure unit load integrity is maintained throughout the supply chain. The events were statistically analysed to understand their probability of occurrence, severity level, and quantify critical parameters such as event rise and hold times. For the braking manoeuvre, the statistical mean of average deceleration was 0.25 g with a corresponding rise and hold duration of 0.83 and 1.27 s, respectively. During the vehicle's acceleration manoeuvre, the statistical mean of average acceleration was 0.29 g with a rise and hold time of 1.29 and 1.39 s, respectively. Utilizing the field data, composite profiles were developed, and these profiles were compared to the currently available test procedures and previous results of other studies.     

Confined acoustic phonons in ultrathin SOI layers

We try to reproduce experimental mobility curves in ultrathin silicon-on-insulator inversion layers using a Monte Carlo simulator and a bulk model for the electron scattering with acoustic phonons. While it is possible to reproduce the experimental behavior for the thicker samples, the electron mobility is strongly overestimated when the thinnest samples are considered. The mobility curves for the thinnest samples can be reproduced using the same model if the deformation potential parameter increases as the silicon thickness decreases. This fact shows that acoustic phonons are also confined in ultrathin silicon on insulator layers. We then study confined phonons in single and three layer structures in order to give a physical motivation to the increase of acoustic phonon scattering rate for in ultrathin silicon layers.     

不同围压条件下钢纤维混凝土受压试验研究

对不同钢纤维体积率的混凝土复合材料在不同围压条件下进行受压试验。针对钢纤雏混凝土在三向应力状态下的强度、变形行为的复杂性,基于试验数据和拟合公式,得出了不同围压和不同钢纤维体积率对钢纤维混凝土峰值强度和应变的影响系数,建立了其峰值应力比、峰值应变比与围压比的关系模型。分析计算结果显示,该模型可以有效的描述不同围压下钢纤维混凝土的力学性能．     

计算机数控系统光滑时间最优轨迹规划

基于控制向量参数化(CVP)方法, 研究了计算机数控(CNC)系统光滑时间最优轨迹规划方法. 通过在规划问题中引入加加速度约束, 实现轨迹的光滑给进. 引入时间归一化因子, 将加加速度约束的时间最优轨迹规划问题转化为固定时间的一般性最优控制问题. 以路径参数对时间的三阶导数(伪加加速度)和终端时刻为优化变量, 并采用分段常数近似伪加加速度, 将最优控制问题转化为一般的非线性规划(NLP)问题进行求解. 针对加加速度、加速度等过程不等式约束, 引入约束凝聚函数, 将过程约束转化为终端时刻约束, 从而显著减少约束计算. 构造目标和约束函数的Hamiltonian函数, 利用伴随方法获得求解NLP问题所需的梯度.     

Self-consistent analysis of the band structure of doped lattice-matched GaNAsBi-based QWs operating at 1.55 μm

Band structures of n–i doped lattice-matched GaNAsBi/GaAs quantum wells are studied theoretically using a self-consistent calculation (based on the envelop function formalism) combined with the 16-band anti-crossing model. Operating at 1.55 μm, these QWs can represent active zones of temperature-insensitive optoelectronic device applications intended for optical fiber communications. We have calculated physical parameters of the structures such as the confining potential profiles, the Fermi level, the subband energies and their corresponding wavefunctions as well as the oscillator strength of inter-band transitions, the subband occupations, and the confined electrons density distributions. Finally, the absorption coefficient spectra of GaNAsBi-based QWs are also computed.     

Experimental study on the confined flow over a circular cylinder with a splitter plate

An experimental study was carried out to investigate the effect of a splitter plate on wake flows downstream of a circular cylinder symmetrically placed in a confined channel. A particle image velocimetry (PIV) measurement was applied to visualize the flow structure and analyze changes in the vortex shedding process. The control elements of the splitter plate length, L/D (D is the cylinder diameter) was varied from 0 to 1.5 and Reynolds number, Re_D was considered at 2400 and 3000. The experimental results showed that the splitter plate had an influence on stabilization of wake turbulences in a confined channel. For shorter splitter plate length of L/D=0.5 and 0.75 cases, flow structures were significantly modified and the vortex shedding frequency decreased as compared with bare cylinder cases. For longer splitter plate length of L/D=1, 1.25 and 1.5 cases, the generation of a secondary vortex was observed based on the snapshot proper orthogonal decomposition (snapshot POD) analysis. In addition, turbulent characteristics corresponding to turbulent kinetic energy (TKE) and Reynolds shear stress correlations took the lowest values and the dominant vortex shedding frequency disappeared. There was an optimal value of the splitter plate length at L/D=1 on suppression of velocity fluctuations. Moreover, the stabilizing effect of a splitter plate was more obvious at Reynolds number of Re_D=3000 than that at Re_D=2400.