Hydraulic reactivity and cement formation of baghdadite

In this study, the hydraulic reactivity and cement formation of baghdadite (Ca₃ZrSi₂O₉) was investigated. The material was synthesized by sintering a mixture of CaCO₃, SiO₂, and ZrO₂ and then mechanically activated using a planetary mill. This leads to a decrease in particle and crystallite size and a partial amorphization of baghdadite as shown by X-ray powder diffraction (XRD) and laser diffraction measurements. Baghdadite cements were formed by the addition of water at a powder to liquid ratio of 2.0 g/ml. Maximum compressive strengths were found to be ~2 MPa after 3-day setting for a 24-h ground material. Inductively coupled plasma mass spectrometry (ICP-MS) measurements showed an incongruent dissolution profile of set cements with a preferred dissolution of calcium and only marginal release of zirconium ions. Cement formation occurs under alkaline conditions, whereas the unground raw powder leads to a pH of 11.9 during setting, while prolonged grinding increased pH values to approximately 12.3.     

Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives

We demonstrate in this study that the combination of modern inline monitoring methods [here: inline nuclear magnetic resonance (NMR)] with simulations gains more exact and profound kinetic results than previously used methods like linearization without that combination. The ¹H-NMR spectroscopic data (more than 100 data points) are used to construct the copolymerization diagram. The reactivity ratios are obtained applying the van Herks nonlinear least square method. The examination of the radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) with (2-{[2-(ethoxycarbonyl)prop-2-en-1-yl]oxy}ethyl) phosphonic acid (ECPPA) as important adhesive monomer used in dentistry yields reactivity ratios of r_HEMA = 1.83; r_ECPPA = 0.42. The copolymerization diagram reflects nonideal, non-azeotropic copolymerization. The sequence distribution of the obtained by Monte Carlo simulation indicates the generation of statistical copolymers. As an important finding, it is demonstrated that the repeating units responsible for etching and adhesion are arranged over the whole polymer chain, which is necessary to achieve proper functionality. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48256.     

Effects of unequal reactivity of functional groups on gelation phenomena in polyurethane systems

A model to describe the effect of unequal reactivity on curing of a diisocyanate with water, polyol and a diol was developed. The model predicts whether a given initial composition would gel or not and the fractional conversions of functional groups at the gel point. It has been shown that the relative speeds of reaction of water and hydroxyl groups can be used to classify water's behaviour as that of a (i) nonreactive diluent (ii) monofunctional blocking agent and (iii) chain extender capable of connecting branch points.     

Electro-copolymerisation of indene and styrene

Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation.     

Age and gender differences in cardiac reactivity and subjective emotion responses to emotional autobiographical memories.

This research reports age and gender differences in cardiac reactivity and subjective responses to the induction of autobiographical memories related to anger, fear, sadness, and happiness. Heart rate (HR) and subjective state were assessed at baseline and after the induction of each emotion in 113 individuals (61 men, 52 women; 66% European American, 34% African American) ranging in age from 15 to 88 years (M = 50.0; SD = 20.2). Cardiac reactivity was lower in older individuals; however, for anger and fear, these age effects were significantly more pronounced for the women than the men. There were no gender differences in subjective responses, however, suggesting that the lower cardiac reactivity found among older people is dependent on gender and the specific emotion assessed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Hyperion, IKONOS, ALI, and ETM+ sensors in the study of African rainforests

The goal of this research was to compare narrowband hyperspectral Hyperion data with broadband hyperspatial IKONOS data and advanced multispectral Advanced Land Imager (ALI) and Landsat-7 Enhanced Thematic Mapper Plus (ETM+) data through modeling and classifying complex rainforest vegetation. For this purpose, Hyperion, ALI, IKONOS, and ETM+ data were acquired for southern Cameroon, a region considered to be a representative area for tropical moist evergreen and semi-deciduous forests. Field data, collected in near-real time to coincide with satellite sensor overpass, were used to (1) quantify and model the biomass of tree, shrub, and weed species; and (2) characterize forest land use/land cover (LULC) classes.The study established that even the most advanced broadband sensors (i.e., ETM+, IKONOS, and ALI) had serious limitations in modeling biomass and in classifying forest LULC classes. The broadband models explained only 13-60% of the variability in biomass across primary forests, secondary forests, and fallows. The overall accuracies were between 42% and 51% for classifying nine complex rainforest LULC classes using the broadband data of these sensors. Within individual vegetation types (e.g., primary or secondary forest), the overall accuracies increased slightly, but followed a similar trend. Among the broadband sensors, ALI sensor performed better than the IKONOS and ETM+ sensors.When compared to the three broadband sensors, Hyperion narrowband data produced (1) models that explained 36-83% more of the variability in rainforest biomass, and (2) LULC classifications with 45-52% higher overall accuracies. Twenty-three Hyperion narrowbands that were most sensitive in modeling forest biomass and in classifying forest LULC classes were identified and discussed.     

Effect of Mineral on Metallurgical Coke Solution Loss Reaction in Blast Furnace

Thecokesolutionlossreactionisoneofthemostimportanteffectsresultingincokepulverizinginblastfurnace .Thefactorswhichaffectreactionincludecokeporestructure ,micro crystalstructureonporewall ,thecontentandconstituentofminer als ,etc .Amongthesefactors ,theconstituentofmineralsisemphasizedallovertheworldinrecentyears .Buttheemphasisofmoststudieswasputontheeffectofalkalimetals (K ,Na)oncokesolutionlossreactionandtheeffectofotherelementswassel domreported[1-5] .Theeffectofthirteenmineralsoncokesolut…     

Testing multi-characteristic product capability indices

Recently, studies associated with testing the quality and performance of each process for a product with multi-characteristics are proposed more often. However, most studies are limited to discussing one single type of quality characteristic. Practically, a multi-characteristic product is potentially composed of three types: smaller-the-better, larger-the-better, and nominal-the-best. In this paper, we propose an integrated product capability index which considers these three different types of quality characteristics. According to the theory of testing hypothesis, we develop a testing procedure for the product capability index to judge whether the process capabilities of total quality characteristics meet the customers’ demands. In addition, the relationship between the product capability index and the yield of the entire product will be introduced. Finally, an example is provided as a practical application.