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排序方式: 共有3862条查询结果,搜索用时 15 毫秒
1.
Sirshendu Guha 《American Institute of Chemical Engineers》2022,68(3):e17505
In continuation to my previous work (Guha S. AIChE J. 2013;59(4):1390-1399), in this work, effects of ionic migration are evaluated for disk region of a rotating ring disk electrode system by numerically solving complex differential equations, developed for mass transfer along with kinetic complication in presence of ionic migration under limiting current condition. The system for simulation is 0.01 M Fe2(SO4)3 solution with H2SO4 as supporting electrolyte. Simulation cases are presence and absence of ionic migration with kinetic complication (oxidation of Fe2+ to Fe3+ under O2 pressure). Results show that concentration boundary layer thickness of reactant Fe3+ reduces appreciably and steady-state disk current reduces substantially in presence of migration. Simulated steady-state disk current in absence of migration case agrees well with published data. Results indicate higher Fe2+ concentration in presence of migration and thereby higher rate of oxidation of Fe2+ to Fe3+ at all rate constant values. 相似文献
2.
C. Busuioc C.D. Ghitulica A. Stoica M. Stroescu G. Voicu V. Ionita L. Averous S.I. Jinga 《Ceramics International》2018,44(8):9433-9441
Bacterial cellulose membranes were employed as templates for calcium phosphates deposition by successive immersion in solutions of Ca(NO3)2·4H2O and (NH4)2HPO4, under ultrasonication. During the wet chemical reaction, mineral phases were loaded on bacterial cellulose fibrils, leading to precursor hybrid composites. These were subjected to a lyophilisation procedure in order to preserve the 3D porous aspect and afterwards to a thermal treatment with the aim of removing the polymeric phase and generating well crystallized structures. Different types of morphologies were achieved by varying the heating rate, as well as the calcination temperature and period. The as-prepared samples and the final ones were investigated from compositional and structural point of view through X-ray diffraction and Fourier-transform infrared spectroscopy and morphologically concerning by scanning electron microscopy. The magnetic properties were also evaluated in order to demonstrate the suitability of the obtained materials for the development of magnetic scaffolds dedicated to hard tissue applications. 相似文献
3.
Recently, in our laboratory a closed form expression for the correlation function of the hard-sphere dimer fluid obtained
from Wertheims multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation was presented by Kim
et al. [2001]. However, it is difficult to apply its expression to perturbation theory and vapor-liquid equilibria calculations,
since it is of very complex form. In this work, we present a simplified expression for the first shell of the radial distribution
function (RDF) of the hard-sphere dimer fluid using a series expansion of the analytical expression. The expansion is carried
out in terms of both the packing fraction and the radial distance. Expressions are also obtained for the coordination number
and its first and second derivatives as functions of radial distance and packing fraction. These expressions, which are useful
in perturbation theory, are simpler to use than those obtained from the starting equation, while giving good agreement with
the original expression results. Then we present an simplified equation of state for the square-well dimer fluid of variable
well width (λ) based on Barker-Henderson perturbation theory using its expression for the radial distribution function of
the hard-sphere dimer fluid, and test its expression with NVT and Gibbs ensemble Monte Carlo simulation data [Kim et al.,
2001]. 相似文献
4.
This paper presents the mass transfer results from an impinging liquid jet to a rotating disk. The mass transfer coefficients were measured using the electrochemical limiting diffusion current technique (ELDCT). Rotational Reynolds number (Rer) in the range of 3.4 × 104–1.2 × 105, jet Reynolds number (Rej) 1.7 × 104–5.3 × 104 and non-dimensional jet-to-disk spacing (H/d) 2–8 were taken into consideration as parameters. It was found that the jet impingement resulted in a substantial enhancement in the mass transfer compared to the case of the rotating disk without jet. 相似文献
5.
This paper considers the axisymmetric steady flow driven by exact counter rotation of two co-axial disks of finite radius.
At the edges of the rotating disks one of three conditions is (typically) imposed: (i) zero velocity, corresponding to a stationary,
impermeable, cylindrical shroud (ii) zero normal velocity and zero tangential fluid traction, corresponding to a (confined)
free surface and (iii) an edge constraint that is consistent with a similarity solution of von Kármán form. The similarity
solution is valid in an infinite geometry and possesses a pitchfork bifurcation that breaks the midplane symmetry at a critical
Reynolds number. In this paper, similar bifurcations of the global (finite-domain) flow are sought and comparisons are made
between the resulting bifurcation structure and that found for the similarity solution. The aim is to assess the validity
of the nonlinear similarity solutions in finite domains and to explore the sensitivity of the solution structure to edge conditions
that are implicitly neglected when assuming a self-similar flow. It is found that, whilst the symmetric similarity solution
can be quantitatively useful for a range of boundary conditions, the bifurcated structure of the finite-domain flow is rather
different for each boundary condition and bears little resemblance to the self-similar flow. 相似文献
6.
改善磁盘阵列性能的方法 总被引:5,自引:0,他引:5
磁盘阵列是解决计算机I/O瓶颈问题的有效方法之一,通过对现有磁盘阵列结构的研究,提出了4种改善磁盘阵列性能的方法,即良分利用磁盘带宽,平衡多盘的负载,减少奇偶检验数据存取时间和磁盘阵列Cache技术等,分析结果表明:在事务处理应用领域,利用Cache来把小写转化为大写可大大改善目前一般情况下,以一道数据大小来作为磁盘的基本存取大小是合适的选择,磁盘阵列负载平衡设计不足是指正常模式下系统请求在多盘间 相似文献
7.
陈籁民 《建筑科学与工程学报》1996,(2)
基圆半径的确定方法,除了用图解法和试算法外,还可用解析法和图解分析法求解。4种方法各有优缺点,设计时要根据具体情况选择。 相似文献
8.
通过对某型杀伤枪榴弹引信所发生的三次弹道炸的原因进行分析,提出用延期索替代延期药盘,并对有关机构进行再设计的对策。 相似文献
9.
传统工艺加工阀体、活门时,对机床的性能要求较高,一般为数控镗床。介绍了一种采用普通镗床加工阀体、活门的工艺方法及蝶阀在厂内装配的工艺方法。 相似文献
10.
Jeong Ho Moon Hak Soo Han Yong Gun Shul Do Hoon Jang Muyng Do Ro Du Suk Yun 《Progress in Organic Coatings》2007
This study relates to the development of coatings for optical discs in high-density digital versatile disc systems (HD-DVD or blue lay disk) that use a high numerical aperture of 0.85 at 405 nm wavelength and have a protective top layer over a primer layer for protection against damage and dust. Ultraviolet-curable raw materials of two acrylic monofunctional monomers ( isobornylacrylate, IBA and tetrahydrofurfurylacrylate, THFA) and two kinds of urethaneacrylate oligomers (OUMD and OUME) have been easily mixed with photoinitiators. Curing rate of these materials was characterized by FT-IR. In case of top coats, VTES (vinyltriethoxysilane) and acrylic acid were added to enhance the abrasion resistance. These two kinds of UV-curable resinous materials having no solvent were synthesized and investigated as means for making a blue ray disk having good optical and mechanical properties. In addition, dynamic characteristics including reflectivity, fluctuation of RF signal and noise level were also investigated. 相似文献