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排序方式: 共有646条查询结果,搜索用时 31 毫秒
1.
Shmuel Borenstain Gil Bar-Haim Keren Goldshtein Gili Cohen-Taguri 《Color research and application》2020,45(6):1153-1169
Investigation of ink formulation options with the purpose to obtain color-gamut-optimal set of Cyan Magenta and Yellow CMY inks is reported. Implementation of the thickness dependent Kubelka-Munk model on multiple ink layers having different and well-defined thicknesses, provides characteristic absorption and scattering (K, S ) spectra of the ink ingredients. These data enable accurate computation of the reflectance spectrum and thus the L*a*b* color coordinates for any given ink thickness or substrate. Pigment materials investigated are quinacridone as magenta, copper-phthalocyanine as cyan, and arylide yellow. Scaling the peak of the absorption band to the number of molecules per unit area for the specific pigments studied in this article provides the molar extinction coefficients, 1.21 × 104 , 4.7 × 104 , and 3.3 × 104 cm2/millimole respectively, regardless of the different ink formulations used, in accord with Avogadro's principle. Having a set of three pairs of K, S spectra is used to compute the color gamut of any CMY color combination in the L*a*b* space as a function of ink layer thickness and formulation. Using an iterative algorithm, a color-gamut-optimal set of CMY inks is obtained. 相似文献
2.
The Nd-doped and Er-doped LuF3 single crystals were grown by the micro-pulling-down method to study their scintillation properties in the vacuum-ultraviolet (VUV) region. The doubly Nd–Er codoped single crystal was grown to study possibility of scintillation performance improvement by energy transfer from Er3+ to Nd3+ ions. The LiF flux was to avoid phase transition below melting temperature. The 1%Nd-doped sample showed the highest overall scintillation efficiency under X-ray excitation which was 7 times as high as that of the LaF3:Nd 8% standard. The leading Nd3+ 5d–4f emission was situated at 176 nm, while the Er3+ 5d–4f emission for Er-doped samples was observed at 163 nm, which better matches the sensitivity of some VUV-sensitive photodetectors. The optimum Er concentration was determined to be around 1–3 mol%. No Er3+ 5d–4f emission was observed for the doubly Er,Nd-codoped sample due to energy transfer from the Er3+ to Nd3+ ions. Slight improvement of the light yield was observed in the doubly-doped sample with respect to the Nd-only doped one. 相似文献
3.
Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid 总被引:2,自引:0,他引:2
A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations. 相似文献
4.
用真空蒸发制备了酞菁氧钒 (VOPc)薄膜 ,并在磁场中进行了热处理。用X光电子能谱、X射线衍射、紫外 可见吸收光谱、原子力显微镜等手段对制备的薄膜进行了表征。结果表明沉积的酞菁氧钒薄膜为α 型 ,成分接近酞菁氧钒的分子式。制备的薄膜在磁场中进行了热处理 ,发现磁场使酞菁氧钒薄膜性质发生改变 :UV VIS吸收谱Q带发生红移 ;XRD谱图衍射峰强度明显增强 ,峰位略有变化 ;原子力显微镜 (AFM)分析发现晶粒大小无明显变化。以上结果说明磁场的存在使得VOPc分子在热处理过程中发生了定向的排列 相似文献
5.
P. Lutsyk J. Misiewicz A. Podhorodecki Ya. Vertsimakha 《Solar Energy Materials & Solar Cells》2007,91(1):47-53
The optical and photovoltaic properties of dichlorotin phthalocyanine (SnCl2Pc) films and SnCl2Pc/pentacene (Pn) heterostructures (HS) have been studied. Weak bands at 1.35, 1.52 and 2.05 eV have been found in absorption and modulated photoreflectance spectra of SnCl2Pc films. These bands can be caused by the formation of charge transfer states. The low concentration of recombination centers of charge carriers has been formed on a free surface of SnCl2Pc films. This concentration essentially decreases at air evacuation before vacuum deposition of a Pn layer. Therefore, interface with an insignificant recombination rate of charge carriers is formed for SnCl2Pc/Pn HS. 相似文献
6.
四异丁氧基镍酞菁的合成及其溶剂效应 总被引:2,自引:0,他引:2
4 异丁氧基邻苯二腈与氯化镍在强有机碱 1 ,8 二氮杂双环 (5 ,4,0 )十一碳烯 7催化下反应 ,合成了四异丁氧基镍酞菁 ,产物经FT -IR、元素分析、UV -Vis吸收光谱和1 H NMR表征了结构 ;并研究了其溶剂效应 ,结果表明 :最大吸收峰波数ν与函数 f(n ,ε)存在一定的线性关系 ,线性相关系数为 0 940 2 ,而Bayliss函数项 (n2 - 1 ) /(2n2 +1 )决定了最大吸收波长 (λmax)的位移变化 ;化合物的λmax在不同溶剂中随聚集程度增加 ,发生一定程度的蓝移 相似文献
7.
8.
The adsorption of cobalt phthalocyanine dye onto activated carbon in a continuous stirred tank adsorber was studied. The variables investigated were: adsorbent mass, adsorbent particle size and fluid flowrate. Several models based on film, pore and surface diffusion were constructed and fitted to the experimental data. Experimental results showed: (i) the increasing importance of the film mass transfer resistance for increasing adsorbent loads; (ii) the increasing importance of the surface diffusion mechanism for increasing adsorbent loads; and (iii) the better discrimination among different models for higher adsorbent loads and lower flowrate. 相似文献
9.
10.
功能分离型光接受体系是由载流子产生层(CGL),载流子传输层(CTL)和载流子阻挡层(UCt)组A成的一种多层光接受体系.本文合成了一系列载流子传输层材料,如吡唑啉、唑和腙的衍生物,并将上述CTL材料与酞菁类CGL材料,按一定涂布工艺制成近红外敏感(780~830nm)的多层光接受体系.通过对样品电照相性能的表征,着重讨论了CGLlCTL界面能级匹配问题及其对体系光导性能的影响。 相似文献