Transport properties of nonelectrolyte liquid mixtures—IV. Viscosity coefficients for benzene,perdeuterobenzene, hexafluorobenzene,and an equimolar mixture of benzene + hexafluorobenzene from 25 to 100°c at pressures up to the freezing pressure

Viscosity coefficient measurements made with an estimated accuracy of ±2% using a self-centering falling body viscometer are reported for benzene, perdeuterobenzene, hexafluorobenzene and an equimolar mixture of benzene + hexafluorobenzene at 25, 50, 75 and 100°C at pressures up to the freezing pressure. The data for each liquid at different temperatures and pressures are correlated very satisfactorily by a graphical method based on plots of 9.118×10⁷ V ^2/3/(MRT)^1/2 versus logV, and are reproduced to within the experimental uncertainty by a free-volume form of equation. Application of the empirical Grunberg and Nissan equation to the mixture viscosity coefficient data shows that the characteristic constant G is practically temperature- and pressure-independent for this system.     

Viscosity Measurements and Correlation of the Squalane + CO<Subscript>2</Subscript> Mixture

Experimental results for the viscosity of squalane + CO₂ mixtures are reported. The viscosities were measured using a rolling ball viscometer. The experimental temperatures were 293.15, 313.15, 333.15, and 353.15 K, and pressures were 10.0, 15.0, and 20.0 MPa. The CO₂ mole fraction of the mixtures varied from 0 to 0.417. The experimental uncertainties in viscosity were estimated to be within ±3.0%. The viscosity of the mixtures decreased with an increase in the CO₂ mole fraction. The experimental data were compared with predictions from the Grunberg–Nissan and McAllister equations, which correlated the experimental data with maximum deviations of 10 and 8.7%, respectively.     

Design of Unskewed Interior Permanent Magnet Traction Motor with Asymmetric Flux Barriers and Shifted Magnets for Electric Vehicles

Abstract

Interior permanent magnet synchronous motors (IPMSMs) are commonly used in electric and hybrid electric vehicles. Nissan Leaf electric vehicle (EV) uses skewed-rotor IPMSM as a traction motor. This motor is considered as a benchmark in this work. Although, skewing improves the torque quality of the motor by reducing the torque ripple, it reduces the average torque and increases the motor manufacturing complexity and cost. This article proposes improvements to the benchmark motor torque quality without skewing. The proposed motor uses the same stator winding and rotor magnet topologies of the benchmark motor with the same geometric constraints and magnet volume. Modifications are applied to the placement of the magnets in the rotor and the shape of the flux barriers to achieve the performance requirements. The design procedure of the proposed unskewed design is illustrated. Moreover, the electromagnetic performance of the proposed design is investigated. The design shows competitive performance in terms of the average torque, torque ripple, cogging torque, and efficiency compared to the benchmark motor. The mechanical integrity of the design is also verified. The proposed design is found to be a suitable alternative to the benchmark traction motor with a reduced rotor weight and without skewing.     

Transport properties of nonelectrolyte liquid mixtures—VII. Viscosity coefficients for isooctane and for equimolar mixtures of isooctane + n-octane and isooctane + n-dodecane from 25 to 100°C at pressures up to 500 MPa or to the freezing pressure

Changes in the high-pressure self-centering falling-body viscometer system, and the new automated data logging system, are described. Viscosity coefficient measurements made with an estimated accuracy of ± 2 % are reported for isooctane and for equimolar mixtures of isooctane + n-octane and isooctane + n-dodecane at 25, 50, 75, and 100°C at pressures up to 500 MPa or to the freezing pressure. The pressure dependence of the results is found to be represented equally well by the recent equation of Makita and by a free-volume form of equation. The Grunberg and Nissan equation gives a good fit to the mixture viscosity coefficient data.     

Total computer control systems in an automobile industry

This article introduces a case of the Nissan Motor Co., Ltd, as an example of how the computer is used in the Japanese automobile industry. The introduction gives a profile of Nissan, followed by a brief explanation for the economics and history, that caused the rapid pace of computerization in Japan. A general outline of the systems and their use at an assembly plant is described. Process control and some future prospects in this field are also discussed.     

日本汽车轻量化发展趋势

目前,车用燃料约占石油消耗总量的35%,汽车排放的CO2_约占人类活动排放CO_2总量的20%。汽车轻量化有助于降低排放、缓解环境压力,已成为世界汽车工业发展的趋势。实施汽车轻量化需采用的主要材料有碳纤维、铝合金、镁合金、钛合金、工程塑料、复合材料和高强度钢等。本文分别以丰田汽车、日产汽车和三菱化学作为日本汽车和化学工业的代表,介绍世界汽车工业强国——日本汽车轻量化的发展趋势。     

Transport properties of nonelectrolyte mixtures. IX. Viscosity coefficients for acetonitrile and for three mixtures of toluene+acetonitrile from 25 to 100°c at pressures up to 500 MPa

A two-coil self-centering falling-body viscometer has been used to measure viscosity coefficients for acetonitrile and three binary mixtures of toluene+ acetonitrile at 25, 50, 75, and 100°C and pressures up to 500 MPa. The results for acetonitrile can be interpreted by an approach based on hard-sphere theory, with a roughness factor of 1.46. The binary-mixture data are well represented by the Grunberg and Nissan equation with a mixing parameter which is pressure and temperature dependent but composition independent.     

Transport properties of nonelectrolyte liquid mixtures—VI. Viscosimetric study of binary mixtures of hexafluorobenzene with aromatic hydrocarbons

Viscosity coefficients for binary mixtures of hexafluorobenzene with benzene, toluene, para-xylene, and mesitylene have been measured along the saturation line at temperatures from 15 to 120°C using specially designed capillary viscometers. Densities were measured using a pyknometer and volume-change apparatus. Deviations of the viscosities from a rectilinear dependence on mole fraction are consistent with enhanced interactions between unlike species, which increase with increasing number of methyl groups on the aromatic hydrocarbon and decrease with increasing temperature. The application of the Grunberg and Nissan equation, the Hildebrand equation, and energy of activation theories to these results is examined.     

Viscosity measurement and modeling of canola oil and its blend with canola stearin in equilibrium with high pressure carbon dioxide

During enzymatic reactions carried out in supercritical CO₂ (SCCO₂) media, CO₂ can expand the liquid reactant mixture, especially lipid-type substances, due to pressure increase and dissolution of CO₂, causing viscosity reduction, and improvement of the diffusion of reactants and products. For better understanding of the transesterification reaction of canola oil and canola stearin in SCCO₂ media, the viscosity of canola oil at 40, 50, 65, and 75 °C and its blend with canola stearin (30 wt%) at 65 °C in equilibrium with high pressure CO₂ was measured up to 12.4 MPa using a rotational rheometer equipped with a high pressure cell. The solubility of CO₂ in canola oil at 40 and 65 °C and its blend with canola stearin at 65 °C was also determined at pressures of up to 20 MPa using a high pressure view cell. The viscosity of canola oil at 40, 50, 65, and 75 °C and its blend with canola stearin at 65 °C decreased exponentially to 87.2, 84.7, 74.8, 66.2, and 74.2% of its value at atmospheric pressure, respectively, with pressure increase up to 12.4 MPa. The viscosity of the samples decreased with an increase in temperature, but the effect of temperature diminished above 10 MPa. The viscosities of CO₂-expanded canola oil and its blend with canola stearin at 65 °C were similar up to 12.4 MPa. The samples exhibited shear-thickening behavior as the flow behavior index reached almost 1.2 at elevated pressures. The mass fraction of CO₂ in canola oil at 40 and 65 °C and its blend with canola stearin at 65 °C reached 24 and 21% at 20 MPa, respectively. The Grunberg and Nissan model was used to correlate the viscosity of CO₂-expanded lipid samples.