添加微量铝对TS-2合成及苯酚羟基化的影响

以硅溶胶为硅源合成分子筛TS 2时 ,在溶胶制备过程中添加微量的铝 ,可以降低模板剂氢氧化四丁基铵 (TBAOH)的用量 ,当TBAOH/SiO2 降低到 0 .1以下时 ,仍然合成了性能优良的TS 2 ,而且用于苯酚过氧化氢羟基化反应过程中催化活性也大大提高。所得催化剂用XRD ,IR ,ICP进行了表征     

A data porting tool for coupling models with different discretization needs

The presented work is part of a larger research program dealing with developing tools for coupling biogeochemical models in contaminated landscapes. The specific objective of this article is to provide researchers with a data porting tool to build hexagonal raster using information from a rectangular raster data (e.g. GIS format). This tool involves a computational algorithm and an open source software (written in C). The method of extending the reticulated functions defined on 2D networks is an essential key of this algorithm and can also be used for other purposes than data porting. The algorithm allows one to build the hexagonal raster with a cell size independent from the geometry of the rectangular raster. The extended function is a bi-cubic spline which can exactly reconstruct polynomials up to degree three in each variable. We validate the method by analyzing errors in some theoretical case studies followed by other studies with real terrain elevation data. We also introduce and briefly present an iterative water routing method and use it for validation on a case with concrete terrain data.     

Connectivity Infrastructure and Components for POCT Environments - Overall Infrastructure

Connectivity infrastructure, hardware and software components for point-of-care testing (POCT) environments at medium-to-large sized hospitals with expected number of POCT instruments in the order of hundreds or thousands are described. The instruments include both network-ready and non-network-ready devices. The latter are connected to the network by means of a hardware-based Instrument Network Adapter. Instrument messages are converted to standardized form and, depending on message content, are routed and delivered to appropriate destinations by a software-based Message Routing System consisting of a Message Router and a Delivery Agent. Target information systems consist of departmental and central information systems.     

International Working Group for Sabotage Concerns of Transport and Storage Casks

Abstract

The International Working Group for Sabotage Concerns of Transport and Storage Casks (IWGSTSC), gathers multiple organisations from different countries (for US party Department of Energy, Nuclear Regulatory Commission, and Sandia National Laboratories; for German party Gesellschaft für Anlagen- und Reaktorsicherheit and Fraunhofer Institut; for the French party Institut de Radioprotection et de Sûreté Nucléaire). The goal of the IWGSTSC is to continue cooperation to improve the analytic capabilities, through information sharing and collaborative research and development plus modelling, to understand the potential adverse public health effects and environmental impacts of radiological sabotage directed at or associated with the transport and storage of civilian nuclear material or other civilian radioactive materials. The Parties may also undertake collaborative research and development in other areas of the physical protection of civilian nuclear materials or other radioactive materials. Since 2000, the IWGSTSC has conducted an extensive test programme for the assessment of the aerosol source term produced in the case of spent fuel transport sabotage by a high energy density device, after having examined several scenarios. The major goal of this programme is to produce an accurate estimate of the so called spent fuel ratio in the domain of respirable, aerosol particles produced. All the reports prepared by Sandia National Laboratories have precisely emphasised the important efforts they have made from the beginning and the amount of work already accomplished. In parallel, the International Atomic Energy Agency (IAEA), assisted by technical experts from different countries, has provided a draft document promised to become guidance for the security of radioactive or nuclear materials during transport. The IAEA document contains general guidance addressed to anyone who intends to implement or improve the security of material transports, but the text is, as of today, limited to rather general recommendations. Based on all the knowledge accumulated from past experiments and also based on the work carried out in Vienna at the IAEA, the IWGSTSC members have decided to work on the development of a method for the evaluation of the vulnerability and the source term. So for doing that, joint projects for the research, development, testing and evaluation of the consequences of the malevolent actions during transport are being pursued and are described in this paper.     

Multipass rolling of aluminium alloys: finite element simulations and microstructural evolution

Abstract

Use of numerical predictive methods such as finite element analysis is becoming progressively more common for modelling industrial hot metal working and forming processes. These tools are used not only to predict the thermomechanical behaviour of metals but increasingly to predict microstructural changes by linking them to physical models of recrystallisation and textural evolution. This paper describes the development and application of a fully integrated model for the prediction of thermomechanical and microstructural behaviour during multipass hot rolling of aluminium alloy AA 3104. Finite element code ABAQUS/standard has been used in the work and the process is modelled assuming plane strain conditions. It is shown that for this alloy the static recrystallisation which occurs during interpass cooling does not significantly influence the thermomechanical response during subsequent rolling passes.     

Super mechano-systems project

The super mechano-system (SMS) project is the Grand-in-Aid for COE Research Project, which started is April 1997 at the Tokyo Institute of Technology for the Creation of New Functionality by the Fusion of Control and Mechanisms, and is supported by the Ministry of Education, Sciences, Sports and Culture. The project aims to establish a new discipline by the functional integration of advanced technologies in mechanisms and control. This paper briefly describes the SMS project.     

Influence of Erroneous Data on the Results of Calculations From Acid–Base Surface Free Energy Theories. III. Solution of a Three-Equation Set in the Case of Homoscedastic Error

The van Oss–Chaudhury–Good theory (vOCGT) was checked for a large artificial set of work of adhesion input data calculated for 15 solids and 300 liquids. Numerical values of LW component and acid (A) and base (B) parameters were assigned to 15 solids. These 15 solids were grouped in 5 sets of 3 solids in each. Also numerical values of LW component and A and B parameters were assigned to 300 liquids (three sets of 100 liquids in each). Data for these solids and liquids were especially selected to represent real types of materials encountered in practice. For all 15 solids and 300 liquids the work of adhesion values were calculated and these values were assumed to be error-free. Next, new values of the work of adhesion were obtained by adding a random homoscedastic error (A vector of random variables is homoscedastic if it has the same finite variance.) of the normal distribution (Also called the Gaussian distribution — it is continuous probability distribution defined by two parameters: the mean and variance (standard deviation squared, σ ²).), belonging to 8 distributions of a mean value equal to the error-free work of adhesion value and standard deviations of 0.5, 1, 2, 5, 7, 10, 15 and 20 mJ/m². The LW components and A and B parameters for these solids were back-calculated for each error level. Two different methods for the solution of a 3-equation set were used and they gave practically the same results irrespective of the error level and liquids and solids used. It was found that there existed a linear correlation between the RMSE (root mean square error) of the solution and the standard deviation of the work of adhesion data. This correlation was highly significant (with a correlation coefficient higher than 0.999) and was true separately for LW component, A and B parameters as well as for the total solution vector (i.e., combinedly for the LW component, A and B parameters). The RMSE values of the total solution vector (having as elements values of the LW component, A and B parameters) as well as separately for LW component and A and B parameters were correlated with the condition number of a given 3-equation set. A very good correlation was found only for the total solution, much worse for A or B parameters, and practically there was a lack of correlation for the LW component. Based on the correlation between the RMSE and the standard deviation of the work of adhesion it was possible to determine what should have been the maximal standard deviation of the work of adhesion if the calculated value of a given LW component or A or B parameter did not differ by more than 1 mJ/m² from an error-free (true) value.     

16—THE PREPARATION,FINE STRUCTURE,AND PHYSICAL PROPERTIES OF PARTLY METHYLATED COTTON FABRICS

Cotton fabric has been methylated under a variety of conditions. The extent of methylation has been shown to be dependent on the time of methylation and on the degree of swelling or disruption of structure. The latter is caused by the alkali pretreatment or by the swelling of the partly methylated cellulose. Fabric physical properties have been measured and the influence of the methylation treatment has been examined.     

一种新颖的分布式光纤喇曼温度传感器信号处理方法的研究

本文首次在分布式喇曼光纤传感技术的信号处理过程中引入去卷积的信号处理方法;通过对传统的和去卷积的两种方法的理论分析、计算机模拟和比较,说明了新的处理方法可以在不压缩驱动脉宽的情况下有效的提高系统空间分辨率,为提高分布式喇曼光纤传感器的空间分辨率开辟了新的途径。