Photo-Fenton removal of water-soluble polymers

This paper presents the results of experiments carried out in a laboratory-scale photochemical reactor on the photodegradation of different polymers in aqueous solutions by the photo-Fenton process. Solutions of three polymers, polyethyleneglicol (PEG), polyacrylamide (PAM), and polyvinylpyrrolidone (PVP), were tested under different conditions. The reaction progress was evaluated by sampling and analyzing the total organic carbon concentration in solution (TOC) along the reaction time. The behavior of the different polymers is discussed, based on the evolution of the TOC–time curves. Under specific reaction conditions, the formation and coalescence of solid particles was visually observed. Solids formation occurred simultaneously to a sharp decrease in the TOC of the liquid phase. This may be favorable for the treatment of industrial wastewater containing polymers, since the photodegradation process can be coupled with solid separation systems, which may reduce the treatment cost.     

Transient analysis of an advanced static var compensator using quad-series voltage-source PAM inverters

This paper deals with an advanced static Var compensator (ASVC) using quad-series voltage-source PAM inverters. The ASVC consists of four three-phase voltage-source inverters with a common dc capacitor and four three-phase transformers, each primary winding of which is connected in series with each other. Each inverter outputs a square-wave voltage, while the synthesized output voltage of the ASVC has a 24-step wave shape. This results not only in a great reduction of harmonic currents and dc voltage ripples but also in fewer switching and snubbing losses. In this paper, transient analysis is performed with the focus on the response of reactive power and the resonance between the dc capacitor and ac reactors. Experimental results obtained from a small-rated laboratory model of 10 kVA are also shown to verify analytical results based on the p-q transformation. The analytical results help in the design of system parameters such as the capacity of the dc capacitor and feedback gains.     

粉状阳离子聚丙烯酰胺的研制

用聚丙烯酰胺胶体,在≥20％浓度的硫酸盐溶液中,进行Mannich反应,经真空干燥后,制取水溶性阳离子型高分子。初步探讨了盐浓度、温度、时间、配比对产物的阳离子度、溶解性的影响。     

气动人工肌肉手臂的神经网络Smith预估控制

针对含时滞d的1关节气动人工肌肉(PAM)手臂,用三层递归神经网络(RNN),建立PAM手臂包含时滞的模型(即非线性Smith预估器),并超前d步预测PAM手臂的输出角度.将此超前d步的预测值作为反馈量,与设定值相比较得到的误差作为PID控制器输入量,实现Smith预估PID控制.同时每一步都用RNN模型当前时刻的输出值与PAM手臂当前时刻实际输出值之差的平方做为RNN权值的在线调整准则对RNN预测模型的权值进行在线调整,以自适应PAM手臂的不确定性和时变性.使用Matlab通过串口和研华亚当模块对实物PAM手臂进行控制,控制效果表明所提出的Smith预估PID控制算法比常规PID控制算法的性能有显著提高,证明所提出的算法是有效的和切实可行的.     

参激随机共振及纠错码技术的应用

为了有效地降低数字信号传输过程中的比特误码率,提出了纠错编码与参数调节随机共振技术的结合.在经过噪声污染后,依据参数调节随机共振技术的性质,给出通过系统参数调节的二进制脉冲幅值调制（PAM）输入信号的渐近误码率公式,应用纠错码技术采用中间值估计的方法得到修正的比特误码率.数字仿真试验证实,理论计算结果与试验结果相吻合,纠错码技术与参激随机共振技术的结合应用于二进制基带信号传输,可以降低误码率,从而可以得到更好的效果,提高通信的可靠性和有效性.     

Degradable Superhydrophilic Iron-Pillared Bentonite Doped with Polybutylene Adipate/Terephthalate Open-Cell Foam: Its Application in Dye Degradation,Removal of Heavy Metal Ions,and Oil–Water Separation

Development of industrialization has brought convenience to people's lives; however, it has also brought serious harm to the environment, where, water pollution is the most obvious. Here, a polybutylene adipate terephthalate (PBAT) open-cell foam doped with iron-pillared bentonite (IPB) is prepared by using sugar as a pore-forming agent and solution phase separation, and then combined with a solution dipping method to coat the foam surface with a polyacrylamide/SiO₂, which makes the PBAT foam superhydrophilic. The static adsorption effect of superhydrophilic IPB-doped PBAT open-cell foam on methylene blue (MB) and Cu²⁺ is studied. The adsorption isotherm fitting shows that the adsorption conforms to the Langmuir model and it has biased toward monolayer adsorption. The adsorption kinetics fitting confirms that the adsorption process is in line with the pseudo-second-order adsorption model, which is dominated by chemical adsorption. The modified PBAT open-cell foam has an adsorption effect on Cu²⁺; however, it has weak cyclic adsorption capacity. It shows a good cyclic adsorption ability for the cationic dye MB and it has >95% photodegradation efficiency of the MB after five time's cyclic adsorption. The superhydrophilicity makes the foam to have better applications in oil–water separation.     

气化炉改用脱油沥青原料系统结垢原因分析及对策

针对气化炉使用脱油沥青过程中出现的结垢问题，重点分析了其原因及机理，介绍了所采取的措施和效果。     

Responses of the reflectance indices PRI and NDVI to experimental warming and drought in European shrublands along a north-south climatic gradient

The aim of this study was to evaluate the use of ground-based canopy reflectance measurements to detect changes in physiology and structure of vegetation in response to experimental warming and drought treatment at six European shrublands located along a North-South climatic gradient. We measured canopy reflectance, effective green leaf area index (green LAIe) and chlorophyll fluorescence of dominant species. The treatment effects on green LAIe varied among sites. We calculated three reflectance indices: photochemical reflectance index PRI [531 nm; 570 nm], normalized difference vegetation index NDVI₆₈₀ [780 nm; 680 nm] using red spectral region, and NDVI₅₇₀ [780 nm; 570 nm] using the same green spectral region as PRI. All three reflectance indices were significantly related to green LAIe and were able to detect changes in shrubland vegetation among treatments. In general warming treatment increased PRI and drought treatment reduced NDVI values. The significant treatment effect on photochemical efficiency of plants detected with PRI could not be detected by fluorescence measurements. However, we found canopy level measured PRI to be very sensitive to soil reflectance properties especially in vegetation areas with low green LAIe. As both soil reflectance and LAI varied between northern and southern sites it is problematic to draw universal conclusions of climate-derived changes in all vegetation types based merely on PRI measurements. We propose that canopy level PRI measurements can be more useful in areas of dense vegetation and dark soils.     

不确定数据聚类的U-PAM算法和UM-PAM算法的研究

UK-means算法在处理不确定数据时对孤立点非常敏感,而且事先必须已知不确定数据的分布函数或概率密度,然而这在实际中往往很难获得。因此,针对UK-means在处理不确定测量数据时的不足,首先提出了基于区间数的PAM不确定聚类算法——U-PAM,该算法用区间数和标准差合理地描述了不确定测量数据的不确定性,进而完成有效的聚类;其次,针对海量不确定测量数据难以聚类的问题,基于U-PAM聚类算法,采用抽样技术提出了处理海量不确定测量数据的算法——UM-PAM算法,该算法先抽样,对样本数据聚类,然后再总体聚类;最后,基于U-PAM算法和CH聚类的有效性指标函数对聚类结果进行分析,以确定最佳聚类数。实验理论表明,所提算法聚类效果明显。     

一种基于PSO&PAM的聚类算法

PAM是最早提出的k-medoids算法之一,该算法比较健壮,比k-means算法鲁棒性更强,但是PAM对初始值敏感,易陷入局部收敛。利用PSO算法对PAM进行优化,提出一种基于PSO和PAM的聚类方法,充分利用PAM和PSO两者对于不同问题的优势,来不断地更新PAM的聚类中心。通过建立基于熵的聚类有效性函数,对混合聚类算法的性能进行客观评价。从来自UCI的数据的测试结果表明,这种混合聚类的方法有较高的聚类正确率。