磷矿的电选试验研究

清水沟中低品位磷矿性质复杂，嵌布粒度细，磨至-0．174mm 92．8％，通过振动—气流联合作用摩擦荷电，采用悬浮电选机经-粗-精-扫电选。可由含P2O5为24．47％的原矿获得含P2O5为30．23％。回收率为83．26％，杂质含量合格的磷精矿。     

低铁耗条件下转炉高碳低磷工艺实践与应用

对转炉炼钢实现低铁耗和高碳低磷工艺进行了分析，介绍了南钢公司转炉炼钢实践低铁耗条件下高碳低磷工艺的具体应用措施。     

Groundwater-surface water interactions and agricultural nutrient transport in a Great Lakes clay plain system

Nutrient export from agricultural land to surface waters is a significant environmental concern within the Great Lakes Basin (GLB). A field-based watershed-scale study was completed to investigate spatial and temporal variations of phosphorus and nitrate to assess nutrient transport pathways and groundwater-surface water interactions in an agriculturally dominated clay plain system. This was conducted in the 127 km² Upper Parkhill Watershed, near Lake Huron in southwestern Ontario, Canada. Data collection occurred from June 2018 to May 2019 via continuous sensor deployment and discrete sampling of stream water, groundwater, hyporheic zone, and tile drainage water. Samples were analyzed for various nutrient species (total, total dissolved, soluble reactive, and particulate phosphorus, and nitrate-N) to examine the hydrological dynamics of principal transport pathways of agriculturally-derived nutrients. Total phosphorus and nitrate concentrations in stream water ranged from 0.007 to 0.324 mg/L and 0.32 to 13.13 mg NO₃^?-N/L, respectively. Tile drainage water total phosphorous concentrations varied from 0.006 to 0.066 mg/L. Groundwater total dissolved phosphorus concentrations ranged from <0.003 to 0.085 mg/L. Transport of phosphorus through tile drainage was observed to be greater than through groundwater over the study period. No distinct relationship was observed between nutrient concentrations in the hyporheic zone and the vertical hydraulic gradient within this zone in the studied stream reach. Preliminary correlations were discerned between water quality observations and recognized land management practices. Given the elevated stream nutrient concentrations, these results are consequential for the continual improvement of strategies and programs devised to conserve water resources within the GLB.     

A phosphorus budget of a poultry farm and a dairy farm in the southeastern U.S., and the potential impacts of diet alterations

Current and potential environmental problems associated with P transport from lands receiving high application rates of animal waste are a major concern. Phosphorus management strategies are needed to reduce P loading on land. This study was conducted to compare on-farm P budgets for a modern broiler farm and a dairy farm under traditional diets and management practices. Phosphorus inputs, recycling and outputs were assessed for both farms. A typical broiler and a dairy farmer from North Carolina were interviewed and pertinent information for the study was obtained, in cooperation with extension agents, and other professionals associated with the farms. The annual on-farm P surplus for the broiler farm was 6,380 kg, while that for the dairy farm was 1,141 kg. This corresponds to an annual application of 65 kg P ha^–1 for the broiler farm and 20 kg P ha^–1 for the dairy farm in excess of removal. The potential for reducing P surpluses by the addition of phytase enzymes and/or the use of low phytic acid corn (Zea mays L.) feed in the broiler farm diet was also assessed. Estimates by animal nutritionists indicate that feed supplementation with phytase enzyme can reduce the broiler farm's P surplus by 33%. The use of low phytic acid corn can reduce the surplus by 49% and a combination of the two can reduce the surplus by 58%. In this study, the incorporation of soybean (Glycine max (L.) Merr.) and alfalfa (Medicago sativa) land into the waste utilization plan of the dairy farm decreases the annual P surplus from 20 to 9 kg P ha^–1. The use of new feed technology and expanding waste application to a larger land base can significantly alter the P budgets of broiler and dairy farms and reduce P surpluses, minimizing the risk of environmental problems.     

Transport of phosphorus forms and of nitrate through a clay soil under grass and cereal production

Many nutrients are lost from soil to water viatile drains. However, there are very few reliable studies of such phosphorus(P)losses under Swedish agriculture practices, especially in connection tofertiliser and slurry applications and related to nutrient balances. Tile drainlosses were measured from nine experimental plots in south-west Sweden; fourplots were measured for 7 years and five plots for 2–3 years. Cereals,mainly spring barley (Hordeum vulgare, L.) and oats(Avena sativa, L.), were grown in six plots, while oneplotwas cultivated with grass, timothy (Phleum pratense L.)andmeadow fescue (Festuca pratensis, L.), one with lucerne(Medicago sativa, L.) and meadow fescue (F.pratensis, L.), and the last one was a set-aside withgrass (Lolium perenne, L. and Trifoliumrepens, L.) that was neither fertilised nor used for crop removal.Attention was paid to the forms in which P was transported to water since thishas important ecological implications. Average losses of particulate P (PP)fromthe set-aside land was significantly lower than from the cerealproduction, but the average losses of soluble reactive P (SRP) and dissolvednonreactive P (DUP) were the same. Average loss of PP from the grass ley during 3years (0.09 kg per ha^–1 y^–1) wassignificantly less than the losses from cereal production. Total P loss of 0.3kg per ha^–1 y^–1 was equal to the averagelossfrom the Swedish monitoring network of observation fields. Compared to theaverage nitrate-nitrogen (NO₃-N) leaching, which was 7 kg perha^–1 y^–1 from cereals, the NO₃-Nleaching was very low from the plots with lucerne-grass and set-aside.After applying and directly ploughing in 80 kg ha^–1 ofsuperphosphate for cereal production in November 1998, 0.6–1.8 kgSRP ha^–1 y^–1 was lost through the drain tiles.Surface application of cattle slurry in spring 1999 to the grass ley alsoresulted in a very pronounced increased base level of SRP. This paper documentsthe importance of applying slurry during dry conditions and of placingfertiliser into the soil according to crop requirements in the time perspectiveof one year.     

19 500 kVA三相6根电极制磷电炉性能考核总结

针对19500 kVA三相6根电极制磷电炉在试生产中出现的炉气温度高、电极位置高,消耗、成本居高不下等现象,通过性能考核,分析了主要原因是入炉焦炭水分高、粒度过大过细,洗涤收磷系统热量不够,电极布置有过热区,操作纪律执行不严格,仪表监测不准等。综合评价了该制磷电炉生产能力和存在问题,提出只有通过对原料质量、操作指标的严格控制、科学管理、整改和完善存在问题,以期该制磷电炉在最佳和优惠工艺条件下运行。     

Groundnut Yield Response to Single Superphosphate, Calcitic Lime and Gypsum on Acid Granitic Sandy Soil

Phosphorus and calcium are the major nutrients limiting groundnut production. The objectives were to determine (a) optimum application levels of P and Ca, and (b) compare the effectiveness of calcitic lime (40% Ca, 4.5% Mg) and gypsum (22% Ca, 17% S) as sources of Ca for groundnut grown on sandy soils. Field experiments were established in smallholder farming areas using four levels of P (0, 8.5, 17 and 34 kg ha⁻¹) combined factorially with calcitic lime (0, 200, 400 and 800 kg ha⁻¹) to give 16 treatments. Similar levels of P were combined factorially with gypsum (0, 100, 200 and 400 kg ha⁻¹) to give sixteen treatments. Experiments were laid in a randomized complete block design with three replications. Phosphorus had a significant effect on groundnut yield at the majority of the experimental sites. Application of P at 8.5 kg ha⁻¹ gave the optimum groundnut yield response. The optimum application rates for calcitic lime and gypsum were 200 and 100 kg ha⁻¹. Gypsum and calcitic lime were not significantly different as sources of Ca for groundnut. Soil chemical properties were significantly improved following application of P and Ca sources.     

贵州省磷化工现状及发展前景

阐述贵州磷资源、煤炭、电力基本情况及在全国的地位和我省发展磷化工的重要意义。介绍我省磷化工生产现状、生产能力、实际产量、产品出口等情况。对世界磷化工产品市场需求，我国和我省的磷化工到2000年的发展情况，达到的目标进行初步援测和构想，并对我省磷化工发展对策进行探讨，提出几点建设性意见。     

Effect of phosphorus on activity of hydrotreating catalyst of Maya heavy crude

The effect of phosphorus on physical properties of the catalyst and on activity of hydrotreating of Maya crude was studied in this work. Catalysts were prepared by the co-impregnation method. Alumina-titania binary oxide was used as a support material. The presence of phosphorus in the catalyst decreases the percentage of micropores, and it results in a decrease of specific surface area. Temperature program reduction (TPR) shows that phosphates reduce metal support interaction. It leads to the formation of polymolybdate phases in expense of strongly bonded tetrahedral molybdates. At higher P loading, polymolybdates may be present with quasi crystalline MoO₃. However, the TPR experiment is not sufficiently sensitive to distinguish several phases present on the catalysts used by the authors. A slight increment of HDM activity is observed, but HDS activity is lower in the P containing catalyst compared with the P free catalyst. The changes of physical properties of the spent catalysts are mainly due to the coke formation on the catalyst. The presence of phosphorus on hydrotreating catalysts inhibits coke formation during the hydrotreating reaction.     

Crop residue,manure and fertilizer in dryland maize under reduced tillage in northern China: I grain yields and nutrient use efficiencies

The rapidly increasing population and associated quest for food and feed in China has led to increased soil cultivation and nitrogen (N) fertilizer use, and as a consequence to increased wind erosion and unbalanced crop nutrition. In the study presented here, we explored the long-term effects of various combinations of maize stover, cattle manure and nitrogen (N) and phosphorus (P) fertilizer applications on maize (Zea mays L.) yield and nutrient and water use efficiencies under reduced tillage practices. In a companion paper, we present the effects on nutrient balances and soil fertility characteristics. The ongoing factorial field trial was conducted at Shouyang Dryland Farming Experimental Station in northern China from 1993 onwards. The incomplete, determinant-optimal design comprised 12 treatments, including a control treatment, in duplicate. Grain yields and N, P, and potassium (K) uptakes and N, P and K use efficiencies were greatly influenced by the amount of rain during the growing season (GSR), and by soil water at sowing (SWS). There were highly significant interactions between GSR and added stover and manure, expressed in complex annual variations in grain yield and N, P and K use efficiencies. Annual mean grain yields ranged from 3,000 kg ha⁻¹ to 10,000 kg ha⁻¹ and treatment mean yields from 4,500 kg ha⁻¹ to 7,000 kg ha⁻¹. Balanced combination of stover (3,000–6,000 kg), manure (1,500–6,000 kg) and N fertilizer (105 kg) gave the highest yield. Stover and manure were important for supplying K, but the effects differed greatly between years. Overall mean N recovery efficiency (NRE) ranged from 28% to 54%, depending on N source. NRE in wet years ranged from 50% to 90%. In conclusion, balanced combinations of stover, manure and NP fertilizer gave the highest yield and NRE. Reduced tillage with adding stover and manure in autumn prior to ploughing is effective in minimizing labor requirement and wind erosion. The potentials of split applications of N fertilizer, targeted to the need of the growing crop (response farming), should be explored to further increase the N use efficiency.