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排序方式: 共有255条查询结果,搜索用时 31 毫秒
1.
V.I. Popkov O.V. Almjasheva V.N. Nevedomskiy V.V. Panchuk V.G. Semenov V.V. Gusarov 《Ceramics International》2018,44(17):20906-20912
Formation and structural transformations of yttrium orthoferrite crystals have been studied using X-ray diffractometry, Mössbauer spectroscopy and transmission electron microscopy combined with electron microdiffraction. Said processes have been studied under heat treatment of glycine-nitrate combustion products. There have been identified formations of three structural yttrium orthoferrite modifications – amorphized hexagonal <h1>-YFeO3 (P63cm) and nanocrystalline hexagonal h2-YFeO3 (P63/mmc), as well as nanocrystalline orthorhombic o-YFeO3 (Pbnm), which are selectively formed depending on available three-dimensional confinements. Based on the analysis of changes in the fluid and size composition formulation, it has been proposed mechanism for formation and transformation of YFeO3 nanocrystals, including growth stage of h2-YFeO3 crystals due to amorphized phase of <h1>-YFeO3 up to critical size of about 15?nm and their subsequent transformation into orthorhombic form o-YFeO3. 相似文献
2.
The solvent-dependent polymorphism of the active pharmaceutical ingredient (API) carbamazepine is interpreted from calculations of the solid-state and API-solvent intermolecular interactions. These simulations suggested that apolar solute-solute interactions could be disrupted by apolar solvents. In contrast, the polar solute-solute interactions were found to be easily disrupted by polar and protic solvents. This is consistent with experimental observations that the crystallization of the metastable form II is more dominant in apolar solvents. The Mercury program remains the gold standard in terms of usability; however, further expansion into more complex simulation techniques could make this package of even greater use in pharmaceutical manufacturing workflows. 相似文献
3.
The inhibition effect of three organic additives on the precipitation and polymorphism of CaCO3 deposited on gold surfaces was investigated using electrochemical and microscopic techniques. Additives, two polyacrylic acid (PAA) polymers with different molecular weights (Mw 2100, Mw 30,000), and 1,2,4,5‐benzenetetracarboxylic acid (BTCA), were either added to the solution before or during deposition. In the presence of 100 ppm of one of the three additives in solution, almost no scale was observed on the surface for at least 24 hours. In the presence of lower concentrations of PAA Mw 2100, only distorted calcite crystals were obtained while with PAA Mw 30,000 the polymorph was spherical vaterite. A mixture of calcite and vaterite was observed with the BTCA additive. Addition of the polymers inhibits further nucleation and growth even if added after partial deposition of CaCO3 while BTCA has no effect once nucleation has started. The results indicate that the inhibit ion effect of the PAA polymers is due to adsorption on the electrode surface while the effect of BTCA is related to chelation of calcium ions in solution. 相似文献
4.
This work examined how the molecular weight of atactic polystyrene (aPS) affects the thermal properties and crystal structure of syndiotactic polystyrene (sPS)/aPS blends using differential scanning calorimetry, polarized light microscopy and wide angle X-ray diffraction (WAXD) technique. For comparative purposes, the structure and properties of the parent sPS was also investigated. The experimental results indicated that these blends showed single glass transition temperatures (Tgs), implying the miscibility of these blends in the amorphous state regardless of the aPS molecular weight. The non-isothermal and isothermal melt crystallization of sPS were hindered with the incorporation of aPSs. Moreover, aPS with a lower molecular weight caused a further decrease in the crystallization rate of sPS. Complex melting behavior was observed for parent sPS and its blends as well. The melting temperatures of these blends were lower than those of the parent sPS, and they decreased as the molecular weight of aPS decreased. Compared with the results of the WAXD study, the observed complex melting behavior resulted from the mixed polymorphs (i.e. the α and β forms) along with the melting-recrystallization-remelting of the β form crystals during the heating scans. The degree of melting-recrystallization-remelting phenomenon for each specimen was dependent primarily on how fast the sPS crystals were formed instead of the incorporation of aPSs. Furthermore, the existence of aPS in the blends, especially the lower molecular weight aPS, apparently reduced the possibility of forming the less stable α form in the sPS crystals. 相似文献
5.
王军 《上海第二工业大学学报》2003,20(1):50-54
介绍了软件工程领域的技术同实际应用相结合的具体方法,面向对象技术是当今的主流软件开发方法,它具有封装性、继承性和多态性。文中讨论了面向对象技术的封装性和多态性在冷冲模CAD系统中的应用,分析他们在提高系统可扩充性、降低系统复杂度方面的作用,并举例分别加以说明。 相似文献
6.
7.
Marija Djokić Jelena Djuriš Ljiljana Solomun Kyriakos Kachrimanis Zorica Djurić Svetlana Ibrić 《Chemical Engineering Research and Design》2014
The purpose of this study was to investigate the influence of spiral jet-milling process on the physicochemical characteristics of α polymorphic active pharmaceutical ingredient, using Carbamazepine form III as a model drug, and taking into consideration Quality by Design (QbD) approach to pharmaceutical development. A 2(4-1) factorial screening design was implemented to identify the spiral jet-milling process variables that significantly affect the particle size distribution of milled samples. Diameter of injector nozzles, diameter of ring nozzles and air pressure were selected for further analysis using a 2(3-1) factorial experimental design. Particle size distribution of additional samples was determined, while physicochemical properties were examined by differential scanning calorimetry (DSC), hot-stage polarized microscopy (HSPM), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), and compared to those of un-milled drug. The gathered results shown that applied experimental design approach is capable to predict material behavior and could help in better understanding of material behavior during jet-milling process. Created design space (DS) provides assurance of product quality, expressed as the powder particle sizes lower than 5 μm, as well as, in initial polymorph form existence after jet-milling through combination and interaction of input variables. 相似文献
8.
Nathan M. Korlesky Lucas J. Stolp Dharma R. Kodali Robert Goldschmidt William C. Byrdwell 《Journal of the American Oil Chemists' Society》2016,93(7):995-1005
Montmorency sour cherry (Prunus cerasus L.) pit oil (CPO) was extracted and characterized by various methods including: GC, LC–MS, NMR, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and X‐ray powder diffraction (XRD). The oil gave an acid value of 1.45 mg KOH/g, saponification value of 193 mg KOH/g and unsaponifiable matter content of 0.72 %. The oil contained oleic (O) and linoleic (l ) acids as the major components with small concentrations of α‐eleostearic acid (El, 9Z,11E,13E‐octadecatrienoic acid) and saturated fatty acid palmitic (P) acid. The CPO contained six major triacyglycerols (TAG), OOO (16.83 %), OLO (16.64 %), LLO (13.20 %), OLP (7.25 %), OOP (6.49 %) and LElL (6.16 %) plus a number of other minor TAG. The TAG containing at least one saturated fatty acid constitute 33 % of the total. The polymorphic behavior of CPO as studied by DSC and XRD confirmed the presence of α, β′ and β crystal forms. The oxidative induction time of CPO was 30.3 min at 130 °C and the thermal decomposition temperature was 352 °C. 相似文献
9.
Yan Chen Xiao-yan Jiang Li Xu Xia Li Fei-fei Cao Lei Li Ming Lu Li Jin Xiao-feng Wang 《Lipids》2009,44(8):719-723
Recently, two polymorphisms (rs1884052 and rs3778099) of estrogen receptor α (ER-alpha) gene were identified as being associated
with primary quantitative bone mineral density (BMD) in a genome-wide association (GWA) study in Framingham cohorts. In this
study we aimed at investigating the association of rs1884052 and rs3778099, and another polymorphism (rs2234693) located at
intron 1 of the ER-alpha gene with BMD, body mass index (BMI), glucose, triglyceride, and total cholesterol (CHO) levels in
Chinese Hans. We recruited 425 consecutive adult volunteers who had a physical examination in the Jinan Maternity and Child
Care Hospital. We did not observe significant association of rs1884052 and rs3778099 with BMD, BMI, glucose, triglyceride,
and total cholesterol (CHO) levels. For rs2234693, increased levels of BMD for hip, spine or whole-body regions were consistently
observed in TT/TC genotype carriers than in CC genotype carriers, although the board line significance diminished after adjusting
for age and gender. However, significant association of rs2234693 with glucose and CHO levels were observed in our sample.
Subjects with TC/CC genotypes were associated with an increased level of glucose (p = 0.013) and CHO (p = 0.032) levels than subjects with TT genotypes. In conclusion, we did not confirm the association of rs1884052 and rs3778099
with BMD originally discovered in a GWA study; however, we made novel discoveries that rs2234693 was associated with glucose
and CHO levels in Chinese Hans.
Y. Chen and X. Jiang have contributed equally. 相似文献
10.
Java语言中的继承与多态 总被引:1,自引:0,他引:1
在Java教学时、类的继承、多态是教学中的重点和难点。通过用内存解析的方法来讲解继承与多态,更容易被学生接受和理解。 相似文献