Copper–4,4′-dipyridyl coordination compound as solid reagent for spectrophotometric determination of reducing sugar employing a multicommutation approach

In this work a multicommuted flow system employing copper–4,4′- dipyridyl coordination compound as the solid-phase reagent for the spectrophotometric determination of reducing sugar was developed. The coordination compound was synthesized through a reaction of the 4,4′-dipyridyl and copper (II) nitrate, under hydrothermal conditions. The complex was characterized by infrared spectroscopy (FTIR), power X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and thermogravimetric analysis (TGA). Based on the characterization, a multicommuted spectrophotometric procedure for the determination of reducing sugar using copper (II) complex as solid reagent is proposed. The proposed method was based on the redox reaction between a monosaccharide, such as fructose and glucose (reducing sugar) and Cu(II). This reaction, mediated in an alkaline medium, produces a yellow compound that can be determined by absorption electronic spectroscopy (λ_ABS = 420 nm). Under optimum experimental conditions, a linear response ranging from 1.0 to 20.0 g L⁻¹ (R = 0.9978 and n = 5), a detection (3σ criterion) and quantification (10σ criterion) limit estimated at 0.23 and 0.75 g L⁻¹, respectively, a standard deviation relative of 4.7% (n = 7), for a reference solution of 10.0 g L⁻¹ reducing sugar, and a sampling rate of 75 determinations per hour were achieved. The proposed system was applied to the determination of reducing sugars in coconut water and juices. The analysis of ten samples and the application of the t-test to the results found, and those obtained using reference procedures (AOAC), provided no significant differences at a 95% confidence level. This system enabled the analysis of reducing sugar with ease and simplicity, providing a significant economy of the solid reagent (600 μg per determination) and reducing effluent generation.     

Data sharing mechanism of various mineral resources based on blockchain

Basins with various mineral resources coexisting and enriching often occupy an important strategic position. The exploration of various mineral resources is repetitive at present due to unshared data and imperfect management mechanism. This situation greatly increases the cost of energy exploitation in the country. Traditional data-sharing mode has several disadvantages, such as high cost, difficulty in confirming the right of data, and lack of incentive mechanism, which make achieving real data sharing difficult. In this paper, we propose a data-sharing mechanism based on blockchain and provide implementation suggestions and technical key points. Compared with traditional data-sharing methods, the proposed data-sharing mechanism can realize data sharing, ensure data quality, and protect intellectual property. Moreover, key points in the construction are stated in the case study section to verify the feasibility of the data-sharing system based on blockchain proposed in this paper.     

个性化公开密钥系统的设计

论文提出利用用户提供的个性化信息来随机产生关联大素数,保证了素数选取的随机化、个性化,提高了RSA算法的安全性。     

开关电源的平均电流自动均流技术

针对多个开关电源并联时易出现负载电流在各模块间分配不均的现象,介绍了常用的负载电流自动均流法——平均电流自动均流法及其工作特性。并针对其存在母线电压降低的缺陷,提出了一种改进的平均电流自动均流方法,经试验证明均流精度比较高。     

没有SDC的(t，n)门限秘密共享方案

利用椭圆曲线离散问题对数问题的难解性,给出了基于椭圆曲线密码体制的(t,n)门限秘密共享方案。基于门限秘密共享方案一般分为需要SDC和不需要SDC两类,在分布式环境下,一个被所有成员信任的SDC并不存在,不需要SDC的门限秘密共享方案的安全性得到很大的提高,该方案中由组成员共同生成群公钥和私有密钥。并给出了当新成员加入时,无SDC下的周期密钥分片的更新方案。还给出了一个本方案数据实例,最后对本方案的安全性进行了分析。     

全球3G市场管制政策分析

主要对各国3G许可证与使用技术标准的抽绑政策．各国对2G／3G网络漫游的管制规定。以及3G网络之间共享的种类及实施方式等方面做了详尽的讲解，并进行比较和分析。     

多服务组的流媒体安全通信机制

提出了一种基于多服务组的流媒体安全通信机制.现有的方案一般是针对用户只参加一个多播组的通信,很少涉及到一个用户同时参加多个多播组的通信,而且没有提供有效的发送方身份验证机制.本文提出了一种具有发送方身份验证功能的一个用户同时可以参加多个组通信的方案,大大地降低了用户和服务器的存储开销,与传统的密钥树方案相比,用户的存储开销降低为原来的l/lgn(n为组中的用户数目),有良好的可扩展性.另外,本机制实现了可靠的发送方身份验证功能.     

雷达间的电磁兼容性判决

通过对雷达信号(或干扰)处理过程的分析,对发现概率和虚警概率的定义作了合理的扩展,使二者可以直接用于雷达间的电磁兼容判定,并在此基础上建立了雷达间电磁兼容判决模型.这种基于经典雷达信号检测理论的模型能客观、真实地反映出雷达间的干扰情况,并且可以应用在雷达间电磁兼容性预测模型中.     

一个完善的秘密分享方案

可验证秘密分享在实用密码学领域内是一个非常重要的工具,它在密钥管理协议、门限或分布式签名协议、电子商务、多方安全计算及团体式密码系统等许多方面都有极为广泛的应用。针对一类突发事务须及时、安全解决的特点, 利用离散对数问题的难解性,在假设初始化阶段和秘密恢复阶段始终有一位值得信赖的分发者参与的情况下,提出了一个可公开验证的门限秘密分享方案。     

On Finding the Multicast Protection Tree Considering SRLG in WDM Optical Networks

In this letter, a new sharing mechanism, SRLG sharing, is proposed, which allows the links of the same shared risk link group (SRLG) in a primary light tree to share protections in WDM optical networks. In previous studies, how to share spare resources with SRLG constraints has not been studied in multicast optical networks. In this letter, considering SRLG sharing, we propose a novel algorithm –multicast with SRLG sharing (MSS)– to establish a protection light tree. Finally, the algorithm MSS and the algorithm multicast with no SRLG sharing (MNSS) are compared through a simulation to show that our new sharing scheme of SRLG sharing is more efficient than that of no SRLG sharing in terms of spare resource utilization and blocking probability.